1,4-bis(trifluorovinyloxy)benzene | 134130-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(trifluorovinyloxy)benzene
• 英文别名: Benzene, 1,4-bis[(trifluoroethenyl)oxy]-；1,4-bis(1,2,2-trifluoroethenoxy)benzene
• CAS: 134130-25-9
• 化学式: C₁₀H₄F₆O₂
• 分子量: 270.131
• InChiKey: RERAQYMIICCJKF-UHFFFAOYSA-N

物化性质

• 沸点：
  168.6±40.0 °C(Predicted)
• 密度：
  1.424±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,4-bis(2-bromotetrafluoroethoxy)benzene 在 锌 作用下， 以 乙腈 为溶剂， 反应 29.0h， 以54%的产率得到1,4-bis(trifluorovinyloxy)benzene
  参考文献：
  名称：

  Optical Properties of Perfluorocyclobutane Aryl Ether Polymers for Polymer Photonic Devices

  摘要：

  New thermoplastic PFCB aryl ether monomers, 1,5-bis(trifluorovinyloxy)naphthalene (TFVON) and 1,4-bis(trifluorovinyloxy)benzene (TFVOB), were synthesized, and homopolymers, PTFVON and PTFVOB, and a copolymer, TFVON-co-TFVOB, were successfully prepared from them by 2pi + 2pi cyclopolymerization. The C-H vibrational absorption of the monomer was investigated by IR and nearIR spectrum analysis. The optical properties of the polymers in the form of plastic optical fibers and thin films were examined. The absorptions corresponding to fundamental and overtones of C-H vibrations in PFCB monomers were greatly reduced due to the presence of the fluorine substituents, which could lead to low attenuation loss of the resulting polymers in the near-IR region. Polymerization conditions such as temperature and time significantly affected the optical loss values of the polymers as well as their molecular weights and thermal properties. We prepared plastic optical fibers of the PFCB polymers, and optical windows were observed at 820, 910, 1025, 1260, and 1530 run. The attenuation loss of PTFVON was typically 0.083 dB/cm at 910 nm, the lowest optical window, 0.190 dB/cm at 1300 nm, and 0.227 dB/cm at 1550 nm. Copolymerization further reduced optical loss, and optical loss of the copolymer was about 0.03-0.1 dB/cm lower than that of the homopolymer. A birefringence of the spin-coated films of the PFCB polymers was also investigated and found to be exceptionally low. A birefringence of less than 0.001 was found in all the polymers. The lowest birefringence of 0.0005 was measured for PTFVON films.

  DOI：

  10.1021/ma035161c

文献信息

• SULFONATED PERFLUOROCYCLOBUTANE ION-CONDUCTING MEMBRANES
  申请人：3M Innovative Properties Company

  公开号：EP1290041A1

  公开（公告）日：2003-03-12
• PROTON CONDUCTIVE POLYMER ELECTROLYTES AND FUEL CELLS
  申请人：MacKinnon Sean M.

  公开号：US20090281262A1

  公开（公告）日：2009-11-12

  In one embodiment, a copolymer comprises a sulfonatable segment covalently linked to an un-sulfonatable segment through an organic linking group. The sulfonatable group segment may be sulfonated through direction sulfonation or sulfonation through a spacer molecule. In another embodiment, a copolymer comprises a sulfonated segment and an unsulfonated segment. A membrane electrode assembly and a fuel cell may be produced using the copolymer.
• US5540997A
  申请人：——

  公开号：US5540997A

  公开（公告）日：1996-07-30
• US6559237B1
  申请人：——

  公开号：US6559237B1

  公开（公告）日：2003-05-06
• US7897693B2
  申请人：——

  公开号：US7897693B2

  公开（公告）日：2011-03-01