1-p-methoxyphenyl-3,5-diphenylpyrazinium perchlorate | 675198-89-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-p-methoxyphenyl-3,5-diphenylpyrazinium perchlorate
• 英文别名: Pyrazinium, 1-(4-methoxyphenyl)-3,5-diphenyl-, perchlorate；1-(4-methoxyphenyl)-3,5-diphenylpyrazin-1-ium;perchlorate
• CAS: 675198-89-7
• 化学式: C₂₃H₁₉N₂O*ClO₄
• 分子量: 438.867
• InChiKey: FMJIUJIIBSGCCH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.06
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  100
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N,N-diphenacyl-p-anisidine 在 乙酸铵 作用下， 以 溶剂黄146 为溶剂， 反应 2.0h， 以80%的产率得到1-p-methoxyphenyl-3,5-diphenylpyrazinium perchlorate
  参考文献：
  名称：

  Arylaliphatic 3-Aza-1,5-diketones: Reactions with N-Nucleophiles

  摘要：

  1-Substituted 3,5-diphenylpyrazinium salts were obtained by reactions of tertiary bis(phenacyl)amines with ammonium acetate, hydroxylamine hydrochloride, and hydrazine hydrate in acid medium. The reaction of quaternary dimethylbis(phenacyl)ammonium bromide with hydrazine hydrate afforded 3,6-diphenylpyridazine.

  DOI：

  10.1023/b:rujo.0000010226.45434.ab

文献信息

• Arylaliphatic 3-Aza-1,5-diketones: Reactions with N-Nucleophiles
  作者：T. I. Akimova、N. N. Trofimenko、Zh. A. Ivanenko

  DOI：10.1023/b:rujo.0000010226.45434.ab

  日期：2003.9

  1-Substituted 3,5-diphenylpyrazinium salts were obtained by reactions of tertiary bis(phenacyl)amines with ammonium acetate, hydroxylamine hydrochloride, and hydrazine hydrate in acid medium. The reaction of quaternary dimethylbis(phenacyl)ammonium bromide with hydrazine hydrate afforded 3,6-diphenylpyridazine.