3-(2,4-二溴苯氧基)-2-羟基丙基丙烯酸酯 | 92816-23-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 3-(2,4-二溴苯氧基)-2-羟基丙基丙烯酸酯
• 英文名称: 3-(2,4-Dibromophenoxy)-2-hydroxypropyl acrylate
• 英文别名: [3-(2,4-dibromophenoxy)-2-hydroxypropyl] prop-2-enoate
• CAS: 92816-23-4
• 化学式: C₁₂H₁₂Br₂O₄
• 分子量: 380.03
• InChiKey: VZDQBADMMJDJES-UHFFFAOYSA-N

物化性质

• 沸点：
  475.2±45.0 °C(Predicted)
• 密度：
  1.690±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• Resin material for plastic lens and lens composed thereof
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0134861A1

  公开（公告）日：1985-03-27

  A polymer having a high refractive index is obtained by polymerizing a urethanized acrylic or methacrylic monomer obtained by reacting the hydroxyl group of an acrylic or methacrylic monomer having a nucleus-halogen-substituted aromatic ring and a hydroxyl group with the isocyanate group of a polyfunctional isocyanate. This polymer is valuable as a resin material for a plastic lens.

  一种具有高折射率的聚合物是通过聚合尿烷化丙烯酸或甲基丙烯酸单体而获得的，这种单体是由具有核-卤代芳香环和羟基的丙烯酸或甲基丙烯酸单体的羟基与多官能异氰酸酯的异氰酸酯基反应而获得的。这种聚合物可作为塑料镜片的树脂材料。
• Hard transparent resins and process for the production thereof
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0345748A2

  公开（公告）日：1989-12-13

  The present invention relates to a process for preparing a hard transparent resin comprising polymerizing a monomer (A) having both a functional group of the following formula (I): wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and a functional group selected from the group consisting of a functional group of the formula (II): CH2CR-COO- (II) wherein R is selected from the group consisting of hydrogen and methyl group, and a functional group of the formula (III): The invention also provides a process for preparing a transparent resin comprising copolymerizing monomer (A) with a monomer (B) having at least one functional group selected from the group consisting of CH2CH=COO-, CH2 = C(CH3)-COO-, and This resin can be suitably used as a glazing material, and in the manufacture of optical lenses, optical information recording medium substrates, etc. It has a crosslinked structure, high surface hardness, and may be easily polymerized.

  本发明涉及一种制备硬质透明树脂的工艺，包括聚合具有下式（I）官能团的单体（A）： 其中 X 选自由氧原子和硫原子组成的组、 和一个从式（II）官能团组成的组中选出的官能团： CR-COO- (II) 其中 R 选自氢和甲基组成的组、 和一个式 (III) 的官能团： 本发明还提供了一种制备透明树脂的工艺，该工艺包括将单体（A）与单体（B）共聚，单体（B）具有至少一个选自由 CH=COO- 组成的组的官能团、 CH2 = C（CH3）-COO-，以及 这种树脂可用作上光材料，也可用于制造光学镜片、光学信息记录介质基板等。它具有交联结构，表面硬度高，易于聚合。
• Photochromic compound, composition and use thereof
  申请人：TOKUYAMA CORPORATION

