4-Oxo-2-propionyl-hexanoic acid methyl ester | 113277-47-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• 英文名称: 4-Oxo-2-propionyl-hexanoic acid methyl ester
• 英文别名: Hexanoic acid, 4-oxo-2-(1-oxopropyl)-, methyl ester；methyl 4-oxo-2-propanoylhexanoate
• CAS: 113277-47-7
• 化学式: C₁₀H₁₆O₄
• 分子量: 200.235
• InChiKey: UFYYAMGZCXXJQP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  60.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  丙醛 、 丙烯酸甲酯（MA） 在 lithium nitrate 作用下， 以 水 、 乙腈 为溶剂， 以58%的产率得到4-Oxo-2-propionyl-hexanoic acid methyl ester
  参考文献：
  名称：

  Diacylation of activated olefins promoted by electrochemically generated NO3·p1

  摘要：

  It has been found in this study that an acyl radical is formed by the reaction of an aldehyde with a radical NO3. generated by the anodic oxidation of NO3- and the reaction of this acyl radical with activated olefins lead to the formation of a diacylated compound.

  DOI：

  10.1016/s0040-4039(00)73139-x

文献信息

• Diacylation of activated olefins promoted by electrochemically generated NO3·p1
  作者：Tatsuya Shono、Takeshi Soejima、Katsuya Takigawa、Yoshihide Yamaguchi、Hirofumi Maekawa、Shigenori Kashimura

  DOI：10.1016/s0040-4039(00)73139-x

  日期：1994.6

  It has been found in this study that an acyl radical is formed by the reaction of an aldehyde with a radical NO3. generated by the anodic oxidation of NO3- and the reaction of this acyl radical with activated olefins lead to the formation of a diacylated compound.