1,2-bisethane | 98815-26-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bisethane
• 英文别名: (1,2-bis(di-4-chlorophenyl)phosphine)ethane；1,2-bis(di-p-chlorophenylphosphino)ethane；1,2-bis[bis(p-chlorophenyl)phosphino]ethane；2-Bis(4-chlorophenyl)phosphanylethyl-bis(4-chlorophenyl)phosphane
• CAS: 98815-26-0
• 化学式: C₂₆H₂₀Cl₄P₂
• 分子量: 536.204
• InChiKey: NKJYGMUAGPFKBP-UHFFFAOYSA-N

物化性质

• 沸点：
  587.1±50.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Tungsten, tetrachlorobis(triphenylphosphine)- 、 1,2-bisethane 以 苯 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  钼和钨配合物中的二氮键结合和电化学

  摘要：

  一系列配合物[M（N 2）2 {（p -XC 6 H 4）2 PCH 2 CH 2 P（C 6 H 4 X- p）2 } 2的制备描述]（M ＝ Mo或W）。磷化氢取代基氧化电位的变化表明，电子结构涉及磷化氢磷与二氮之间的金属穿透共轭，这有助于金属-二氮键的强度。膦上的供电子取代基使化合物易于氧化。对苯甲腈替代二氮的速率的研究表明，供电子取代基也增加了金属-二氮键的不稳定性。

  DOI：

  10.1039/dt9840001703
• 作为产物：
  描述：

  4-溴氯苯 、 1,2-双(二氯磷基)-乙烷 在 正丁基锂 作用下， 生成 1,2-bisethane
  参考文献：
  名称：

  某些二膦R 2 PCH 2 CH 2 PR 2（R =烷基或芳基）及其rh（I）二氮衍生物的制备及性能

  摘要：

  描述了从Cl 2 PCH 2 CH 2 PCl 2合成一定范围的二膦R 2 PCH 2 CH 2 PR 2。讨论了从它们衍生的一系列配合物[ReCl（N 2）（R 2 PCH 2 CH 2 PR 2）2 ]的性质。的值之间的关系Ë ½牛和ν（N 2），用于所述配合物表明在二膦即吸电子取代基打乱σ和铼二氮键合π作用的通常的平衡。

  DOI：

  10.1039/dt9850001131
• 作为试剂：
  描述：

  乙烯基三甲氧基硅烷 、 苯甲醛 在 CuF*3PPh₃*2EtOH 、 1,2-bisethane 四丁基氟化铵 、 水 作用下， 以 四氢呋喃 为溶剂， 反应 24.17h， 以47%的产率得到1-苯基-2-丙烯-1-醇
  参考文献：
  名称：

  Process for producing an alcohol or a silyl ether thereof

  摘要：

  生产醇或其硅基醚的方法，其分子式为（4）：其中R1代表烃基、杂环基或烷氧羰基；R2代表氢或CO2R；X代表分子式（3）的芳基或烯基；R8代表氢或硅基残基，通过将化合物R1(C═O)R2与硅烷（R3）2R4Si—X反应，其中R3和R4分别代表烷基、烷氧基或芳基，在（i）含有氟化铜的催化剂组分或含有铜化合物和氟化物的催化剂组分和（ii）双齿膦化合物的存在下，或在从上述组分得到的络合物的存在下。

  公开号：

  US20060199973A1

文献信息

• Process for producing an alcohol or its silyl ether
  申请人：Takasago International Corporation

  公开号：EP1698609A1

  公开（公告）日：2006-09-06

  There is provided a process for producing an alcohol or its silyl ether represented by the formula (4): wherein R1 represents a hydrocarbon group, a heterocyclic group, or an alkoxycarbonyl group; R2 represents a hydrogen atom or CO2R; X represents an aryl group or an alkenyl group represented by the following general formula (3): and R8 represents a hydrogen atom or a silyl residue, by reacting a compound represented by the formula (1):          R1(C=O)R2     (1) wherein R1 and R2 are the same as defined above, with a silane represented by the formula (2):          (R3)2R4Si-X     (2) wherein R3 and R4 each represents an alkyl group, an alkoxy group, or an aryl group; and X is the same as defined above, in the presence of (i) a catalyst component containing copper fluoride, or a copper compound and a fluoride, and (ii) a bidentate phosphine compound or in the presence of a complex obtained from the foregoing components.

