2,2'-bis{6-[4-(2-(4-hexyloxyphenyl)pyrimidine-5-yl)phenyloxy]hexyloxy}biphenyl | 1357468-66-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 2,2'-bis{6-[4-(2-(4-hexyloxyphenyl)pyrimidine-5-yl)phenyloxy]hexyloxy}biphenyl
• 英文别名: 2-(4-Hexoxyphenyl)-5-[4-[6-[2-[2-[6-[4-[2-(4-hexoxyphenyl)pyrimidin-5-yl]phenoxy]hexoxy]phenyl]phenoxy]hexoxy]phenyl]pyrimidine；2-(4-hexoxyphenyl)-5-[4-[6-[2-[2-[6-[4-[2-(4-hexoxyphenyl)pyrimidin-5-yl]phenoxy]hexoxy]phenyl]phenoxy]hexoxy]phenyl]pyrimidine
• CAS: 1357468-66-6
• 化学式: C₆₈H₇₈N₄O₆
• 分子量: 1047.39
• InChiKey: ZHYATRZOKDWNBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.4
• 重原子数：
  78
• 可旋转键数：
  35
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,2'-二羟基联苯 、 在 potassium carbonate 作用下， 以 环己酮 为溶剂， 以57%的产率得到2,2'-bis{6-[4-(2-(4-hexyloxyphenyl)pyrimidine-5-yl)phenyloxy]hexyloxy}biphenyl
  参考文献：
  名称：

  Pre-Organization Effects on Chirality, Polarity and Biaxiality in Liquid Crystals: Novel Laterally Connected Mesogens showing Anomalous Properties

  摘要：

  Pre-organization effects are investigated for the laterally-connected liquid crystals possessing a biphenyl connecting group. The homeotropic texture of the N phase of a free-standing film sample was found to change into the other "Schlieren" texture on cooling even in the N phase, which then changes into the "Schlieren" texture of the SmC phase on further cooling. The possibility of the emergence of biaxiality in the N phase is discussed.

  DOI：

  10.1080/15421406.2011.581528

文献信息

• Pre-Organization Effects on Chirality, Polarity and Biaxiality in Liquid Crystals: Novel Laterally Connected Mesogens showing Anomalous Properties
  作者：Isa Nishiyama、Yuka Tabe、Jun Yamamoto、Hiroshi Yokoyama

  DOI：10.1080/15421406.2011.581528

  日期：2011.10.28

  Pre-organization effects are investigated for the laterally-connected liquid crystals possessing a biphenyl connecting group. The homeotropic texture of the N phase of a free-standing film sample was found to change into the other "Schlieren" texture on cooling even in the N phase, which then changes into the "Schlieren" texture of the SmC phase on further cooling. The possibility of the emergence of biaxiality in the N phase is discussed.