1-(2-allyl-phenoxy)-2-vinyloxy-ethane | 89037-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(2-allyl-phenoxy)-2-vinyloxy-ethane
• 英文别名: 1-(2-Allyl-phenoxy)-2-vinyloxy-aethan；1-[2-(Ethenyloxy)ethoxy]-2-(prop-2-EN-1-YL)benzene；1-(2-ethenoxyethoxy)-2-prop-2-enylbenzene
• CAS: 89037-84-3
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.269
• InChiKey: SXXCIJGUIQBYHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-烯丙基酚 、 2-氯乙基乙烯基醚 在 sodium hydroxide 作用下， 生成 1-(2-allyl-phenoxy)-2-vinyloxy-ethane
  参考文献：
  名称：

  Two-stage Polymerizations. III. Infrared Evidence for the Course of Polymerization of Vinyl Ethers of Unsaturated Phenols¹

  摘要：

  DOI：

  10.1021/ja01607a080

文献信息

• ALDIMINES AND COMPOSITIONS COMPRISING ALDIMINE
  申请人：Burckhardt Urs

  公开号：US20100101455A1

  公开（公告）日：2010-04-29

  The present invention relates in a first consideration to aldimines of formula (I). Said aldimines are particularly suitable as latent hardeners in curable compositions, particularly compositions comprising one or two-component isocyanate groups. Due to the presence of the reactive group, they can be converted to compounds of the formulas (X) and (XII) comprising aldimine groups, implementing a further consideration of the present invention. The aldimines, or the compounds comprising aldimine groups, can be used primarily in adhesive and sealant materials, but also in coatings, and can be produced easily from readily available source materials, and have good thermal stability. The tertiary amino group thereof has a surprisingly low alkalinity and can in some cases have a catalytic effect in chemical reaction systems.

  本发明涉及公式(I)的醛胺，首先考虑这些醛胺作为可固化组合物的潜在固化剂，特别是含有一种或两种异氰酸基团的组合物。由于具有反应性基团，它们可以转化为公式(X)和(XII)的化合物，包括醛胺基团，这是本发明的进一步考虑。这些醛胺或含有醛胺基团的化合物主要可用于粘合剂和密封材料，也可用于涂料，并且可以从易得的原料中轻松制备，并具有良好的热稳定性。其中的三级氨基具有惊人的低碱度，在某些情况下可以在化学反应系统中具有催化作用。
• Method for the prevention of mist formation in a device comprising rolls during the coating of flexible media with a crosslinkable liquid silicone composition
  申请人：ELKEM SILICONES FRANCE SAS

  公开号：US11078379B2

  公开（公告）日：2021-08-03

  Approaches are described for coating various flexible media, such as sheets of paper, synthetic polymer (polyolefin, polyester, etc.) sheets or fabric sheets, with a silicone on high-speed rolls. For example, an efficient method is described for minimizing and/or reducing mist formation when coating flexible supports with a liquid silicone composition precursor of crosslinked coatings. The coating process can be performed using a coating device that includes a roll operating at a high speed.

  本文介绍了在高速辊上用有机硅涂覆各种柔性介质（如纸张、合成聚合物（聚烯烃、聚酯等）薄片或织物薄片）的方法。例如，在用交联涂料的液态硅酮组合物前驱体涂覆柔性支撑物时，描述了一种最大限度减少和/或降低雾气形成的有效方法。涂布过程可使用涂布装置进行，该装置包括一个高速运转的辊子。
• Use of silicone compositions crosslinkable by the cationic route under UV radiation and of a photoinitiator of the onium borate type for coatings for sheet gaskets, in particular cylinder head gaskets
  申请人：——

  公开号：US20030050418A1

  公开（公告）日：2003-03-13

  The invention concerns the use of cross-linkable silicone compositions for fast, economical and simple impregnation and/or varnishing of flat joints (e.g. cylinder head gaskets). More precisely it concerns the use of silicone compositions cross-linkable under UV radiation, by cationic process and in the presence of specific phoinitiators selected among onium borates or organometallic complexes, of which the borate counter-anions contain at least a boron bound to at least a substituted phenyl (Me, F). The silicone liquid precursor is a polydimethylsiloxane (PDMS) substituted by cross-linking functional groups, by cationic process (G f p ) under UV of the epoxy or vinyloxy type. These G f p are present at the rate of 0.15 to 2.0 pr kg of PDMS. The invention also relates to the method for impregnating/varnishing flat joints (e.g. cylinder head gaskets) using the specific PDMS composition+photoinitiator of borate type as well as the treated joints and the composition themselves.

