2-ethyl-3,5,6-trimethyl-p-phenylenediamine | 104177-53-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-ethyl-3,5,6-trimethyl-p-phenylenediamine
• 英文别名: 2-Aethyl-3,5,6-trimethyl-p-phenylendiamin；2-Ethyl-3,5,6-trimethylbenzene-1,4-diamine
• CAS: 104177-53-9
• 化学式: C₁₁H₁₈N₂
• 分子量: 178.277
• InChiKey: FNBLGBSQYXIENA-UHFFFAOYSA-N

物化性质

• 沸点：
  319.4±37.0 °C(Predicted)
• 密度：
  1.014±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-ethyl-3,5,6-trimethyl-p-phenylenediamine 在 盐酸 、 三氯化铁 作用下， 生成 ethyl-trimethyl-[1,4]benzoquinone
  参考文献：
  名称：

  The Reaction between Quinones and Metallic Enolates. XIV. Synthesis of the Three 3-Carboxy-6-hydroxy-bz-dimethyl Ethylcoumarins and their Ethyl Esters¹

  摘要：

  DOI：

  10.1021/ja01849a011
• 作为产物：
  描述：

  1-乙基-2,4,5-三甲基苯 在 盐酸 、 氯仿 、 硫酸 、 硝酸 、 溶剂黄146 、 tin(ll) chloride 作用下， 生成 2-ethyl-3,5,6-trimethyl-p-phenylenediamine
  参考文献：
  名称：

  The Jacobsen Reaction. VI.¹ Ethyltrimethylbenzenes

  摘要：

  DOI：

  10.1021/ja01874a002

文献信息

• Racemic Drug Resolution Using Polymer Supported Chiral Selector
  申请人：COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEAECH

  公开号：US20160208088A1

  公开（公告）日：2016-07-21

  The present invention relates to a process for the separation of enantiomers or resolution of racemic mixtures using high surface area core-shell polymer beads. The present invention further relates to a core-shell functionalized polymer comprising a core which comprises copolymer made from monomers selected from non-aromatic acrylate, ethylene dimethacrylate and divinyl-benzene, a shell which comprises monomers selected from glycidyl ethers of methacrylate and a chiral selector selected from tartaric acid derivatives and amino acids.

  本发明涉及使用高表面积核壳聚合物珠子分离对映体或分离混合物的过程。本发明还涉及一种核壳功能化聚合物，包括一个核，该核由从非芳香族丙烯酸酯、乙二醇二甲基丙烯酸酯和二乙烯基苯中选择的单体共聚而成，一个壳，该壳由从甲基丙烯酸醋酸酯的环氧乙醚和酒石酸衍生物和氨基酸中选择的单体组成的手性选择剂。
• Orientation layer composition for liquid crystal display devices
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0365855A1

  公开（公告）日：1990-05-02

  An orientation layer composition for liquid crystal display devices comprising a polyamic acid obtainable by reacting (1) a diamine component consisting of one or more diamines selected from aromatic diamines and aliphatic diamines, the diamine component (1) containing at least one diamine represented by the following general formula (I): wherein R¹, R², R³, and R⁴ each independently are an aliphatic hydrocarbon group having from 1 to 10 carbon atoms, and (2) a tetracarboxylic acid dianhydride component; an orientation layer for liquid crystal display devices prepared by using the orientation layer composition for liquid crystal display devices; and a liquid crystal display device including orientation layers prepared by using the orientation layer composition. The orientation layer prepared by using the orientation layer composition for liquid crystal display devices induces a pre-tilt angle of not less than 4° in liquid crystal material and therefore, is particularly advantageous for STN liquid crystal displays in that the selection ranges of cell gap and liquid crystal materials can be expanded.

  一种用于液晶显示设备的定向层组合物，包含一种聚酰胺酸，可通过以下反应获得 (1) 由一种或多种选自芳香族二元胺和脂肪族二元胺的二元胺组成的二元胺组 分，二元胺组分(1)含有至少一种由下式通式(I)表示的二元胺： 其中 R¹、R²、R³ 和 R⁴ 各自独立地为具有 1 至 10 个碳原子的脂肪族烃基、 和 (2) 四羧酸二酐组分；使用该液晶显示器件定向层组合物制备的液晶显示器件定向层；以及包括使用该定向层组合物制备的定向层的液晶显示器件。 使用液晶显示器件用取向层组合物制备的取向层可诱导液晶材料产生不小于 4° 的预倾斜角，因此特别适用于 STN 液晶显示器，可扩大单元间隙和液晶材料的选择范围。
• Polyimide alignment film from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane, dianhydride and ortho-substituted aromatic diamines for active matrix liquid crystal displays
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0768559A1

  公开（公告）日：1997-04-16

  A polyimide alignment film based on 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride and ortho-substituted aromatic diamines, such as 2,3,5,6-tetramethyl-p-phenylene diamine, 2,4,6-trimethyl-m-phenylene diamine and 1,5-diaminonaphthalene, providing high voltage holding ratio and high tilt angle when used in active matrix liquid crystal displays.

  一种基于 2,2-双（3,4-二羧基苯基）六氟丙烷二酐和正交取代芳香族二胺（如 2,3,5,6-四甲基对苯二胺、2,4,6-三甲基间苯二胺和 1,5-二氨基萘）的聚酰亚胺配向膜，用于有源矩阵液晶显示器时可提供高电压保持率和高倾斜角。
• Polyimide photo alignment film from 3, 3'4,4'-Benzophenone tetracarboxylic dianhydride and ortho-substituted aromatic diamines for liquid crystal displays
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP1004925A2

  公开（公告）日：2000-05-31

  The present invention relates to polyimide photo alignment films for liquid crystal display devices comprising an aromatic tetracarboxylic dianhydride component containing 3,3'4,4'-benzophenone tetracarboxylic dianhydride and an aromatic diamine component containing at least one diamine of the group of formulae AI to AIII as given in the text. Further display devices and methods of their fabrication employing a photo alignment process are disclosed.

  本发明涉及用于液晶显示装置的聚酰亚胺光配位薄膜，该薄膜由含有 3,3'4,4'-二苯甲酮四羧酸二酐的芳香族四羧酸二酐组分和含有至少一种如文中所示式 AI 至 AIII 组二胺的芳香族二胺组分组成。本发明还公开了采用光配准工艺的显示设备及其制造方法。
• Active-matrix liquid crystal displays with polyimide alignment films from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane, dianhydride and ortho-substituted aromatic diamines
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0768559B1

  公开（公告）日：2003-08-13