3-(1H,1H,9H-十六氟壬氧基)-1,2-环氧丙烷 | 125370-60-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 3-(1H,1H,9H-十六氟壬氧基)-1,2-环氧丙烷
• 中文别名: 缩水甘油醚十六氟壬基醚
• 英文名称: 2-{[(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-Hexadecafluorononyl)oxy]methyl}oxirane
• 英文别名: 2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorononoxymethyl)oxirane
• CAS: 125370-60-7
• 化学式: C₁₂H₈F₁₆O₂
• mdl: MFCD00236091
• 分子量: 488.16
• InChiKey: AVKVPTNDWAGIMH-UHFFFAOYSA-N

物化性质

• 沸点：
  251 °C(lit.)
• 密度：
  1.682 g/mL at 25 °C(lit.)
• 闪点：
  >230 °F
• 稳定性/保质期：

  如果按照规格使用和储存，则不会分解，也未有已知危险反应。

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  30
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  18

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38
• WGK Germany：
  3

文献信息

• [EN] METHOD FOR PREPARING SILICON-CONTAINING HETEROCYCLES<br/>[FR] PROCÉDÉ DE PRÉPARATION D'HÉTÉROCYCLES CONTENANT DU SILICIUM
  申请人：HENKEL AG & CO KGAA

  公开号：WO2019015809A1

  公开（公告）日：2019-01-24

  The present invention relates to a method for preparing silicon-containing heterocycles of the general formula (I), wherein R1 is hydrogen; R2 and R3 are same or different and are, independently from one another, selected from a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6-C18 aryl residue which may be interrupted by at least one heteroatom; R4 is selected from a linear or branched C1-C20 alkylene residue which may be interrupted by at least one heteroatom; R5 and R6 are same or different and are, independently from one another, selected from the group consisting of hydrogen, a linear or branched, substituted or unsubstituted C1-C20 alkyl or C6- C18 aryl which may be interrupted by at least one heteroatom, and a C4-C8 cycloalkyl, or R5 and R6 may form a ring, preferably a 4- to 8-membered alkyl ring; and n is 0, 1 or 2, preferably 2, said method comprising a one-step reaction of at least one epoxide compound of the general formula (II) and at least one aminoalkoxysilane having a primary amino group in the presence of a catalyst formula (II), wherein R5 and R6 are the same as defined for the general formula (I) above; as well as the use of the silicon-containing heterocycles of the general formula (I).

  本发明涉及一种制备通式（I）中含硅杂环化合物的方法，其中R1为氢；R2和R3相同或不同，分别选择自一种线性或支链的取代或未取代的C1-C20烷基或C6-C18芳基残基，其可以被至少一个杂原子中断；R4选择自一种线性或支链的C1-C20烷基残基，其可以被至少一个杂原子中断；R5和R6相同或不同，分别选择自氢、一种线性或支链的取代或未取代的C1-C20烷基或C6-C18芳基，其可以被至少一个杂原子中断，以及一种C4-C8环烷基，或者R5和R6可以形成环，优选为4-至8-成员烷基环；n为0、1或2，优选为2，所述方法包括在催化剂的存在下，至少一种通式（II）的环氧化合物和至少一种具有主要氨基团的氨基烷氧基硅烷的一步反应，其中R5和R6与上述通式（I）中定义的相同；以及使用通式（I）中的含硅杂环化合物。
• SYNTHESIS OF CYCLIC TRITHIOCARBONATES FROM EPOXIDES
  申请人：Parker Kenton Dane

  公开号：US20060004210A1

  公开（公告）日：2006-01-05

  This invention provides a low cost technique for synthesizing cyclic trithiocarbonates by a simple one step process from epoxides that can be conducted under atmospheric pressure. This synthesis can be depicted as follows: wherein R represents a moiety selected from the group consisting of alkyl groups and aryl groups, wherein R′ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, and wherein R″ represents a moiety selected from the group consisting of alkyl groups, aryl groups, and hydrogen atoms, wherein the R moiety and the R′ moiety can be bonded together to form a cyclic structure, with the proviso that R″ represents a hydrogen atom if R′ represents an alkyl group or an aryl group. In this process carbon disulfide and a thiocyanate salt, such as potassium thiocyanate, are reacted with the epoxide in an ionic liquid, such as 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF 6 ) in the presence of water to produce the cyclic trithiocarbonate.