  公开号：EP0449669A1

  公开（公告）日：1991-10-02

  Spiroxazines of formula (I) wherein R1 and R2 are the same or different and each is alkyl of 1 to 20 carbon atoms, or R1 and R2 together with the carbon to which both R1 and R2 are bonded form a cycloalkyl ring, a bicycloalkyl ring or a tricycloalkyl ring ; R3 is alkyl of 1 to 10 carbon atoms, aryl of 6 to 10 carbon atoms, aralkyl of 7 to 14 carbon atoms, cyanoalkyl wherein the alkyl group has 1 to 10 carbon atoms, or alkoxycarbonylalkyl wherein the alkoxy group has 1 to 10 carbon atoms and the alkylene group has 1 to 10 carbon atoms; R4 and R5 are the same or different and each is hydrogen, halogen, alkyl of 1 to 10 carbon atoms, aryl of 6 to 10 carbon atoms, aralkyl of 7 to 14 carbon atoms, alkoxy of 1 to 10 carbon atoms, cyano, halogenoalkyl of 1 to 4 carbon atoms, amino,mono- or di-subsfituted amino, cyclic amino, alkoxycarbonyl wherein the alkoxy group has 1 to 5 carbon atoms, or a monocyclic heterocydyl group having 5 or 6 ring atoms including one ring nitrogen ; is a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted unsaturated heterocyclic group wherein each substituent is selected from halogen, hydroxyl, cyano, nitro, alkyl of 1 to 20 carbon atoms, alkoxy of 1 to 20 carbon atoms, aryl of 6 to 10 carbon atoms, alkylamino of 1 to 4 carbon atoms, dialkylamino having 1 to 4 carbon atoms in each alkyl group, halogenoalkyl of 1 to 4 carbon atoms, monocyclic heterocyclic group having 5 or 6 ring atoms, aralkyl of 7 to 14 carbon atoms and alkoxycarbonyl of 1 to 5 carbon atoms, and is a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted unsaturated heterocyclic group wherein each substituent is selected from halogen, cyano, nitro, alkyl of 1 to 20 carbon atoms, alkoxy of 1 to 20 carbon atoms, amino or dialkylamino having 1 to 4 carbon atoms in each alkyl group provided that, when R1 and R2 are both methyl, is a substituted or unsubstituted fused polycyclic aromatic hydrocarbon group are photochromic and may be used in photochromic lenses.

  式（I）的螺螨酯 其中 R1 和 R2 相同或不同，各自为 1 至 20 个碳原子的烷基，或 R1 和 R2 与 R1 和 R2 键合的碳一起形成环烷基环、双环烷基环或三环烷基环； R3 是 1 至 10 个碳原子的烷基、6 至 10 个碳原子的芳基、7 至 14 个碳原子的芳烷基、氰基烷基（其中烷基具有 1 至 10 个碳原子）或烷氧基羰基烷基（其中烷氧基具有 1 至 10 个碳原子，亚烷基具有 1 至 10 个碳原子）； R4 和 R5 相同或不同，各自为氢、卤素、1 至 10 个碳原子的烷基、6 至 10 个碳原子的芳基、7 至 14 个碳原子的芳烷基、1 至 10 个碳原子的烷氧基、氰基、1 至 4 个碳原子的卤代烷基、氨基、单或双亚氨基、环氨基、烷氧基为 1 至 5 个碳原子的烷氧羰基或具有 5 或 6 个环原子（包括一个环氮）的单环杂环基； 是取代或未取代的芳香烃基团或取代或未取代的不饱和杂环基团，其中每个取代基都选自卤素、羟基、氰基、硝基、1 至 20 个碳原子的烷基、1 至 20 个碳原子的烷氧基、6 至 10 个碳原子的芳基、1 至 4 个碳原子的烷基氨基、每个烷基中含有 1 至 4 个碳原子的二烷基氨基、1 至 4 个碳原子的卤代烷基、具有 5 或 6 个环原子的单环杂环基团、7 至 14 个碳原子的芳烷基和 1 至 5 个碳原子的烷氧羰基，以及 是取代或未取代的芳香烃基团或取代或未取代的不饱和杂环基团，其中每个取代基均选自卤素、氰基、硝基、1 至 20 个碳原子的烷基、1 至 20 个碳原子的烷氧基、氨基或每个烷基中含有 1 至 4 个碳原子的二烷基氨基，但 R1 和 R2 均为甲基时除外、 是取代或未取代的融合多环芳烃基团，具有光致变色作用，可用于光致变色镜片。
• EP0551867A1
  申请人：——

  公开号：EP0551867A1

  公开（公告）日：1993-07-21
• Laminated transparent plastic material and polymerizable monomer
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0551867B1

  公开（公告）日：2000-06-07