1-(n-Butoxycarbonyl)-4-carboxy-1,3-(E,E)-butadiene | 87729-21-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-(n-Butoxycarbonyl)-4-carboxy-1,3-(E,E)-butadiene
• 英文别名: Muconic acid butyl ester；(2E,4E)-6-butoxy-6-oxohexa-2,4-dienoic acid
• CAS: 87729-21-3
• 化学式: C₁₀H₁₄O₄
• 分子量: 198.219
• InChiKey: LPARONCWTGERSI-YDFGWWAZSA-N

物化性质

• 沸点：
  334.9±25.0 °C(Predicted)
• 密度：
  1.107±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (1S,4R)-4-butoxycarbonylcyclobut-2-ene-1-carboxylate 在 碘 三乙烯二胺 作用下， 以 氯仿 为溶剂， 反应 9.2h， 生成 1-(n-Butoxycarbonyl)-4-carboxy-1,3-(E,E)-butadiene
  参考文献：
  名称：

  Rotational selectivity in cyclobutene ring openings. Model studies directed toward a synthesis of verrucarin A

  摘要：

  DOI：

  10.1021/jo00177a015

文献信息

• [EN] SYNTHESIS AND PURIFICATION OF MUCONIC ACID ESTER FROM ALDARIC ACID ESTERS<br/>[FR] SYNTHÈSE ET PURIFICATION D'ESTER D'ACIDE MUCONIQUE À PARTIR D'ESTERS D'ACIDE ALDARIQUE
  申请人：TEKNOLOGIAN TUTKIMUSKESKUS VTT OY

  公开号：WO2019155128A1

  公开（公告）日：2019-08-15

  According to an example aspect of the present invention, there is provided a method for producing muconic acid ester from aldaric acid ester, and for separating and purifying the produced muconic acid ester by high vacuum distillation in a total heating environment.

  根据本发明的一个实施例，提供了一种从醛糖酸酯生产须二酸酯的方法，并通过在总加热环境下进行高真空蒸馏来分离和纯化所生产的须二酸酯。
• Synthesis and purification of muconic acid ester from aldaric acid esters
  申请人：Teknologian tutkimuskeskus VTT Oy

  公开号：US10968161B2

  公开（公告）日：2021-04-06

  According to an example aspect of the present invention, there is provided a method for producing muconic acid ester from aldaric acid ester, and for separating and purifying the produced muconic acid ester by high vacuum distillation in a total heating environment.

  根据本发明的一个示例方面，提供了一种从醛酸酯生产粘多酸酯的方法，以及在全加热环境下通过高真空蒸馏分离和提纯所生产的粘多酸酯的方法。
• EP3749634A1
  申请人：——

  公开号：EP3749634A1

  公开（公告）日：2020-12-16
• Monodisperse Polymers Containing (Alkyl)Acrylic Acid Moieties, Precursors and Methods for Making them and their Applications
  申请人：Du Prez Filip

  公开号：US20080262160A1

  公开（公告）日：2008-10-23

  This invention relates to monodisperse or nearly monodisperse (co)polymers containing acrylic or (α-substituted)acrylic acid moieties, polymeric precursors thereof as well as methods for making them by at least partial hydrolysis of said polymeric precursors. The invention also relates to compositions comprising such (co)polymers optionally in combination with polymer processing additives for use in various fields of technology including imaging applications.
• MONODISPERSE POLYMERS CONTAINING (ALKYL)ACRYLIC ACID MOIETIES, PRECURSORS AND METHODS FOR MAKING THEM AND THEIR APPLICATIONS
  申请人：DU PREZ Filip

  公开号：US20130096268A1

  公开（公告）日：2013-04-18

  This invention relates to monodisperse or nearly monodisperse (co)polymers containing acrylic or (α-substituted)acrylic acid moieties, polymeric precursors thereof as well as methods for making them by at least partial hydrolysis of said polymeric precursors. The invention also relates to compositions comprising such (co)polymers optionally in combination with polymer processing additives for use in various fields of technology including imaging applications.