  本发明涉及使用可交联的有机硅组合物，对平面接头（如汽缸盖垫片）进行快速、经济和简单的浸渍和/或上光。更确切地说，它涉及在紫外线辐射下，通过阳离子工艺，在特定的硼酸鎓或有机金属络合物（其中硼酸反离子至少含有一个与至少一个取代苯基（Me，F）结合的硼元素）存在的情况下，使用可交联的有机硅组合物。硅酮液前驱体是由交联官能团取代的聚二甲基硅氧烷（PDMS），通过阳离子工艺（G f p ）在紫外线下进行环氧或乙烯基氧基类型的交联。这些 G f p 的含量为 0.15 至 2.0 pr kg PDMS。本发明还涉及使用特定 PDMS 组合物和硼酸盐型光引发剂浸渍/上光平面接头（如气缸盖垫片）的方法，以及处理过的接头和组合物本身。
• Silicone/adhesive complex whereof the interface has a release force capable of being modulated by electron beam irradiation
  申请人：——

  公开号：US20030186013A1

  公开（公告）日：2003-10-02

  The invention concerns a silicone/adhesive complex comprising at least a silicone coating applied on a first support and an adhesive coating applied on a second support and whereof the release force of a silicone/adhesive interface is capable of being modulated. The invention is characterised in that its silicone coating is derived from polymerisation and/or crosslinking of polyorganosiloxane monomers, oligomers and/or polymers and said silicone coating further comprises at least an additive regulating the release force of a silicone/adhesive interface and whereof the activity is initiated and capable of being modulated by electron beam irradiation.

  本发明涉及一种硅胶/粘合剂复合物，至少包括涂在第一支撑物上的硅胶涂层和涂在第二支撑物上的粘合剂涂层，其中硅胶/粘合剂界面的释放力可以调节。本发明的特征在于其有机硅涂层是由聚有机硅氧烷单体、低聚物和/或聚合物聚合和/或交联而成，所述有机硅涂层还包括至少一种可调节有机硅/粘合剂界面释放力的添加剂，其活性可通过电子束辐照启动和调节。
• Silicone composition used in the production of antifriction varnishes, method for the application of said varnishes to a support and support thus treated
  申请人：Bertry Jean-Louis

  公开号：US20050037210A1

  公开（公告）日：2005-02-17

  The invention relates to silicone compositions that are used in the production of varnishes that can be applied to supports in order to reduce the friction coefficient. The inventive composition comprises at least one polyorganosiloxane A (POS) which can be cationically and radically cross-linked by functional cross-linking groups (GFR) and a primer C chosen from onium borates, charcterised in that the inventive composition also comprises molecules (POS D) which are substituted by secondary functional groups (GFS) carried by silicon atoms and selected from those that include at least one alkoxy and/or epoxy and/or carboxy motif and optionally a charge (e.g. silica). The invention can be used with anti-friction varnishes for RTV silicone coatings for material used in air bags, thermal transfer ribbons or packing films.

  本发明涉及用于生产清漆的有机硅组合物，该清漆可涂在支撑物上以降低摩擦系数。本发明的组合物包括至少一种聚有机硅氧烷 A（POS），该聚有机硅氧烷可通过功能交联基团（GFR）进行阳离子和辐射交联，以及一种选自硼酸铈的底漆 C，其特征在于本发明的组合物还包括由硅原子携带的仲官能团（GFS）取代的分子（POS D），这些分子选自包括至少一个烷氧基和/或环氧基和/或羧基基团以及可选电荷（如二氧化硅）的分子。本发明可与抗摩擦清漆一起用于气袋、热转印带或包装膜材料的 RTV 硅涂层。