lanthanum(III) triformate | 2081-11-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: lanthanum(III) triformate
• 英文别名: lanthanum methanoate；lanthanum formate；lanthanum(3+);formate
• CAS: 2081-11-0
• 化学式: 3CHO₂*La
• 分子量: 273.959
• InChiKey: CFZMSAFPTUGFDG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.63
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  lanthanum(III) triformate 生成 lanthanum(III) oxycarbonate
  参考文献：
  名称：

  甲酸镧的热分解

  摘要：

  甲酸镧的热分解已通过TG，DTA，GC，IR和X射线衍射技术进行了重新研究。发现甲酸镧根据以下方案分解。

  DOI：

  10.1016/0022-1902(80)80326-5
• 作为产物：
  描述：

  lanthanum(III) nitrate 在 ammonium carbonate 作用下， 以 甲酸 为溶剂， 生成 lanthanum(III) triformate
  参考文献：
  名称：

  Fedorova, I. V.; Shchurov, V. A.; Fedorov, A. A., Journal of applied chemistry of the USSR, 1992, vol. 65, p. 587 - 591

  摘要：

  DOI：

文献信息

• Thermal decomposition of formates. Part IX. Thermal decomposition of rare earth formate anhydrides
  作者：Yoshio Masuda

  DOI：10.1016/0040-6031(83)80108-7

  日期：1983.9

  Abstract The thermal decomposition of rare earth formate anhydrides in a flowing nitrogen atmosphere was studied systematically by means of thermogravimetry and differential thermal analysis. The decomposition consisted of two or three stages 2 Ln(HCO 2 ) 3 → 2 LnO(HCO 2 ) → Ln 2 O 2 ·CO 3 → Ln 2 O 3 The monoxyformate did not appear in the decomposition of the lighter element formates except for lanthanum

  摘要 采用热重法和差热分析法，系统地研究了稀土甲酸酐在流动氮气气氛中的热分解。分解由两个或三个阶段组成 2 Ln(HCO 2 ) 3 → 2 LnO(HCO 2 ) → Ln 2 O 2 ·CO 3 → Ln 2 O 3镧甲酸。在整个系列中都观察到了碳酸氢盐。镨和钕的碳氧酸盐晶体结构为单斜晶型，其他元素为四方晶型。稀土甲酸盐的热稳定性与其结构畸变有关，这必须归因于稀土金属离子半径的收缩。镧分解为甲酸镝的第一阶段是 Avrami 型反应。钬到镥的甲酸盐在分解的主要第一阶段熔化，它们的动力学是一级反应的特征。确定了分解主要阶段的动力学参数，如活化能和指前因子。
• Bismuth and mixed bismuth-lanthanide carboxylates as precursors for pure and Ln-promoted bismuth molybdate catalysts
  作者：M. Devillers、F. De Smet、O. Tirions

  DOI：10.1016/0040-6031(95)90492-1

  日期：1995.8

  Several bismuth(III) carboxylates (formate, acetate, propionate, oxalate, lactate) and the analogous tervalent lanthanum, samarium and praseodymium formates and acetates were synthesized and characterized in view of their use as precursors for the formation of bismuth- or lanthanide-based molybdate catalysts upon controlled thermal decomposition on MoO3 support. Mixed Bi-Ln carboxylates were prepared

  合成了几种铋 (III) 羧酸盐（甲酸盐、乙酸盐、丙酸盐、草酸盐、乳酸盐）和类似的三价镧、钐和镨甲酸盐和乙酸盐，并根据它们作为形成铋或镧系元素的前体的用途进行了表征MoO3 载体上受控热分解的钼酸盐催化剂。制备了混合的 Bi-Ln 羧酸盐并同时用作 Ln 促进的钼酸铋催化剂的前体。发现镧系元素的性质和煅烧温度决定了特定钼酸盐型相在载体上的形成。通过 X 射线衍射和 FTIR 光谱对这些催化剂进行详细检查，确定了在 823 K 下煅烧的含 Bi 和 Pr 样品中的 α-M(2)Mo(3)O(12) 相，
• Outstanding fluoride removal from aqueous solution by a La-based adsorbent
  作者：Weisen Yang、Fengshuo Shi、Wenlong Jiang、Yuhuang Chen、Kaiyin Zhang、Shaoju Jian、Shaohua Jiang、Chunmei Zhang、Jiapeng Hu

  DOI：10.1039/d2ra06284d

  日期：——

  A La-based adsorbent was prepared with La(NO₃)₃·6H₂O, 2-methylimidazole and DMF via amide-hydrolysis and used for fluoride decontamination from aqueous water.

  通过酰胺水解法利用 La(NO3)3-6H2O、2-甲基咪唑和 DMF 制备了一种 La 基吸附剂，并将其用于去除水体中的氟化物。
• Origin of organic gaseous products formed in the thermal decomposition of formates
  作者：A. Górski、A. Kraśnicka

  DOI：10.1007/bf01905178

  日期：1987.7
• A novel family of lanthanide complexes associating two ligands, glycolate and carbonate. Synthesis and characterization of Ln2 (H3C2O3) 4 (CO3) with Ln (III) = La, Ce and Nd
  作者：J.C. Trombe、S. Roméro、A. Mosset

  DOI：10.1016/s0277-5387(98)00012-6

  日期：1998.7

  New lanthanide complexes involving the two ligands, glycolate and carbonate, have been prepared, as a pure phase, by reacting an aqueous suspension of the corresponding lanthanide formate and glycolic acid in closed reactor, under autogeneous pressure at 200 degrees C for one month. The structure of these compounds was determined from single-crystal X-ray method on neodymium complex. It crystallizes in the monoclinic system (space group P2(1)/n) with a three-dimensional framework structure. The coordination scheme of the two independent neodymium atoms is built up by 9 or 10 oxygen atoms from both glycolate and carbonate ligands. The carbonate group acts as a bismonodentate, bischelating ligand. One glycolate is bischelating while the three latter are chelating and monodentate. Infrared spectrum and thermogravimetric analysis of this family are also presented. A tentative explanation of its synthesis will be briefly discussed. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.