3-(3,7-dimethyloctyloxy)-bromobenzene | 209347-65-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-(3,7-dimethyloctyloxy)-bromobenzene
• 英文别名: 3-(3,7-dimethyloctyloxy)bromobenzene；1-bromo-3-(3,7-dimethyloctoxy)benzene
• CAS: 209347-65-9
• 化学式: C₁₆H₂₅BrO
• 分子量: 313.278
• InChiKey: WQSADWAWXNKZCN-UHFFFAOYSA-N

物化性质

• 沸点：
  347.5±15.0 °C(Predicted)
• 密度：
  1.123±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-(3,7-dimethyloctyloxy)-bromobenzene 在 碘 、 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 2.83h， 生成 C₁₆H₂₅BrMgO
  参考文献：
  名称：

  New polymer and polymer light-emitting device using the same

  摘要：

  提供的是一种聚合物，其包含由公式（1）表示的重复单元，其中，A1表示具有结合距离比（C（α）-A1的结合距离/C（α）-C（β）的结合距离）为1.10或更高的二价基团; R1、R2、R3、R4、R5和R6各自独立地表示氢原子、烷基、烷氧基、芳氧基、芳基烷氧基等。该聚合物可用作发光材料、电荷传输材料等。

  公开号：

  US20050042195A1
• 作为产物：
  描述：

  1-chloro-3,7-dimethyloctane 在 氢氧化钾 作用下， 以 乙醇 、 乙酸乙酯 、 sodium iodide 为溶剂， 生成 3-(3,7-dimethyloctyloxy)-bromobenzene
  参考文献：
  名称：

  Polymerizable biaryls, method for the production and use thereof

  摘要：

  制备可聚合的联苯衍生物的方法包括将具有1,4位上酯基或苄羟基的6元环芳香化合物与第二芳香化合物在钯催化的交叉偶联反应中反应，形成联苯，并将酯基或苄羟基转化为一个或多个步骤中的可聚合基团。所得的联苯适用于制备用作电致发光材料的聚合物。

  公开号：

  US06323373B1

文献信息

• Substituted poly(arylene vinylenes), method for producing the same, and their use in electroluminescent elements
  申请人：——

  公开号：US20020064680A1

  公开（公告）日：2002-05-30

  Poly(arylenevinylenes) comprising at least 20% of recurring units of the formula (I), 1 where the symbols and indices have the following meanings: Aryl: is an aryl group having 4 to 14 carbon atoms; R′: is a substituent which is either in the labeled phenylene position 5 or 6 and is CN, F, Cl, N(R 1 R 2 ) or a straight-chain, branched or cyclic alkyl, alkoxy or thioalkoxy group having 1 to 20 carbon atoms, in which, in addition, one or more H atoms may be replaced by F; R″: are identical or different and are CN, F, Cl or a straight-chain, branched or cyclic alkyl or alkoxy group having 1 to 20 carbon atoms, where one or more non-adjacent CH 2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR 1 —, —(NR 2 R 3 ) + —A − or —CONR 4 —, and where one or more H atoms may be replaced by F, or an aryl group having 4 to 14 carbon atoms, which may be substituted by one or more non-aromatic radicals R′; R 1 , R 2 , R 3 , R 4 are identical or different and are H or an aliphatic or aromatic hydrocarbon radical having 1 to 20 carbon atoms; A − : is a singly charged anion or an equivalent thereof; and n: is 0, 1, 2, 3, 4 or 5, are suitable as electroluminescent materials.

  聚芳烃乙烯基化合物包含至少20％的重复单元，其化学式为（I），其中符号和指数具有以下含义：芳基：是具有4至14个碳原子的芳基基团；R'：是一个取代基，它位于标记的苯基位置5或6，并且是CN，F，Cl，N（R1R2）或直链，支链或环状烷基，烷氧基或硫代烷氧基基团，具有1至20个碳原子，在其中，另外一个或多个H原子可以被F取代；R″：相同或不同，并且是CN，F，Cl或直链，支链或环状烷基或烷氧基基团，具有1至20个碳原子，其中一个或多个非相邻的CH2基团可以被—O—，—S—，—CO—，—COO—，—O—CO—，—NR1—，—（NR2R3）+—A−或—CONR4—取代，其中一个或多个H原子可以被F取代，或者是具有4至14个碳原子的芳基基团，它可以被一个或多个非芳香基团R'取代；R1，R2，R3，R4相同或不同，是H或具有1至20个碳原子的脂肪族或芳香族烃基；A−：是单价阴离子或其当量；n：为0，1，2，3，4或5，适用作电致发光材料。
• Substituted poly(arylenevinylenes), process for their preparation, and their use in electroluminescent elements
  申请人：——

  公开号：US20030088050A1

  公开（公告）日：2003-05-08

  Poly(arylenevinylenes) comprising at least 20% of recurring units of the formula (I), 1 where the symbols and indices have the following meanings: Aryl: is an aryl group having 4 to 14 carbon atoms; R′: is a substituent which is either in the labeled phenylene position 5 or 6 and is CN, F, Cl, N(R 1 R 2 ) or a straight-chain, branched or cyclic alkyl, alkoxy or thioalkoxy group having 1 to 20 carbon atoms, in which, in addition, one or more H atoms may be replaced by F; R″: are identical or different and are CN, F, Cl or a straight-chain, branched or cyclic alkyl or alkoxy group having 1 to 20 carbon atoms, where one or more non-adjacent CH 2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR 1 —, —(NR 2 R 3 ) + -A − or —CONR 4 —, and where one or more H atoms may be replaced by F, or an aryl group having 4 to 14 carbon atoms, which may be substituted by one or more non-aromatic radicals R′; R 1 , R 2 , R 3 , R 4 are identical or different and are H or an aliphatic or aromatic hydrocarbon radical having 1 to 20 carbon atoms; A − : is a singly charged anion or an equivalent thereof; and n: is 0, 1, 2, 3, 4 or 5. are suitable as electroluminescent materials.

