3,6-双(2-甲基-2-吗啉丙酰基)-9-辛基咔唑 | 104005-37-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 3,6-双(2-甲基-2-吗啉丙酰基)-9-辛基咔唑
• 中文别名: 3,6-二(2-甲基-2-吗啉代丙酰)-9-辛基咔唑
• 英文名称: 3,6-Bis(2-methyl-2-morpholinopropionyl)-9-octylcarbazole
• 英文别名: 2-methyl-1-[6-(2-methyl-2-morpholin-4-ylpropanoyl)-9-octylcarbazol-3-yl]-2-morpholin-4-ylpropan-1-one
• CAS: 104005-37-0
• 化学式: C₃₆H₅₁N₃O₄
• 分子量: 589.8
• InChiKey: DCBJXJOKADGNAA-UHFFFAOYSA-N

物化性质

• 熔点：
  116-120 °C(lit.)
• 沸点：
  685.7±55.0 °C(Predicted)
• 密度：
  1.14±0.1 g/cm3(Predicted)
• 稳定性/保质期：
  如果按照规格使用和储存，则不会分解，未有已知危险反应。应避免与强氧化物、酸、碱或还原剂接触。

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  43
• 可旋转键数：
  13
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  64
• 氢给体数：
  0
• 氢受体数：
  6

制备方法与用途

用途：光引发剂。

文献信息

• RESIN COMPOSITION
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20190241716A1

  公开（公告）日：2019-08-08

  The present invention provides a resin composition having a high sensitivity and serving to produce a cured film with a low water absorption rate. The resin composition includes: (a) an alkali-soluble resin and (b1) an amido-phenol compound containing a phenolic hydroxyl group in which a monovalent group as represented by the undermentioned general formula (1) is located at the ortho position and/or (b2) an aromatic amido acid compound containing a carboxy group in which a monovalent group as represented by the undermentioned general formula (2) is located at the ortho position: wherein in general formula (1), X is a monovalent organic group having an alkyl group that contains 2 to 20 carbon atoms and bonds directly to the carbonyl carbon in general formula (1) or a monovalent organic group that has —(YO) n —; and in general formula (2), U is a monovalent organic group that has an alkyl group containing 2 to 20 carbon atoms and bonding directly to the amide nitrogen in general formula (2) or a monovalent organic group that has —(YO) n —; wherein Y is an alkylene group containing 1 to 10 carbon atoms and n is an integer of 1 to 20.

  本发明提供了一种树脂组合物，具有高灵敏度，并用于生产具有低吸水率的固化膜。该树脂组合物包括：(a)可溶于碱的树脂和(b1)含有酚羟基的酰胺酚化合物，其中酚羟基化合物中的单价基在邻位上，和/或(b2)含有羧基的芳香酰胺酸化合物，其中羧基化合物中的单价基在邻位上，其通式如下所示：在通式(1)中，X是一个单价有机基，具有含有2到20个碳原子的烷基，并直接连接到通式(1)中的羰基碳，或具有—(YO)n—的单价有机基；在通式(2)中，U是一个单价有机基，具有含有2到20个碳原子的烷基，并直接连接到通式(2)中的酰胺氮，或具有—(YO)n—的单价有机基；其中Y是含有1到10个碳原子的烷基，n是1到20的整数。
• DIAMINE COMPOUND, AND HEAT-RESISTANT RESIN OR HEAT-RESISTANT RESIN PRECURSOR USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20170334837A1

  公开（公告）日：2017-11-23

  Provided are a photosensitive resin composition which has excellent pattern processabilities (high sensitivity and high resolution) and is excellent in chemical resistance and thermal resistance after thermally treated; a heat-resistant resin or heat-resistant resin precursor used for the composition; and a diamine compound which is a raw material of the resin and the precursor. The diamine compound is a diamine compound represented by a general formula (1).

  提供了一种具有优异图案加工性（高灵敏度和高分辨率）且在热处理后具有优异化学耐性和热耐性的光敏树脂组合物；用于该组合物的耐热树脂或耐热树脂前体；以及作为树脂和前体原料的二胺化合物。该二胺化合物是由通式（1）表示的二胺化合物。
• Resin composition for a coating for an optical fiber, and coated optical fiber and optical fiber unit using the same
  申请人：DAINIPPON INK AND CHEMICALS, INC.

  公开号：US20030210879A1

  公开（公告）日：2003-11-13

  A resin composition for a coating for an optical fiber which comprises a radical polymerizable oligomer (A) and a radical polymerizable monomer (B), wherein (A) comprises a radical polymerizable oligomer (A1) with Mn of 600 to 1600 formed by reacting compounds (1) to (3) below: (1) an aliphatic polyol compound with Mn of 50 to 600, (2) a polyisocyanate compound with a ring structure, and (3) a compound with a hydroxyl group and a radical polymerizable unsaturated group; and a radical polymerizable oligomer (A2) formed by reacting compounds (4) to (6) below: (4) an aliphatic polyol compound with Mn of 800 to 10,000, (5) a polyisocyanate compound, and (6) a compound with a hydroxyl group and a radical polymerizable unsaturated group; a mass ratio (A1)/ (A2) is 20/80 to 80/20, and a concentration of urethane linkages within the resin composition is 1.85 to 3.00 mol/kg.

