2-mercapto-decanoic acid | 146793-36-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-mercapto-decanoic acid
• 英文别名: 2-Mercapto-caprinsaeure；2-Mercapto-decansaeure；2-mercaptodecanoic acid；Mercaptodecanoic acid；2-sulfanyldecanoic acid
• CAS: 146793-36-4
• 化学式: C₁₀H₂₀O₂S
• 分子量: 204.334
• InChiKey: FWZCYACMKSIMGD-UHFFFAOYSA-N

物化性质

• 沸点：
  310.1±25.0 °C(Predicted)
• 密度：
  1.008±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  38.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-mercapto-decanoic acid 在 乙醇 、 碘 作用下， 生成 10,11-dithia-docosanedioic acid
  参考文献：
  名称：

  Eggerth, Journal of Experimental Medicine, 1931, vol. 53, p. 28

  摘要：

  DOI：
• 作为产物：
  描述：

  2-溴癸酸 、 potassium ethyl xanthogenate 生成 2-mercapto-decanoic acid
  参考文献：
  名称：

  Eggerth, Journal of Experimental Medicine, 1931, vol. 53, p. 28

  摘要：

  DOI：

文献信息

• Stereoselective synthesis of anti-PAF active thiazolidin-4-ones via cyclo-condensation of alkyl α-mercaptocarboxylates with arylimines
  作者：Yoo Tanabe、Yoshi-no Kubota、Yuzuru Sanemitsu、Nobushige Itaya、Gohfu Suzukamo

  DOI：10.1016/s0040-4039(00)92634-0

  日期：1991.1

  Two distinctive methods for the synthesis of cis- and trans-2, 5-disubstituted-thiazolidin-4-ones via stereoselective cyclo-condensation between α-mercaptocarboxylic esters and arylimines have been developed. With the new reaction used as the key step, two sets of optically active anti-PAF active thiazolidin-4-ones were synthesized.

  已经开发出两种独特的方法，其通过α-巯基羧酸酯和芳胺的立体选择性环缩合合成顺式和反式-2，5-二取代-噻唑烷-4-酮。以新的反应为关键步骤，合成了两套光学活性的抗PAF活性噻唑烷酮-4-酮。
• [EN] METHODS FOR LIGNIN DEPOLYMERIZATION USING THIOLS<br/>[FR] PROCÉDÉS DE DÉPOLYMÉRISATION DE LIGNINE À L'AIDE DE THIOLS
  申请人：UNIV MICHIGAN STATE

  公开号：WO2018195000A1

  公开（公告）日：2018-10-25

  The disclosure relates to a method for depolymerizing lignin. The method includes reacting a lignin compound with a thiol compound to depolymerize the lignin compound and to form a depolymerized lignin product having a reduced molecular weight relative to the lignin compound prior to reacting. The method can further include forming an oxidized thiol reaction product between two thiol groups from one or more thiol compounds, and then reducing the oxidized thiol reaction product to re-form or regenerate the thiol compound for further lignin depolymerization.

  该披露涉及一种降解木质素的方法。该方法包括将木质素化合物与硫醇化合物反应，以降解木质素化合物并形成一个相对于反应前的木质素化合物具有降低分子量的降解木质素产物。该方法还可以包括形成两个硫醇化合物中的一个或多个硫醇基之间的氧化硫醇反应产物，然后还原氧化硫醇反应产物以重新形成或再生用于进一步木质素降解的硫醇化合物。
• Fluorine-containing photocurable composition
  申请人：Otaguro Tsuneyuki

  公开号：US20070066779A1

  公开（公告）日：2007-03-22

  A fluorine-containing photocurable composition containing a (meth)acrylate having a fluorinated alkyl group (A) and a photopolymerization initiator (B). The (meth)acrylate (A) includes a group represented by general formula (1) and two or more (meth)acryloyl groups, and a fluorine atom content in one molecule of the acrylate is 25% by weight or more, and molecular weight of the (meth)acrylate is 500 to 4000 (in the general formula (1), R represents a hydrogen atom or alkyl group having 1 to 4 carbon atoms; X represents an alkylene chain, which may have a hetero atom, or a connecting group represented by the following general formula (2); and Rf represents a fluorinated alkyl group) (in the formula (2), Y represents an oxygen atom or a sulfur atom, m and n are an integer of 1 to 4 which may be the same as or different from each other; and Rf 1 is a fluorinated alkyl group).

  一种含氟光固化组合物，包含具有氟化烷基的（甲基）丙烯酸酯（A）和光引发剂（B）。 （甲基）丙烯酸酯（A）包括由通式（1）表示的基团和两个或更多（甲基）丙烯酰基团，并且丙烯酸酯中的一个分子中的氟原子含量为25％或更多，且（甲基）丙烯酸酯的分子量为500至4000（在通式（1）中，R表示氢原子或具有1到4个碳原子的烷基; X表示可以具有杂原子的烷基链或由以下通式（2）表示的连接基团; Rf表示氟化烷基）（在公式（2）中，Y表示氧原子或硫原子，m和n是1到4的整数，可以相同或不同; Rf1是氟化烷基）。
• ULTRAVIOLET ABSORBING POLYMER, CELLULOSE ESTER OPTICAL FILM, METHOD OF PRODUCING CELLULOSE ESTER OPTICAL FILM, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY
  申请人：Suzuki Takayuki

  公开号：US20100104775A1

  公开（公告）日：2010-04-29

  Disclosed is an ultraviolet absorbing polymer which is characterized by being derived from an ethylenically unsaturated monomer having a partial structure represented by Formula (A) below in a molecule, and a monomer represented by Formula (B) below:

  本发明涉及一种紫外线吸收聚合物，其特征在于其由分子中具有以下式(A)所表示的部分结构的乙烯基不饱和单体和以下式(B)所表示的单体衍生而来：
• ACTIVE ENERGY RAY CURABLE AQUEOUS RESIN COMPOSITION, ACTIVE ENERGY RAY CURABLE AQUEOUS COATING MATERIAL, AND ARTICLE COATED WITH THE COATING MATERIAL
  申请人：DIC Corporation

  公开号：US20140309360A1

  公开（公告）日：2014-10-16

  The present invention provides an active energy ray curable aqueous resin composition prepared by reacting an acrylic resin (A), a polyisocyanate compound (B), and (meth)acrylate (C) having a hydroxyl group and dispersing the reaction product in an aqueous medium, the resin (A) being produced by copolymerizing an acrylic monomer (a1) having a polyoxyalkylene group, an acrylic monomer (a2) having a hydroxyl group, and an acrylic monomer (a3) other than the acrylic monomer (a1) and the acrylic monomer (a2) as essential raw materials. The active energy ray curable aqueous resin composition has excellent storage stability and forms a cured coating film with a good appearance and high adhesion to a substrate even after immersion in hot water, and thus can be desirably used for an active energy ray curable aqueous coating material.

  本发明提供了一种活性能量辐射可固化的水性树脂组合物，其通过反应丙烯酸树脂（A）、聚异氰酸酯化合物（B）和具有羟基的（甲基）丙烯酸酯（C）并将反应产物分散在水性介质中制备而成，其中树脂（A）是由共聚丙烯酸单体（a1）具有聚氧烷基，丙烯酸单体（a2）具有羟基和丙烯酸单体（a3）除了丙烯酸单体（a1）和丙烯酸单体（a2）以外的其他基本原材料制备而成。该活性能量辐射可固化的水性树脂组合物具有良好的储存稳定性，并形成具有良好外观和高附着力的固化涂层膜，即使在热水中浸泡后仍然如此，因此可以理想地用于活性能量辐射可固化的水性涂料材料。