glycidyl ether of cyclohexane-1,4-dimethanol | 46354-03-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: glycidyl ether of cyclohexane-1,4-dimethanol
• 英文别名: 1,4-Cyclohexanedimethanol glycidyl ether；[4-(oxiran-2-ylmethoxymethyl)cyclohexyl]methanol
• CAS: 46354-03-4
• 化学式: C₁₁H₂₀O₃
• 分子量: 200.278
• InChiKey: YFQPJCUYATWTLO-UHFFFAOYSA-N

物化性质

• 沸点：
  317.5±12.0 °C(Predicted)
• 密度：
  1.058±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  42
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,4-环己烷二甲醇 、 环氧氯丙烷 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成 glycidyl ether of cyclohexane-1,4-dimethanol
  参考文献：
  名称：

  Process for the preparation of adducts of epoxides and alcohols

  摘要：

  一种通过在催化剂存在下将醇与环氧化合物反应制备缩合物的方法，其中包括将式I的醇（其中A是脂肪族、环脂族或芳基脂肪族基团，r为1至10的数字）与单质或双环氧化物以当量比为1:20至20:1的比例，基于羟基和环氧基团，在式II的金属配合物催化剂[M.sup.n+ (L.sub.1).sub.x (L.sub.2).sub.y (L.sub.3.sup.m-).sub.z ][X.sup.k- ].sub.(n-zm)/k (II)存在下反应，其中M是元素周期表主族或亚族的金属，L.sub.1和L.sub.2是弱键合的中性、单或多齿配体，L.sub.3是强键合的不可替代的中性或带负电的单或多齿配体，X是以下化学式的阴离子BF.sub.4.sup.-、PF.sub.6.sup.-、AsF.sub.6.sup.-、SbF.sub.6.sup.-、ClO.sub.4.sup.-、IO.sub.4.sup.-、NO.sub.3.sup.-或是全氟烷基磺酸的磺酸根，n是1至6的整数，m是0或1至6的整数，k是1或2，x是1至1000的整数，y是0或1至1000的整数，z是0或1至6的整数。

  公开号：

  US05342903A1

文献信息

• EPOXY RESINS AND PROCESSES FOR PREPARING THE SAME
  申请人：Hefner, JR. Robert E.

  公开号：US20110039982A1

  公开（公告）日：2011-02-17

  Epoxy resins comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety and processes for preparing the epoxy resins. The process of preparation of the epoxy resins comprises reacting (a) a mixture of a cis-1,3-cyclohexanedimethanol, a trans-1,3-cyclohexanedimethanol, a cis-1,4-cyclohexanedimethanol, and a trans-1,4-cyclohexanedimethanol, (b) an epihalohydrin, (c) a basic acting substance, (d) optionally, a solvent, (e) optionally, a catalyst, and/or (f) optionally, a dehydrating agent. The process may be a slurry epoxidation process, an anhydrous epoxidation process, or a Lewis acid catalyzed coupling and epoxidation process.
• MAGNESIUM HALIDE ADDUCTS, CATALYST COMPONENTS AND CATALYSTS COMPRISING THE SAME, AND PREPARATION PROCESSES THEREOF
  申请人：XIA Xianzhi

  公开号：US20120302708A1

  公开（公告）日：2012-11-29

  A magnesium halide adduct is provided, comprising at least one compound of the formula MgXY, at least one compound of the formula ROH, methanol, at least one modifying agent chosen from DOE and o-hydroxy benzoates, and optionally water. Also provided herein are a catalyst component comprising the magnesium halide adduct, a catalyst for olefin polymerization comprising the catalyst component; the respective processes for preparing the magnesium halide adduct and the catalyst component; use of the magnesium halide adduct for preparing the catalyst component, use of the catalyst component in a catalyst for olefin polymerization and use of the catalyst in olefin polymerization; and a process of olefin polymerization.
• PROCESS FOR PREPARING EPOXY RESINS
  申请人：Hefner, JR. Robert E.

  公开号：US20130178601A1

  公开（公告）日：2013-07-11

  A process for preparing an aliphatic or cycloaliphatic epoxy resin including the steps of: (I) reacting a mixture of (a) an aliphatic or cycloaliphatic hydroxyl containing material, (b) an epihalohydrin, (c) a basic acting substance, (d) a non-Lewis acid catalyst, and (e) optionally, a solvent, forming an epoxy resin composition; (II) subjecting the epoxy resin composition produced in step (I) to a separation process to remove (A) “light” components such as, for example, solvent used in the epoxidation reaction, if any, unreacted epihalohydrin, and co-products such as di(epoxypropyl)ether; (B) unreacted aliphatic or cycloaliphatic hydroxyl containing material, if any; (C) partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material, such as, for example, MGE; (D) fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material, such as, for example, DGE, such that the (E) aliphatic or cycloaliphatic polyfunctional epoxy resin product remaining contains no more than 50% by weight of said fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material (D); and (III) recycling the isolated partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material (C) and any mixtures of partially epoxidized aliphatic or cycloaliphatic hydroxyl containing material (C) with fully epoxidized aliphatic or cycloaliphatic hydroxyl containing material (D) from step (II) to a new reaction mixture of step (I).
• US8962792B2
  申请人：——

  公开号：US8962792B2

  公开（公告）日：2015-02-24
• US9068026B2
  申请人：——

  公开号：US9068026B2

  公开（公告）日：2015-06-30