  一种用于光纤涂层的树脂组合物，包括一种自由基聚合的寡聚体（A）和一种自由基聚合的单体（B），其中（A）包括一种由下列化合物（1）至（3）反应形成的平均分子量为600至1600的自由基聚合寡聚体（A1）：（1）平均分子量为50至600的脂肪族多元醇化合物，（2）具有环状结构的聚异氰酸酯化合物，以及（3）具有羟基和自由基聚合不饱和基团的化合物；以及由下列化合物（4）至（6）反应形成的自由基聚合寡聚体（A2）：（4）平均分子量为800至10,000的脂肪族多元醇化合物，（5）聚异氰酸酯化合物，以及（6）具有羟基和自由基聚合不饱和基团的化合物；（A1）/（A2）的质量比为20/80至80/20，树脂组合物中脲键的浓度为1.85至3.00摩尔/千克。
• Alkylphenylbisacylphosphine oxides and photoinitiator mixtures
  申请人：——

  公开号：US20020042022A1

  公开（公告）日：2002-04-11

  Compounds of the formula I 1 in which R 1 is C 1 -C 4 alkyl, R 2 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy and R 3 , R 4 , R 6 and R 7 independently of one another are hydrogen, halogen, C 1 -C 20 alkyl, cyclopentyl, cyclohexyl, C 2 -C 12 alkenyl, C 2 -C 18 alkyl which is interrupted by one or more oxygen atoms, or are phenyl-substituted C 1 -C 4 alkyl, or are phenyl which is unsubstituted or is mono- or disubstituted by C 1 -C 4 alkyl and/or C 1 -C 4 alkoxy, with the provisos that at least one of the radicals R 3 , R 4 , R 5 , R 6 and R 7 is other than hydrogen and that, if R 1 and R 2 are methyl, R 3 and R 6 are not methyl, and mixtures of such compounds with &agr;-hydroxy ketones, benzophenones and &agr;-amino ketones, are suitable as photoinitiators.

  化合物I1的公式为：其中R1为C1-C4烷基，R2为氢、C1-C4烷基或C1-C4烷氧基，R3、R4、R6和R7彼此独立地为氢、卤素、C1-C20烷基、环戊基、环己基、由一个或多个氧原子中断的C2-C18烷基，或为苯基取代的C1-C4烷基，或为未取代或被C1-C4烷基和/或C1-C4烷氧基单取代或双取代的苯基。但须满足至少有一个基团R3、R4、R5、R6和R7不是氢，如果R1和R2是甲基，则R3和R6不是甲基。这些化合物与α-羟基酮、苯甲酮和α-氨基酮的混合物适用于光引发剂。
• Resin composition for coating optical fiber and coated optical fiber and optical fiber unit using the same
  申请人：Dainippon Ink and Chemicals, Inc.

  公开号：US20030138231A1

  公开（公告）日：2003-07-24

  A resin composition for an optical fiber is provided which can be sufficiently cured even in high-speed processing (at a low light energy dose) to obtain a cured article having a Young's modulus suitable for use for an optical fiber, and also causes neither increase in viscosity nor deposition of solids in storage for a long period or in storage at a high temperature and can be easily coated even after such storage. A coated fiber and an optical fiber unit, which use the resin composition are also provided. The composition contains a radical polymerizable compound (A); a photopolymerization initiator (B); a sulfide (C) represented by the formulas: R 1 —S—R 1 , R 2 OOCCH 2 CH 2 —S—CH 2 CH 2 COOR 2 , (R 3 —SCH 2 CH 2 COOCH 2 ) 4 C, HOCH 2 CH 2 S—R 4 —SCH 2 CH 2 OH, 1 R 8 —SCH 2 CH 2 COOR 9 ; and an organic amine (D) represented by the formula: 2

  提供了一种用于光纤的树脂组合物，即使在高速处理（低光能剂量）时也可以充分固化，以获得适用于光纤的杨氏模量的固化物，并且在长期储存或高温储存时既不会增加粘度也不会沉淀固体，并且即使在这样的储存后也可以轻松涂层。提供了使用该树脂组合物的涂覆纤维和光纤单元。该组合物包含以下成分：自由基聚合性化合物（A）；光聚合引发剂（B）；硫化物（C），其由以下公式表示：R1—S—R1、R2OOCCH2CH2—S—CH2CH2COOR2、（R3—SCH2CH2COOCH2）4C、HOCH2CH2S—R4—SCH2CH2OH、1R8—SCH2CH2COOR9；以及有机胺（D），其由以下公式表示：2。