  这项发明提供了一种低成本的技术，通过简单的一步法从环氧化物合成环状三硫代碳酸酯，可以在大气压下进行。该合成可表示为：其中R代表从烷基和芳基组成的基团，R'代表从烷基、芳基和氢原子组成的基团，R''代表从烷基、芳基和氢原子组成的基团，其中R基团和R'基团可以结合形成环状结构，但前提是如果R'代表烷基或芳基，则R''代表氢原子。在该过程中，二硫化碳和硫氰酸盐（如硫氰酸钾）与环氧化物在离子液体（如1-丁基-3-甲基咪唑六氟磷酸盐[Bmim] PF6）中在水的存在下反应，生成环状三硫代碳酸酯。
• Process for producing polyether
  申请人：Miyanaga Seiichi

  公开号：US20050004344A1

  公开（公告）日：2005-01-06

  The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L 1 , L 2 and L 3 are same as or different from each other and each of them represents an oxygen-binding ligand.

  本发明提供了一种高效获得高聚度聚醚的方法，通过简单地聚合很难或迄今为止不能得到高聚度的取代环氧化物来提供高聚度聚醚。也就是说，通过在稀土金属化合物(I)和还原化合物的存在下，开环聚合至少一种取代环氧化物（丙烯酸丙烯酯和环氧氯丙烷除外）来获得聚醚：其中，M代表从Sc、Y和镧系元素中选择的稀土元素，L1、L2和L3相同或不同，每个代表一个氧结合配体。
• Polyesters modified with polymers of alkylene oxids
  申请人：The B.F. GOODRICH Company

  公开号：EP0147758A2

  公开（公告）日：1985-07-10

  Thermoplastic compositions comprising blends of at least one thermoplastic solid polyester resin and at least one liquid homopolymer or copolymer of epihalohydrin wherein the copolymers contain at least 80% by weight of polymerized units of an epihalohydrin, said compositions being fusible on cooling and possessing exceptional property of rapid dissipation of electrical charge.

  热塑性组合物，包括至少一种热塑性固体聚酯树脂和至少一种表卤醇的液态均聚物或共聚物的混合物，其中共聚物含有至少 80% 的表卤醇聚合单元（按重量计），所述组合物在冷却时可熔化，并具有快速消散电荷的特殊性能。
• Catalyst component for the polymerisation of olefins and process for preparing olefin polymers using same
  申请人：NIPPON OIL COMPANY, LIMITED

  公开号：EP0587440A2

  公开（公告）日：1994-03-16

  A catalyst component for use in the polymerization or copolymerization of olefin(s) is obtained by contacting the following components (1) to (4) with one another: (1) a compound of the general formula Me¹R¹p(OR²)qX¹4-p-q where R¹ is a hydrocarbon radical having 1 to 24 carbon atoms, X¹ is a halogen atom, Me¹ is Zr, Ti or Hf, and n is 0 ≦ n ≦ 4; (2) a compound of the general formula Me²R³m(OR⁴)nX²z-m-n where R² is a hydrocarbon radical having 1 to 24 carbon atoms, X² is a halogen atom, Me² is an element from Groups I to III in the Periodic Table, z is the valence of Me² and m is 0 ≦ m ≦ z; (3) an organocyclic compound having two or more conjugated double bonds; and (4) a modified organoaluminum compound containing Al-O-Al bond and with at least one branched-chain alkyl group being attached to aluminum atom.

  将下列组分（1）至（4）相互接触，可得到用于烯烃聚合或共聚的催化剂组分： (1) 通式为 Me¹R¹p(OR²)qX¹4-p-q的化合物 其中，R¹为具有 1 至 24 个碳原子的烃基；X¹为卤素原子；Me¹为 Zr、Ti 或 Hf；n 为 0 ≦ n ≦ 4； (2) 通式为 Me²R³m(OR⁴)nX²z-m-n的化合物，其中 R²为具有 1 至 24 个碳原子的烃基；X²为卤素原子；Me²为元素周期表中第 I 至 III 族的元素；z 为 Me²的化合价；m 为 0 ≦ m ≦ z； (3) 具有兩個或以上共轭双键的有机环化合物；及 (4) 含 Al-O-Al 键且至少有一个支链烷基与铝原子相连的改性有机铝化合物。