4-butyryloxy-3-butyryloxymethyl-heptane | 96865-60-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-butyryloxy-3-butyryloxymethyl-heptane
• 英文别名: 4-Butyryloxy-3-butyryloxymethyl-heptan；2-Ethyl-1,3-hexandiol-dibutyrat；(3-Butanoyloxy-2-ethylhexyl) butanoate
• CAS: 96865-60-0
• 化学式: C₁₆H₃₀O₄
• 分子量: 286.412
• InChiKey: IBUNLDSASGMGBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  正丁醛 生成 4-butyryloxy-3-butyryloxymethyl-heptane
  参考文献：
  名称：

  VILLACORTA, G. M.;FILIPPO, J. S. ,, JR, J. ORG. CHEM., 1983, 48, N 8, 1151-1154

  摘要：

  DOI：

文献信息

• v.Braun; Manz, Chemische Berichte, 1934, vol. 67, p. 1703
  作者：v.Braun、Manz

  DOI：——

  日期：——
• Modification of mesoporous silicate SBA-15 with tris[bis(trimethylsilyl)amido]samarium and its utility in Tishchenko reaction
  作者：Yinghua Chen、Zhenyu Zhu、Jie Zhang、Jianzhong Shen、Xigeng Zhou

  DOI：10.1016/j.jorganchem.2005.05.013

  日期：2005.8

  Treatment of mesoporous silicate SBA-15 with Sm[N(SiMe3)(2)](3) led to the formation of a novel organolanthanide/inorganic hybrid material [SBA-15]Sm[N(SiMe3)(2)](x) via abstraction of N(SiMe3)(2) by terminal silanol groups and subsequent surface silylation. The hybrid material was characterized by elemental analyses, IR spectroscopy, X-ray diffraction, and nitrogen sorption, indicating a successful tailoring inside the silicate SBA-15 and the maintenance of the well-ordered mesostructure. This hybrid material is a promising heterogeneous catalyst for the Tishchenko reaction, where it is superior to the homogeneous correspondent in deactivation behavior, reusability and relative tolerance to oxygen, particularly in the control of selectivity of mixed Tishchenko reaction due to the steric hindrance and the diffusion control derived from the surface confinement. (c) 2005 Elsevier B.V. All rights reserved.
• FOUQUET G.; MERGER F.; PLATZ R., LIEBIGS ANN. CHEM., 1979, NO 10, 1951-1601
  作者：FOUQUET G.、 MERGER F.、 PLATZ R.

  DOI：——

  日期：——
• Foaming Agent And Method For Floatation Of Insoluble Components Of Raw Salts
  申请人：Pedan Klaus-Ulrich

  公开号：US20110290704A1

  公开（公告）日：2011-12-01

  The invention relates to a method for separating insoluble components from sylvinite, wherein the sylvinite is suspended in a saturated salt brine, a coagulating agent is added to the suspension, and a foaming agent is then added to the composition thus obtained, said foaming agent comprising and ether and/or ester, wherein a) the ethers of formula 1 correspond to R—O—R′ (1), where R is a linear or branched alkyl or alkenyl groups having 2 to 30 carbon atoms and R′ is a linear or branched alkyl or alkenyl groups having 1 to 30 carbon atoms; b) the esters are derived from monovalent or multivalent alcohols having 1 to 30 carbon atoms (alcohol radicals); or c) the ethers and/or esters are cyclic, wherein the ring size is 6 to 30 carbon atoms.
• US6010989A
  申请人：——

  公开号：US6010989A

  公开（公告）日：2000-01-04