  聚(芳基烯乙烯)至少包含公式(I)中的重复单位的20％，其中符号和指数具有以下含义：芳基：是具有4到14个碳原子的芳基基团；R′：是取代基，可以在标记的苯基位置5或6，并且是CN，F，Cl，N（R1R2）或具有1到20个碳原子的直链，支链或环状烷基，烷氧基或硫代烷氧基，其中，此外，一个或多个H原子可以被F取代；R″：相同或不同，是CN，F，Cl或具有1到20个碳原子的直链，支链或环状烷基或烷氧基，其中一个或多个非相邻CH2基团可以被—O—，—S—，—CO—，—COO—，—O—CO—，—NR1—，—（NR2R3）+—A−或—CONR4—取代，其中一个或多个H原子可以被F取代，或具有4到14个碳原子的芳基基团，可以被一个或多个非芳香基团R′取代；R1，R2，R3，R4相同或不同，是H或具有1到20个碳原子的脂肪族或芳香族碳氢基；A−：是单价阴离子或其等效物；n：为0，1，2，3，4或5。适用作电致发光材料。
• Polymerizable biaryls, process for their preparation and their use
  申请人：——

  公开号：US20020087030A1

  公开（公告）日：2002-07-04

  A process for preparing polymerizable biaryl derivatives comprises reacting an aromatic comprising a 6-membered ring which bears ester or benzylic OH groups in the 1,4 position with a second aromatic in a palladium-catalyzed cross-coupling reaction to give a biaryl and converting the ester or benzylic OH groups into polymerizable groups in one or more steps. The biaryls obtained are suitable for preparing polymers which are used as electroluminescence materials.

  一种制备可聚合的双芳基衍生物的过程包括将含有酯基或苄基羟基的6元环芳香烃与第二个芳香烃在钯催化的交叉偶联反应中反应，得到双芳基，并在一个或多个步骤中将酯基或苄基羟基转化为可聚合基团。所得到的双芳基适用于制备作为电致发光材料的聚合物。
• Polymer thin and polymer thin film device using same
  申请人：Ueda Masato

  公开号：US20060043358A1

  公开（公告）日：2006-03-02

  The present invention relates to a polymer film comprising a polymer having liquid crystallinity, having a number-average molecular weight in terms of polystyrene of 10 3 to 10 8 and having an electron mobility or hole mobility of 10 −5 cm 2 /Vs or more, and having a film thickness in the range from 1 nm to 100 μm. This polymer film can be used for various polymer film devices such as an organic transistor, organic solar battery, optical sensor, electrophotographic photoreceptor, spatial light modulator, photorefractive device and the like.

  本发明涉及一种聚合物薄膜，包括具有液晶性的聚合物，以聚苯乙烯为标准的数量平均分子量为103至108，并具有电子迁移率或空穴迁移率为10-5cm2/Vs或更高，并具有1nm至100μm范围内的薄膜厚度。该聚合物薄膜可用于各种聚合物薄膜器件，例如有机晶体管、有机太阳能电池、光学传感器、电子照相感光鼓、空间光调制器、光折变器件等。
• Aryl-substituted poly (p-arylene-vinylenes), process for their preparation and their use in electroluminescence components
  申请人：Hoechst Aktiengesellschaft

  公开号：US06458909B1

  公开（公告）日：2002-10-01

  Poly(p-arylene-vinylenes) comprising repeating units of the formula (I), where the symbols and indices have the following meanings: Y1, Y2, Y3: identical or different, CH, N; Aryl: an aryl group having from 4 to 14 carbon atoms; R′, R″: identical or different, each a straight-chain or branched or cyclic alkyl or alkoxy group having from 1 to 20 carbon atoms, where one or more non-adjacent CH2 groups may be replaced by —O—, —S—, —CO—, —COO—, —O—CO—, —NR1—, —(NR2R3)+—A−, or —CONR4— and one or more H atoms may be replaced by F, or else CN, F, Cl or an aryl group having from 4 to 14 carbon atoms which may be substituted by one or more nonaromatic radicals R′; R1, R2, R3, R4: identical or different, aliphatic or aromatic hydrocarbon radicals having from 1 to 20 carbon atoms or else H; A−: a singly charged anion or its equivalent; m: 0, 1 or 2; n: 1, 2, 3, 4 or 5; are suitable as electroluminescence materials.

  聚(p-芳烃-乙烯基)是由公式(I)的重复单元组成的，其中符号和指数具有以下含义：Y1、Y2、Y3：相同或不同，为CH、N；Aryl：具有4至14个碳原子的芳基基团；R′、R″：相同或不同，为直链、支链或环状烷基或烷氧基，具有1至20个碳原子，其中一个或多个非相邻的CH2基团可被替换为—O—、—S—、—CO—、—COO—、—O—CO—、—NR1—、—(NR2R3)+—A−或—CONR4—，一个或多个H原子可被F替换，或者是CN、F、Cl或具有4至14个碳原子的芳基，其可被一个或多个非芳香基团R′取代；R1、R2、R3、R4：相同或不同，为具有1至20个碳原子的脂肪族或芳香族碳氢基团，或者是H；A−：是单电荷阴离子或其等价物；m：为0、1或2；n：为1、2、3、4或5；这些材料适用于电致发光材料。