3,9-二(苯氧基)-2,4,8,10-四氧杂-3,9-二磷杂螺[5.5]十一烷 | 144-35-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,9-二(苯氧基)-2,4,8,10-四氧杂-3,9-二磷杂螺[5.5]十一烷
• 中文别名: 3,9-二苯-2,4,8,10-四氧杂-3,9-二磷酸螺[5.5]十一烷
• 英文名称: 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9-diphospha-spiro[5.5]undecane
• 英文别名: 3,9-Diphenoxy-2,4,8,10-tetraoxa-3,9-diphospha-spiro[5.5]undecan；diphenyl pentaerythritol diphosphite；Diphenylpentaerythitholdiphosphit；3,9-Diphenoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
• CAS: 144-35-4
• 化学式: C₁₇H₁₈O₆P₂
• 分子量: 380.274
• InChiKey: SDCYWERHEYVPHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2909309090

反应信息

• 作为反应物：
  描述：

  二-叔-丁基过氧草酸酯 、 3,9-二(苯氧基)-2,4,8,10-四氧杂-3,9-二磷杂螺[5.5]十一烷 以 氯苯 为溶剂， 以100%的产率得到3,9-bis[(2-methylpropan-2-yl)oxy]-2,4,8,10-tetraoxa-3λ5,9λ5-diphosphaspiro[5.5]undecane 3,9-dioxide
  参考文献：
  名称：

  Schwetlick, Klaus; Koenig, Thomas; Rueger, Claus, Zeitschrift fur Chemie, 1986, vol. 26, # 10, p. 360 - 366

  摘要：

  DOI：
• 作为产物：
  描述：

  亚磷酸三苯酯 、 季戊四醇 在 sodium phenoxide 作用下， 生成 3,9-二(苯氧基)-2,4,8,10-四氧杂-3,9-二磷杂螺[5.5]十一烷
  参考文献：
  名称：

  Pentaerythritol products

  摘要：

  公开号：

  US02847443A1

文献信息

• PHASE TRANSFER CATALYST FOR SYNTHESIS OF PENTAERYTHRITOL DIPHOSPHITES
  申请人：Stevenson Donald

  公开号：US20110021839A1

  公开（公告）日：2011-01-27

  The present invention pertains to a process for the preparation of pentaerythritol diphosphites via a one-pot, direct esterification of phosphorus trichloride with pentaerithritol, and either an alkylphenol or an arylalkylphenol which functions both as a reactant and as a solvent, with a phase transfer catalyst such as a quaternary ammonium salt.

  本发明涉及一种通过一锅法，直接将三氯化磷与对羟基苯甲醇或芳基烷基苯甲醇以及对羟基丙烷醇酯化制备对羟基丙烷醇二磷酸酯的方法，并使用季铵盐等相转移催化剂。
• PROCESS FOR MANUFACTURE OF PENTAERYTHRITOL DIPHOSPHITES
  申请人：Larke W. Carroll

  公开号：US20050131244A1

  公开（公告）日：2005-06-16

  A method is disclosed for the production of pentaerythritol diphosphites of high spiro isomer content. The pentaerythritol diphosphites are produced via sequential transesterification of pentaerythritol with a monophosphite followed by a substituted phenol or other alcohol, wherein the transesterification reactions are carried out under controlled conditions of temperature and pressure. The unique reaction conditions result in intermediate and final pentaerythritol diphosphites of high spiro isomer content and high total yield of the diphosphites.

  本发明公开了一种生产高螺旋异构体含量的对叔丁基苯酚二磷酸酯的方法。该方法通过将对叔丁基苯酚或其他醇与单磷酸酯逐步进行酯交换反应，其中酯交换反应在控制温度和压力的条件下进行。独特的反应条件导致中间体和最终产物对叔丁基苯酚二磷酸酯具有高螺旋异构体含量和高总产率的特点。
• Continuous sodium phenate-catalyzed transesterification process for
  申请人：General Electric Company

  公开号：US05247118A1

  公开（公告）日：1993-09-21

  A process for making phosphite esters is provided. The process involves reacting triphenyl phosphite with alcohol using a sodium phenate catalyst. The process yields high purity phenol which may be recycled and reacted with PCl.sub.3 to yield triphenyl phosphite.

