Process for the preparation of alkylenediamine-N,N'-disuccinic acid-iron-base complex with pH control
申请人:The Associated Octel Company Limited
公开号:EP1153914A1
公开(公告)日:2001-11-14
This invention provides a process for the preparation of a complex of the formula L B · M wherein (a) L is of the formula (R1)(R2)N-(CH2)n-N(R3)(R4), wherein each of (R1)(R2)N and N(R3)(R4) is an optically active amino acid, which may be the same or different; and wherein n is an integer from 1 to 10, (b) B is a base and (c) M is a metal, the process comprising the steps of (i) providing a reaction mixture comprising L and B and having a pH of less than 7.5; (ii) contacting the reaction mixture with M to provide an first complex mixture; and (iii) contacting the first complex mixture with a further amount of B to provide a second complex mixture.
本发明提供了一种制备式 L B - M 复合物的工艺,其中(a)L 为式(R1)(R2)N-(CH2)n-N(R3)(R4),其中(R1)(R2)N 和 N(R3)(R4)各自为光学活性氨基酸,可以相同或不同;其中 n 是 1 至 10 的整数,(b) B 是碱,(c) M 是金属,该工艺包括以下步骤:(i) 提供包含 L 和 B 且 pH 值小于 7.5;(ii) 将反应混合物与 M 接触,提供第一络合物混合物;(iii) 将第一络合物混合物与更多量的 B 接触,提供第二络合物混合物。