  提供了一种生产由式（4）表示的醇或其硅基醚的工艺： 其中 R1 代表烃基、杂环基或烷氧羰基；R2 代表氢原子或 CO2R；X 代表由下式通式（3）表示的芳基或烯基： 和 R8 代表氢原子或硅烷基残基： R1(C=O)R2 (1) 其中 R1 和 R2 与上述定义相同，与式 (2) 所代表的硅烷反应： (R3)2R4Si-X (2) 其中 R3 和 R4 各代表一个烷基、一个烷氧基或一个芳基；X 与上文所定义的相同，在 (i) 含有氟化铜或铜化合物和氟化物的催化剂组分和 (ii) 双齿膦化合物的存在下或在由上述组分得到的络合物存在下进行。
• Halogen Photoelimination from Monomeric Nickel(III) Complexes Enabled by the Secondary Coordination Sphere
  作者：Seung Jun Hwang、Bryce L. Anderson、David C. Powers、Andrew G. Maher、Ryan G. Hadt、Daniel G. Nocera

  DOI：10.1021/acs.organomet.5b00568

  日期：2015.10.12

  Endothermic halogen elimination reactions, in which molecular halogen photoproducts are generated in the absence of chemical traps, are rare. Inspired by the proclivity of mononuclear Ni(III) complexes to participate in challenging bond-forming reactions in organometallic chemistry, we targeted Ni(III) trihalide complexes as platforms to explore halogen photoelimination. A suite of Ni(III) trihalide complexes supported by bidentate phosphine ligands has been synthesized and characterized. Multinuclear NMR, EPR, and electronic absorption spectroscopies, as well as single-crystal X-ray diffraction, have been utilized to characterize this suite of complexes as distorted square pyramidal, S = 1/2 mononuclear Ni(III) complexes. All complexes participate in clean halogen photoelimination in solution and in the solid state. Evolved halogen has been characterized by mass spectrometry and quantified chemically. Energy storage via halogen elimination was established by solution-phase calorimetry measurements; in all cases, halogen elimination is substantially endothermic. Time-resolved photochemical experiments have revealed a relatively long-lived photointermediate, which we assign to be a Ni(II) complex in which the photoextruded chlorine radical interacts with a ligand-based aryl group. Computational studies suggest that the observed intermediate arises from a dissociative LMCT excited state. The participation of secondary coordination sphere interactions to suppress back-reactions is an attractive design element in the development of energy-storing halogen photoelimination involving first-row transition metal complexes.
• US7563916B2
  申请人：——

  公开号：US7563916B2

  公开（公告）日：2009-07-21
• Process for producing an alcohol or a silyl ether thereof
  申请人：Shibasaki Masakatsu

  公开号：US20060199973A1

  公开（公告）日：2006-09-07

  A process for producing an alcohol or a silyl ether thereof of formula (4): wherein R 1 represents a hydrocarbon, a heterocyclic, or an alkoxycarbonyl group; R 2 represents hydrogen or CO 2 R; X represents an aryl or an alkenyl group of formula (3): and R 8 represents hydrogen or a silyl residue, by reacting a compound R 1 (C═O)R 2 with a silane (R 3 ) 2 R 4 Si—X, wherein R 3 and R 4 each represents an alkyl, an alkoxy, or an aryl group; in the presence of (i) a catalyst component containing copper fluoride or a catalyst component containing a copper compound and a fluoride and (ii) a bidentate phosphine compound or in the presence of a complex obtained from the foregoing components.

  生产醇或其硅基醚的方法，其分子式为（4）：其中R1代表烃基、杂环基或烷氧羰基；R2代表氢或CO2R；X代表分子式（3）的芳基或烯基；R8代表氢或硅基残基，通过将化合物R1(C═O)R2与硅烷（R3）2R4Si—X反应，其中R3和R4分别代表烷基、烷氧基或芳基，在（i）含有氟化铜的催化剂组分或含有铜化合物和氟化物的催化剂组分和（ii）双齿膦化合物的存在下，或在从上述组分得到的络合物的存在下。
• The preparation and properties of some diphosphines R2PCH2CH2PR2(R = alkyl or aryl) and of their rhenium(I) dinitrogen derivatives
  作者：Joseph Chatt、Wasif Hussain、G. Jeffery Leigh、Hapipah Mohd. Ali、Christopher J. Picket、Douglas A. Rankin

  DOI：10.1039/dt9850001131

  日期：——

  The synthesis of a range of diphosphines R2PCH2CH2PR2 from Cl2PCH2CH2PCl2 is described. The properties of a series of complexes [ReCl(N2)(R2PCH2CH2PR2)2] derived from them are discussed. The relationship between the values of E½ox and ν(N2) for the complexes suggests that electron-withdrawing substituents on the diphosphine upset the usual balance of σ and π effects in rhenium–dinitrogen bonding.

  描述了从Cl 2 PCH 2 CH 2 PCl 2合成一定范围的二膦R 2 PCH 2 CH 2 PR 2。讨论了从它们衍生的一系列配合物[ReCl（N 2）（R 2 PCH 2 CH 2 PR 2）2 ]的性质。的值之间的关系Ë ½牛和ν（N 2），用于所述配合物表明在二膦即吸电子取代基打乱σ和铼二氮键合π作用的通常的平衡。