tterpy-MV2+ | 124598-55-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: tterpy-MV2+
• 英文别名: 4-[4-[[4-(1-Methylpyridin-1-ium-4-yl)pyridin-1-ium-1-yl]methyl]phenyl]-2,6-dipyridin-2-ylpyridine；4-[4-[[4-(1-methylpyridin-1-ium-4-yl)pyridin-1-ium-1-yl]methyl]phenyl]-2,6-dipyridin-2-ylpyridine
• CAS: 124598-55-6
• 化学式: C₃₃H₂₇N₅
• 分子量: 493.611
• InChiKey: JZJQVBVRWVVUHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  46.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  [4'-(p-tolyl)-2, 2':6',2''-terpyridine]osmium trichloride 、 tterpy-MV2+ 在 三乙胺 作用下， 以 乙醇 、 水 为溶剂， 以30%的产率得到{Os(tterpy)(tterpy-MV2+)}(4+)
  参考文献：
  名称：

  与电子受体基团和电子给体基团共价连接的2,2'：6'，2''-吡啶的钌和配合物

  摘要：

  2,2'：6'，2''-三联吡啶配体已被修饰，使其带有一个电子受体或一个电子供体基团；已经证明from络合物从其金属到配体的电荷转移激发态会发生有效的分子内矢量电子转移。

  DOI：

  10.1039/c39890000776

文献信息

• Photoelectrodes based on electropolymerized molecular ruthenium and osmium diads
  作者：Jean Paul Collin、Alain Deronzier、Mohamed Essakalli

  DOI：10.1021/j100168a036

  日期：1991.7

  Ruthenium(II) and osmium(II) complexes with modified terpy ligands (terpy = 2,2':6',2"-terpyridine) have been prepared. The systems consist of two different ligands bonded to the metal center, one bearing an electron acceptor (viologen) and the other being end-linked to a pyrrole ring via its N atom. Electropolymerization of the ruthenium compound affords an electrically conductive film on the surface of a platinum electrode. The polypyrrole backbone is linked to pendent groups containing a photoactive component (ruthenium complex core) and an electron acceptor subunit (viologen). The modified electrode thus obtained acts as a photoelectrode. Visible light irradiation of the material in the presence of an organic electron donor (triethanolamine) in CH3CN leads to a significant photocurrent when the electrode is potentiostated at 0 V. The light energy conversion of the present integrated system is much more efficient than for the analogous material prepared by copolymerization of the two separate components, electron acceptor-pyrrole and ruthenium complex-pyrrole.
• Ruthenium and osmium complexes of 2,2′ : 6′,2″-terpyridine covalently linked to electron acceptor and electron donor groups
  作者：Jean-Paul Collin、Stéphane Guillerez、Jean-Pierre Sauvage

  DOI：10.1039/c39890000776

  日期：——

  2,2′ : 6′,2″-Terpyridine ligands have been modified so as to bear an electron acceptor or an electron donor group; efficient intramolecular vectorial electron transfer has been shown to occur in an osmium complex from its metal-to-ligand charge transfer excited state.

  2,2'：6'，2''-三联吡啶配体已被修饰，使其带有一个电子受体或一个电子供体基团；已经证明from络合物从其金属到配体的电荷转移激发态会发生有效的分子内矢量电子转移。