甲基丙烯酸环氧甲酯与乙烯的聚合物 | 26061-90-5

• 物质功能分类: 催化剂及助剂 - 聚合物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 甲基丙烯酸环氧甲酯与乙烯的聚合物
• 中文别名: 聚(乙烯-CO-甲基丙烯酸缩水甘油酯)
• 英文名称: Ethene;oxiran-2-ylmethyl 2-methylprop-2-enoate
• CAS: 26061-90-5
• 化学式: C9H14O3
• 分子量: 170.21
• InChiKey: CONHAJWVOAJZGC-UHFFFAOYSA-N

物化性质

• 熔点：
  99 °C(lit.)
• 密度：
  0.94 g/mL at 25 °C(lit.)
• 稳定性/保质期：

  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  1.31
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38
• WGK Germany：
  3

制备方法与用途

用途：可交联涂层和助粘剂。

文献信息

• Moisture curable, melt processible graft ethylene copolymers
  申请人：——

  公开号：US20030032728A1

  公开（公告）日：2003-02-13

  The present invention relates to high performance wire and cable compositions and to hot melt adhesives containing a silyl-grafted ethylene copolymer having particularly low levels of glycidyl acrylate monomer. The preferred epoxy glycidyl methacrylate copolymerized into the polymer backbone provides a graft site for the aminosilane. Subsequent moisture crosslinking at the silyl site of the thermally stable graft copolymer provides compositions with attractive physical properties for wire and cable semicons, insulation, and jackets, as well as hot melt adhesives. The preferred aminosilane is N-cyclohexylaminopropyl trimethoxysilane.

  本发明涉及高性能电线电缆组合物和含有具有特别低水平环氧丙烯酸酯单体的硅烷接枝乙烯共聚物的热熔粘合剂。首选的环氧丙烯酸酯共聚物与聚合物骨架共聚提供了氨基硅烷的嫁接位点。在热稳定的接枝共聚物的硅烷位点的随后湿度交联提供了具有吸引力的物理性能的电线电缆半导体、绝缘层和护套，以及热熔粘合剂。首选的氨基硅烷是N-环己基氨丙基三甲氧基硅烷。
• POLY(HYDROXYALKANOIC ACID) PLASTICIZED WITH POLY(TRIMETHYLENE ETHER) GLYCOL
  申请人：Uradnisheck Julius

  公开号：US20110071258A1

  公开（公告）日：2011-03-24

  Toughened, plasticized poly(hydroxyalkanoic acid) polymer compositions comprising poly(trimethylene ether) glycol and ethylene ester copolymers are provided.

  提供了由聚（羟基脂肪酸）塑化的强化聚合物组成物，其中包括聚（三亚甲基醚）乙二醇和乙烯酯共聚物。
• Thermoplastic resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0177151A2

  公开（公告）日：1986-04-09

  A novel thermoplastic resin composition comprising a blend of a resin composition (D) with a copolymer (C) containing epoxy groups, said resin composition (D) being composed of (A) a polypropylene graft-modified by an unsaturated carboxylic acid or anhydride thereof, with or without unmodified polypropylene, and (B) a saturated polyester resin has excellent physical properties and can be used to provide shaped articles, sheets and films having excellent appearance, uniformity and smoothness.

  一种新型热塑性树脂组合物，包括树脂组合物（D）与含有环氧基团的共聚物（C）的混合物，所述树脂组合物（D）由（A）经不饱和羧酸或其酸酐接枝改性的聚丙烯（含或不含未改性聚丙烯）和（B）饱和聚酯树脂组成，具有极佳的物理性能，可用于提供具有极佳外观、均匀性和平滑性的成型物品、板材和薄膜。
• Thermoplastic resin composition and method for preparing the same
  申请人：NIPPON PETROCHEMICALS CO., LTD.

  公开号：EP0338303A2

  公开（公告）日：1989-10-25

  A novel thermoplastic resin composition is here provided which contains (I) 100 parts by weight of a polyoxymethylene resin alone or a mixture of the polyoxymethylene resin and a polycarbonate resin, with (II) 0.1 to 100 parts by weight of a multi-phase structure thermoplastic resin which is composed of 5 to 95% by weight of an epoxy group-containing olefin copolymer and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one kind of vinyl monomer, either of both the components being in the state of a dispersion phase having a particle diameter of 0.001 to 10 µm. Furthermore, a novel method for preparing the above-mentioned thermoplastic resin composition is also provided here.

  本文提供了一种新型热塑性树脂组合物，其中含有 (I) 100 份（按重量计）单独的聚甲醛树脂或聚甲醛树脂与聚碳酸酯树脂的混合物，以及 (II) 0.1 至 100 份（按重量计）多相结构热塑性树脂，该树脂由 5 至 95% （按重量计）的含环氧基团的烯烃共聚物和 95 至 5%（按重量计）的乙烯基聚合物 或由至少一种乙烯基单体生成的共聚物组成，这两种成分中的任何一种都处于粒径为 0.001 至 10 微米的分散相状态。 此外，这里还提供了一种制备上述热塑性树脂组合物的新方法。
• Composition comprising polyarylene sulfide and polyamide
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0495457A2

  公开（公告）日：1992-07-22

  A composition is disclosed, comprising (1) a polyamide as a dispersed phase and (2) a polyarylene sulfide as a continuous phase, wherein at least a part of the polyarylene sulfide has at least one modifying group directly bonded to the aromatic ring thereof, where the modifying group is selected from the group consisting of a carboxyl group, an alkali metal salt of a carboxyl group, and an alkaline earth metal salt of a carboxyl group, and where the modifying group is present at a ratio of 10 or more millimoles of the modifying group per kilogram of the polyamide. The composition has improved mechanical strength.

  公开了一种组合物，其中包括 (1) 作为分散相的聚酰胺和 (2) 作为连续相的聚芳基硫醚、 其中至少一部分聚芳基硫醚具有至少一个直接与芳香环键合的改性基团，改性基团选自由羧基、羧基的碱金属盐和羧基的碱土金属盐组成的组，改性基团的存在比例为每公斤聚酰胺含 10 或更多毫摩尔的改性基团。该组合物具有更好的机械强度。