Bis{2-[(2-methylacryloyl)oxy]ethyl} hexanedioate | 4272-13-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Bis{2-[(2-methylacryloyl)oxy]ethyl} hexanedioate
• 英文别名: bis[2-(2-methylprop-2-enoyloxy)ethyl] hexanedioate
• CAS: 4272-13-3
• 化学式: C₁₈H₂₆O₈
• 分子量: 370.4
• InChiKey: LDCRDNMXNWMORR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  26
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• 海关编码：
  2918990090

反应信息

• 作为产物：
  描述：

  己二酸二乙酯 、 甲基丙烯酸乙酯 在 sodium phenoxide 、 对苯二酚 作用下， 生成 Bis{2-[(2-methylacryloyl)oxy]ethyl} hexanedioate
  参考文献：
  名称：

  Bodnaryuk,F.N. et al., Journal of applied chemistry of the USSR, 1972, vol. 45, p. 2617 - 2621

  摘要：

  DOI：

文献信息

• Curable composition and coated article
  申请人：Higuchi Koichi

  公开号：US20070212557A1

  公开（公告）日：2007-09-13

  A curable composition comprises (A) an organic/inorganic composite in which a hydrolyzable silyl group and/or SiOH group-containing polysiloxane is bonded to a vinyl polymer through a Si—C bond, and (B) an organic UV absorber having a molecular weight of at least 500 and a weight retentivity of at least 95% when held at 150° C. for 24 hours in an open state. The curable composition is coated and cured to an article, whereby the article is endowed with satisfactory weathering resistance while minimizing coloration or degradation.

  一种可治愈的组合物包括（A）一种有机/无机复合物，其中通过Si-C键将可水解的硅基团和/或含有SiOH基团的聚硅氧烷与乙烯基聚合物结合，和（B）一种分子量至少为500且在开放状态下保持150°C持续24小时时重量保留率至少为95％的有机紫外线吸收剂。将可治愈的组合物涂覆并固化到物品上，从而使物品在最小化着色或降解的同时具有令人满意的耐候性。
• Coating composition, coating method, and coated article
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP1122278A2

  公开（公告）日：2001-08-08

  A coating composition comprising the reaction product of a benzotriazole compound having a polymerizable vinyl group and a hydroxyl group with a silane compound and/or a (partial) hydrolyzate thereof is applied to plastic substrates, typically polycarbonate resin substrates to form transparent coatings having improved mar, weather and chemical resistance.

  一种涂料组合物由具有可聚合乙烯基和羟基的苯并三唑化合物与硅烷化合物和/或其 （部分）水解物的反应产物组成，应用于塑料基材，通常是聚碳酸酯树脂基材，以 形成具有更好的防污、耐候性和耐化学性的透明涂料。
• Primer composition, coating method, and coated article
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP1408082A2

  公开（公告）日：2004-04-14

  A primer composition comprises (A) a vinyl copolymer obtained through copolymerization of (a-1) a UV-absorbing vinyl monomer, (a-2) an alkoxysilyl group-containing vinyl monomer, and (a-3) another copolymerizable monomer, (B) a curing agent, and (C) a thermoplastic vinyl resin having a Tg of at least 80°C. Polycarbonate resin articles, when covered with an undercoat of the primer composition and an overcoat of an organopolysiloxane composition, exhibit improved transparency, mar resistance, weather resistance, and chemical resistance and find outdoor use as vehicle and building windows and windshields.

  一种底漆组合物包括（A）通过（a-1）紫外线吸收乙烯基单体、（a-2）含烷氧基硅基的乙烯基单体和（a-3）另一种可共聚单体的共聚得到的乙烯基共聚物；（B）固化剂；以及（C）Tg 至少为 80°C 的热塑性乙烯基树脂。聚碳酸酯树脂制品在涂上底漆组合物的底层和有机聚硅氧烷组合物的外层后，透明度、抗磨损性、耐候性和耐化学性均得到改善，可在室外用作汽车和建筑物的窗户和挡风玻璃。
• Primer coating composition and coating method
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP1418198A1

  公开（公告）日：2004-05-12

  A coating composition comprising the reaction product of a benzotriazole compound having a polymerizable vinyl group and a hydroxyl group with a silane compound and/or a (partial) hydrolyzate thereof is applied to plastic substrates, typically polycarbonate resin substrates to form transparent coatings having improved mar, weather and chemical resistance.

  一种涂料组合物由具有可聚合乙烯基和羟基的苯并三唑化合物与硅烷化合物和/或其 （部分）水解物的反应产物组成，应用于塑料基材，通常是聚碳酸酯树脂基材，以 形成具有更好的防污、耐候性和耐化学性的透明涂料。
• Primer composition and coated article
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1914259A1

  公开（公告）日：2008-04-23

  A primer composition for a polysiloxane hard coating is provided. This primer composition comprises (A) a vinyl polymer having a hydrolyzable silyl group and/or SiOH group and an organic UV absorbing group bonded to its side chain, and (B) fine silica particles dispersed in an organic solvent, and the primer layer formed after coating and curing has a coefficient of linear expansion of up to 150×10-6/°C.

  提供了一种用于聚硅氧烷硬涂层的底漆组合物。这种底漆组合物包括：(A) 乙烯基聚合物，其侧链上键合有可水解的硅烷基和/或 SiOH 基以及有机紫外线吸收基；(B) 分散在有机溶剂中的细小二氧化硅颗粒，涂层固化后形成的底漆层的线膨胀系数高达 150×10-6/°C。