N1,N3-bis(1,1-dimethylethyl)-5-(phenylmethoxy)-1,3-benzenedicarboxamide | 1185753-87-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N1,N3-bis(1,1-dimethylethyl)-5-(phenylmethoxy)-1,3-benzenedicarboxamide
• 英文别名: N,N'-di-tert-butyl-3-(benzyloxy)isophthalamide；1-N,3-N-ditert-butyl-5-phenylmethoxybenzene-1,3-dicarboxamide
• CAS: 1185753-87-0
• 化学式: C₂₃H₃₀N₂O₃
• 分子量: 382.503
• InChiKey: QNTVPCWECXEWEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  67.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N1,N3-bis(1,1-dimethylethyl)-5-(phenylmethoxy)-1,3-benzenedicarboxamide 在 palladium 10% on activated carbon 、 氢气 作用下， 以 甲醇 为溶剂， 50.0 ℃ 、101.33 kPa 条件下， 以99%的产率得到3,5-bis-tert-butylcarbamoyl-phenol
  参考文献：
  名称：

  Redox-responsive morphology transformation of self-assembled nanostructures based on thiol-disulfide interconversion

  摘要：

  One dimensional (1D) nanotubes and three dimensional (3D) flowerlike supernanostructures were transformed reversibly, which was controlled by the oxidation and reduction cycle of aromatic diamide-derived thiol 1 and disulfide 2, as evidenced by SEM study. Their self-assembling patterns were investigated by UV-vis, H-1 NMR, X-ray crystallographic, and powder X-ray diffraction experiments. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.06.063
• 作为产物：
  描述：

  5-苄氧基异邻苯二甲酸 、 叔丁胺 在 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 以54%的产率得到N1,N3-bis(1,1-dimethylethyl)-5-(phenylmethoxy)-1,3-benzenedicarboxamide
  参考文献：
  名称：

  Organic nanotubes assembled from isophthalamides and their application as templates to fabricate Pt nanotubes

  摘要：

  一种新型有机纳米管由简单的间苯二甲酰胺衍生物组装而成，其表面可方便地镀上铂，在用热甲醇去除内部有机材料后形成新的铂纳米管。

  DOI：

  10.1039/b900843h

文献信息

• Redox-responsive morphology transformation of self-assembled nanostructures based on thiol-disulfide interconversion
  作者：Zhi-Gang Tao、Ze-Yun Xiao、Xin Zhao、Xi-Kui Jiang、Zhan-Ting Li

  DOI：10.1016/j.tetlet.2012.06.063

  日期：2012.8

  One dimensional (1D) nanotubes and three dimensional (3D) flowerlike supernanostructures were transformed reversibly, which was controlled by the oxidation and reduction cycle of aromatic diamide-derived thiol 1 and disulfide 2, as evidenced by SEM study. Their self-assembling patterns were investigated by UV-vis, H-1 NMR, X-ray crystallographic, and powder X-ray diffraction experiments. (c) 2012 Elsevier Ltd. All rights reserved.
• Organic nanotubes assembled from isophthalamides and their application as templates to fabricate Pt nanotubes
  作者：Yun-Xiang Xu、Xin Zhao、Xi-Kui Jiang、Zhan-Ting Li

  DOI：10.1039/b900843h

  日期：——

  A new class of organic nanotubes have been assembled from simple isophthalamide derivatives and their surface can be conveniently coated with Pt, which form new Pt nanotubes after the inside organic materials are removed with hot methanol.

  一种新型有机纳米管由简单的间苯二甲酰胺衍生物组装而成，其表面可方便地镀上铂，在用热甲醇去除内部有机材料后形成新的铂纳米管。