methyl 3,5-bis(anthrylmethoxy)benzoate | 540781-07-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: methyl 3,5-bis(anthrylmethoxy)benzoate
• 英文别名: Methyl 3,5-bis(anthracen-9-ylmethoxy)benzoate
• CAS: 540781-07-5
• 化学式: C₃₈H₂₈O₄
• 分子量: 548.638
• InChiKey: CUBKTADAAXNSBS-UHFFFAOYSA-N

物化性质

• 熔点：
  250-251 °C(Solv: acetone (67-64-1))
• 沸点：
  780.7±50.0 °C(Predicted)
• 密度：
  1.266±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  42
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  methyl 3,5-bis(anthrylmethoxy)benzoate 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 以96%的产率得到[3,5-Bis(anthracen-9-ylmethoxy)phenyl]methanol
  参考文献：
  名称：

  Synthesis and photoluminescence study of anthracene based dendrimer and dendron

  摘要：

  A new type of polyaromatic dendrimer composed of six anthracene groups was synthesized, which showed a monomeric fluorescence feature with a diminished quantum yield due to intramolecular self-quenching processes in the dendritic framework. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00334-4
• 作为产物：
  描述：

  9-氯甲基蒽 、 3,5-二羟基苯甲酸甲酯 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以93%的产率得到methyl 3,5-bis(anthrylmethoxy)benzoate
  参考文献：
  名称：

  Synthesis and photoluminescence study of anthracene based dendrimer and dendron

  摘要：

  A new type of polyaromatic dendrimer composed of six anthracene groups was synthesized, which showed a monomeric fluorescence feature with a diminished quantum yield due to intramolecular self-quenching processes in the dendritic framework. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00334-4

文献信息

• DIELS-ALDER CROSSLINKABLE DENDRITIC NONLINEAR OPTIC CHROMOPHORES AND POLYMER COMPOSITES
  申请人：Jen Kwan-Yue

  公开号：US20090299021A1

  公开（公告）日：2009-12-03

  Diels-Alder crosslinkable dendritic nonlinear optical chromophore compounds, films and crosslinked polymer composites formed from the chromophore compounds, methods for making and using the chromophore compounds, films, and crosslinked polymer composites, and electro-optic devices that include films and crosslinked polymer composites formed from the chromophore compounds.
• US8173045B2
  申请人：——

  公开号：US8173045B2

  公开（公告）日：2012-05-08
• US9023248B2
  申请人：——

  公开号：US9023248B2

  公开（公告）日：2015-05-05
• Synthesis and photoluminescence study of anthracene based dendrimer and dendron
  作者：Masaki Takahashi、Tomoya Odagi、Hiroko Tomita、Tatsuo Oshikawa、Mitsuji Yamashita

  DOI：10.1016/s0040-4039(03)00334-4

  日期：2003.3

  A new type of polyaromatic dendrimer composed of six anthracene groups was synthesized, which showed a monomeric fluorescence feature with a diminished quantum yield due to intramolecular self-quenching processes in the dendritic framework. (C) 2003 Elsevier Science Ltd. All rights reserved.