[3,4-Diacetyloxy-5-methyl-2-(2,3,5-triacetyloxy-4-methylphenyl)phenyl] acetate | 1186420-77-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [3,4-Diacetyloxy-5-methyl-2-(2,3,5-triacetyloxy-4-methylphenyl)phenyl] acetate
• CAS: 1186420-77-8
• 化学式: C₂₆H₂₆O₁₂
• 分子量: 530.485
• InChiKey: INSMFPCODUQGQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  38
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  158
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  4,4'-二甲基-1,1'-联苯-2,2',5,5'-四酮 、 乙酸酐 在 硫酸 作用下， 生成 [3,4-Diacetyloxy-5-methyl-2-(2,3,5-triacetyloxy-4-methylphenyl)phenyl] acetate 、 2,2',3,3',6,6'-hexaacetoxy-4,4'-dimethyl-1,1'-biphenyl
  参考文献：
  名称：

  Rust disease control by Aphanocladium album and/or Beauveria brongniartii

  摘要：

  本发明揭示了一种用于控制植物锈病的方法和组合物。通过Aphanocladium album真菌寄生体产生的代谢物被提取并以有效量施用于有患锈病风险的植物上。更具体地，代谢物的施用将导致引起锈病的传染性锈子孢子转变为非传染性的子囊孢子。在更具体的方面，这种代谢物与另一种物质或在特定反应条件下反应，形成对锈病也有效的不同化合物。

  公开号：

  US20070110726A1

文献信息

• Rust disease control by Aphanocladium album and/or Beauveria brongniartii
  申请人：Subbiah Ven

  公开号：US20070110726A1

  公开（公告）日：2007-05-17

  There is disclosed a method and composition for controlling rust disease in plants. Metabolites produced by Aphanocladium album mycoparasites are recovered and applied in an effective amount to plants at risk for acquiring rust disease More specifically, the application of the metabolite converts infective urediniospores that cause rust disease into non-infective teliospores. In a more specific aspect, the metabolite is reacted with another substance or under a specific reaction to result in a different compound which is also effective against rust disease.

  本发明揭示了一种用于控制植物锈病的方法和组合物。通过Aphanocladium album真菌寄生体产生的代谢物被提取并以有效量施用于有患锈病风险的植物上。更具体地，代谢物的施用将导致引起锈病的传染性锈子孢子转变为非传染性的子囊孢子。在更具体的方面，这种代谢物与另一种物质或在特定反应条件下反应，形成对锈病也有效的不同化合物。
• An efficient synthesis of oosporein
  作者：Brian E. Love、Jeffrey Bonner-Stewart、Lori A. Forrest

  DOI：10.1016/j.tetlet.2009.06.103

  日期：2009.9

  Fungal metabolite oosporein was prepared in four steps and 24% overall yield starting from 2.5-dimethoxytoluene. It was demonstrated that treatment of phoenicin with pyrrolidine and copper(II) acetate led to oosporein, whereas similar treatment of the isomeric 'isophoenicin' produced a benzofuran diquinone. No chromatography was required during any step of the synthesis. (C) 2009 Elsevier Ltd. All rights reserved.