  提供了一种制备亚磷酸酯的过程。该过程涉及使用钠苯酚催化剂，将三苯基亚磷酸酯与醇反应。该过程产生高纯度的苯酚，可以回收并与PCl.sub.3反应，以产生三苯基亚磷酸酯。
• Process for providing monovalent and polyvalent metal, particularly antimony, mercaptocarboxylic acid ester salts; monovalent and polyvalent metal mercaptocarboxylic acid salts; polyol mercaptocarboxylic acid monoesters, and esters of such polyol mercaptocarboxylic acid esters with a mercaptocarboxylic acid; stabilizer compositions for polyvinyl chloride resins comprising such compounds; and polyvinyl chloride resin compositions comprising a stabilizing amount of such compounds
  申请人：Mack, Gerry

  公开号：EP0024919A2

  公开（公告）日：1981-03-11

  Antimony mercaptocarboxylic acid esters are provided having the formula: wherein: R is selected from the group consisting of hydrogen, alkyl having from one to about eighteen carbon atoms and alkylene linked with R2 in a ring having from three to about eight carbon atoms; R2 is selected from the group consisting of alkyl having from one to about eighteen carbon atoms, phenyl, and alkylene linked with R, in a ring having from three to about eight carbon atoms; R3 is selected from the group consisting of hydrogen and alkyl having from one to three carbon atoms; R4 is selected from the group consisting of alkyl, aryl, alkylaryl, alkoxycarbonyl-alkylene and acyloxyalkylene having from three to about twenty carbon atoms, the alkylene having from two to about six carbon atoms; R5 is selected from the group consisting of alkylene and cycloalkylene having from one to about eighteen carbon atoms, and such groups having from one to four hydroxyl groups; Z is a bivalent alkylene group having from one to five carbon atoms and carrying the sulfur in a position alpha or beta to -OOC-; and n is a number from 1 to 3. A process for preparing such antimony compounds is also provided, as well as predecessor intermediates, and stabilizer compositions for polyvinyl chloride resin compositions comprising such antimony compounds, if desired with other polyvinyl chloride resin stabilizers.

  巯基羧酸锑酯的化学式如下 其中 R 选自氢、具有 1 至约 18 个碳原子的烷基和与 R2 连接成具有 3 至约 8 个碳原子的环的亚烷基组成的组； R2 选自具有 1 至约 18 个碳原子的烷基、苯基和与 R2 连接在具有 3 至约 8 个碳原子的环中的亚烷基组成的组； R3 选自由氢和具有一至三个碳原子的烷基组成的组； R4 选自具有 3 至约 20 个碳原子的烷基、芳基、烷芳基、烷氧羰基亚烷基和酰氧基亚烷基组成的组，其中亚烷基具有 2 至约 6 个碳原子； R5 选自具有 1 至约 18 个碳原子的亚烷基和环亚烷基，以及具有 1 至 4 个羟基的此类基团； Z 是二价亚烷基，具有 1 至 5 个碳原子，并在 -OOC- 的α或β位上带有硫；以及 n 是 1 至 3 的数字。 本发明还提供了制备此类锑化合物的工艺以及前身中间体，并提供了包含此类锑化合物的聚氯乙烯树脂组合物的稳定剂组合物（如需要与其他聚氯乙烯树脂稳定剂一起使用）。
• Polyvinyl halide resin compositions containing 1,3 Dicarbonyl compounds
  申请人：PHOENIX CHEMICAL CORPORATION

  公开号：EP0040286A2

  公开（公告）日：1981-11-25

  1,3-Dicarbonyl compounds are provided having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; R3 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.

  1,3-二羰基化合物的化学式如下 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的此类基团组成的组，和 R2 选自具有 1 至约 18 个碳原子的烃以及被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的烃所组成的组； R3 选自由氢、具有 1 至约 18 个碳原子的烃基以及被 1 个或多个选自由卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基组成的基团取代的烃基所组成的组； 以及它们的金属盐和有机锡烯酸盐。 这些化合物可有效提高聚乙烯卤化树脂的耐热和耐光劣化性能。