1,4-bis([(2'-benzylaminoformyl)phenoxyl]ethoxyl)benzene | 1095520-57-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis([(2'-benzylaminoformyl)phenoxyl]ethoxyl)benzene
• 英文别名: N-benzyl-2-[2-[4-[2-[2-(benzylcarbamoyl)phenoxy]ethoxy]phenoxy]ethoxy]benzamide
• CAS: 1095520-57-2
• 化学式: C₃₈H₃₆N₂O₆
• 分子量: 616.714
• InChiKey: MYNOOWSSQFYRGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  46
• 可旋转键数：
  16
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  95.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,4-bis([(2'-benzylaminoformyl)phenoxyl]ethoxyl)benzene 、 水 、 neodymium(III) nitrate 以 乙酸乙酯 为溶剂， 生成 Nd2(1,4-bis([(2'-benzylaminoformyl)phenoxyl]ethoxyl)benzene)3(NO3)6*2H2O
  参考文献：
  名称：

  Preparation, characterization and luminescent properties of lanthanide complexes with a new aryl amide bridging ligand

  摘要：

  A new aryl amide type bridging ligand 1,4-bis{[(2'-benzylaminoformyl)phenoxyl]ethoxyl}benzene (L) and its complexes with lanthanide ions (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er) were synthesized and characterized by elemental analysis, infrared spectra and electronic spectra. At the same time, the luminescent properties of the Sm, Eu, Tb and Dy complexes in solid state and the Tb complex in solvents were also investigated. At room temperature. these four complexes exhibited characteristic luminescence emissions of the central metal ions under UV light excitation and could be significant in the field of supramolecular photonic devices. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.03.013
• 作为产物：
  描述：

  N-苄基-2-羟基-苯甲酰胺 、 1,4-bis(tosyloxyethoxy)benzene 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 以63%的产率得到1,4-bis([(2'-benzylaminoformyl)phenoxyl]ethoxyl)benzene
  参考文献：
  名称：

  Preparation, characterization and luminescent properties of lanthanide complexes with a new aryl amide bridging ligand

  摘要：

  A new aryl amide type bridging ligand 1,4-bis{[(2'-benzylaminoformyl)phenoxyl]ethoxyl}benzene (L) and its complexes with lanthanide ions (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er) were synthesized and characterized by elemental analysis, infrared spectra and electronic spectra. At the same time, the luminescent properties of the Sm, Eu, Tb and Dy complexes in solid state and the Tb complex in solvents were also investigated. At room temperature. these four complexes exhibited characteristic luminescence emissions of the central metal ions under UV light excitation and could be significant in the field of supramolecular photonic devices. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.03.013

文献信息

• Preparation, characterization and luminescent properties of lanthanide complexes with a new aryl amide bridging ligand
  作者：Ya-Fei Li、Kuan-Zhen Tang、Yu Tang、Wei-Sheng Liu、Min-Yu Tan

  DOI：10.1016/j.saa.2008.03.013

  日期：2008.12

  A new aryl amide type bridging ligand 1,4-bis[(2'-benzylaminoformyl)phenoxyl]ethoxyl}benzene (L) and its complexes with lanthanide ions (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er) were synthesized and characterized by elemental analysis, infrared spectra and electronic spectra. At the same time, the luminescent properties of the Sm, Eu, Tb and Dy complexes in solid state and the Tb complex in solvents were also investigated. At room temperature. these four complexes exhibited characteristic luminescence emissions of the central metal ions under UV light excitation and could be significant in the field of supramolecular photonic devices. (C) 2008 Elsevier B.V. All rights reserved.