3,9-diphenoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dioxide | 55120-33-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dioxide
• 英文别名: 3,9-Diphenoxy-2,4,8,10-tetraoxa-3lambda5,9lambda5-diphosphaspiro[5.5]undecane 3,9-dioxide；3,9-diphenoxy-2,4,8,10-tetraoxa-3λ5,9λ5-diphosphaspiro[5.5]undecane 3,9-dioxide
• CAS: 55120-33-7
• 化学式: C₁₇H₁₈O₈P₂
• 分子量: 412.273
• InChiKey: HNOHROKNIOHGFR-UHFFFAOYSA-N

物化性质

• 熔点：
  197-199 °C
• 沸点：
  475.0±45.0 °C(Predicted)
• 密度：
  1.45±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  3,9-二氯-2,4,8,10-四氧杂-3,9-二磷杂螺[5.5]十一烷3,9-二氧化物 、 苯酚 在 三乙胺 作用下， 以 苯 为溶剂， 生成 3,9-diphenoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane-3,9-dioxide
  参考文献：
  名称：

  3,9-二(烷基苯氧基)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]十一烷的13C NMR研究

  摘要：

  3,9-二(烷基苯氧基)-2,4,8,10-四氧杂-3,9-二磷螺[5.5]十一烷的14种衍生物和3种衍生物的13C NMR化学位移和13C-31P偶联常数， 9-dioxo 型被报道。所有研究的化合物都具有椅子构象，在赤道位置具有孤对或磷酰氧。烷基苯氧基相对于孤对或磷酰氧处于顺式位置。芳基O键的构象变化可以通过31POC13C偶联进行监测，并且发现它们的角度依赖性是非对称的。

  DOI：

  10.1002/mrc.1260230215

文献信息

• Rueger, C.; Koenig, T.; Schwetlick, K., Journal fur praktische Chemie (Leipzig 1954), 1984, vol. 326, # 4, p. 622 - 632
  作者：Rueger, C.、Koenig, T.、Schwetlick, K.

  DOI：——

  日期：——
• HALOGEN FREE FLAME RETARDANT THERMOPLASTIC STYRENE RESIN COMPOSITION
  申请人：LG Chemical Co. Ltd

  公开号：EP1244746B1

  公开（公告）日：2007-02-28
• STRENIC THERMOPLASTIC RESIN COMPOSITION
  申请人：LEE Sung-Ho

  公开号：US20070259999A1

  公开（公告）日：2007-11-08

  The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrene-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.
• Melt-Extrusion Film and Stretched Film
  申请人：Nitta Hideaki

  公开号：US20090280310A1

  公开（公告）日：2009-11-12

  A melt-extrusion film formed by melt-extruding a resin composition containing (A) a specific amorphous polyolefin typified by an ethylene/norbornene copolymer and (B) a specific phosphite ester or aliphatic ester, wherein the number of gels having a size of 20 μm or larger and existing in the film is 100 pieces/g or less.
• POLYCARBONATE RESIN COMPOSITION WITH EXCELLENT FLAME RETARDANCY
  申请人：Son Seon Mo

  公开号：US20110124781A1

  公开（公告）日：2011-05-26

  A polycarbonate resin composition is provided. The composition comprises (A) 50 to 90% by weight of a polycarbonate resin, (B) 5 to 30% by weight of a polymethyl methacrylate resin, (C) 5 to 20% by weight of a phosphate compound, (D) 0.01 to 2% by weight of a metal sulfonate as an organic salt, and (E) 0.05 to 2% by weight of a fluorinated olefin. The composition is highly flame retardant and scratch resistant.