3-(全氟-5-甲基己基)-2-环氧丙烷 | 24564-77-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 3-(全氟-5-甲基己基)-2-环氧丙烷
• 中文别名: 3-(全氟-5-甲基己基)-1,2-环氧丙烷
• 英文名称: 3-(perfluoro-5-methylhexyl)-1,2-epoxypropane
• 英文别名: 2-[2,2,3,3,4,4,5,5,6,7,7,7-Dodecafluoro-6-(trifluoromethyl)heptyl]oxirane
• CAS: 24564-77-0
• 化学式: C₁₀H₅F₁₅O
• 分子量: 426.125
• InChiKey: NSHDLZDDSBGOKN-UHFFFAOYSA-N

物化性质

• 沸点：
  183 °C(lit.)
• 密度：
  1.706 g/mL at 25 °C(lit.)
• 闪点：
  >230 °F
• 稳定性/保质期：
  在常温常压下保持稳定，应避免与强氧化剂接触。

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  16

安全信息

• 危险等级：
  IRRITANT
• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  2910900090

文献信息

• Catalyst component for the polymerisation of olefins and process for preparing olefin polymers using same
  申请人：NIPPON OIL COMPANY, LIMITED

  公开号：EP0587440A2

  公开（公告）日：1994-03-16

  A catalyst component for use in the polymerization or copolymerization of olefin(s) is obtained by contacting the following components (1) to (4) with one another: (1) a compound of the general formula Me¹R¹p(OR²)qX¹4-p-q where R¹ is a hydrocarbon radical having 1 to 24 carbon atoms, X¹ is a halogen atom, Me¹ is Zr, Ti or Hf, and n is 0 ≦ n ≦ 4; (2) a compound of the general formula Me²R³m(OR⁴)nX²z-m-n where R² is a hydrocarbon radical having 1 to 24 carbon atoms, X² is a halogen atom, Me² is an element from Groups I to III in the Periodic Table, z is the valence of Me² and m is 0 ≦ m ≦ z; (3) an organocyclic compound having two or more conjugated double bonds; and (4) a modified organoaluminum compound containing Al-O-Al bond and with at least one branched-chain alkyl group being attached to aluminum atom.

  将下列组分（1）至（4）相互接触，可得到用于烯烃聚合或共聚的催化剂组分： (1) 通式为 Me¹R¹p(OR²)qX¹4-p-q的化合物 其中，R¹为具有 1 至 24 个碳原子的烃基；X¹为卤素原子；Me¹为 Zr、Ti 或 Hf；n 为 0 ≦ n ≦ 4； (2) 通式为 Me²R³m(OR⁴)nX²z-m-n的化合物，其中 R²为具有 1 至 24 个碳原子的烃基；X²为卤素原子；Me²为元素周期表中第 I 至 III 族的元素；z 为 Me²的化合价；m 为 0 ≦ m ≦ z； (3) 具有兩個或以上共轭双键的有机环化合物；及 (4) 含 Al-O-Al 键且至少有一个支链烷基与铝原子相连的改性有机铝化合物。
• OLEFIN OLIGOMERIZATION CATALYST AND PROCESS FOR THE PREPARATION OF OLEFIN OLIGOMER USING IT
  申请人：NIPPON OIL COMPANY, LTD.

  公开号：EP0758563A1

  公开（公告）日：1997-02-19

  An oligomerization catalyst according to the invention comprises a nickel compound (A); an organophosphoric compound (B); an organoaluminum compound (C); and a compound of the group consisting of carbon-halogen bond-containing compounds, oxoacid and salts thereof, sulfonic acid and derivatives thereof, and compounds of any of the formulae QX4n, QRn, QR'n, QX4lRm, QX4lR'm, QRlR'm, Q1(BR4)p and R''(BR4) wherein Q is an element of the group consisting of Mg, Ti, Zr, B and Sn, Q1 is an element of the group consisting of Li, Na, K, Ca and Zn, X4 is a halogen or hydrogen atom, R is a C1-C12 hydrocarbon group, R' is a C1-C12 oxygen-containing hydrocarbon groiup, R'' is a C1-C20 hydrocarbon group or an ammonium group, n is a valence of Q, l, m is a natural member that satisfied n=l+m, and p is a valence of Q1. This catalyst is useful for the production of alpha-olefinic oligomers.

  根据本发明的低聚催化剂包括镍化合物（A）；有机磷化合物（B）；有机铝化合物（C）；以及由以下物质组成的一组化合物：含碳-卤素键化合物、氧酸及其盐、磺酸及其衍生物，以及式 QX4n、QRn、QR'n、QX4lRm、QX4lR'm、QRlR'm、Q1(BR4)p 和 R''(BR4)中任何一种的化合物 其中 Q 是由镁、钛、锆、硼和锡组成的组中的元素、X4 是卤素或氢原子，R 是 C1-C12 烃基，R'是 C1-C12 含氧烃基，R''是 C1-C20 烃基或铵基，n 是 Q 的化合价，l、m 是满足 n=l+m 的自然数，p 是 Q1 的化合价。这种催化剂可用于生产α-烯烃低聚物。
• FLUORINATED POLYFUNCTIONAL (METH)ACRYLATE ESTERS, COMPOSITIONS, LOW-REFRACTION MATERIALS, AND ANTIREFLECTION FILMS
  申请人：NOF CORPORATION

  公开号：EP0863128A1

  公开（公告）日：1998-09-09

  Fluorine-containing polyfunctional (meth)acrylate represented by the formula (1), as well as a composition, a low refractivity material and a reflection reducing film in which the (meth)acrylate is utilized: wherein X stands for a fluoroalkyl group of C1-14 having 3 or more F, or a fluorocycloalkyl group of C3-14 having 4 or more F; Y1, Y2, and Y3 stand for H, an acryloyl group or a methacryloyl group, and at least two of Y1, Y2, and Y3 stand for an acryloyl group or a methacryloyl group; Z stands for H or an alkyl group of C1-3; and n and m is an integer of 0 or 1, and n+m=1.

  由式(1)表示的含氟多官能度(甲基)丙烯酸酯，以及使用该(甲基)丙烯酸酯的组合物、低折射率材料和减反射薄膜： 其中 X 代表具有 3 个或更多 F 的 C1-14 氟烷基，或具有 4 个或更多 F 的 C3-14 氟环烷基；Y1、Y2 和 Y3 代表 H、丙烯酰基或甲基丙烯酰基，Y1、Y2 和 Y3 中至少有两个代表丙烯酰基或甲基丙烯酰基；Z 代表 H 或 C1-3 烷基；n 和 m 是 0 或 1 的整数，n+m=1。
• Laminated diffractive optical element and resin composition therefor
  申请人：Canon Kabushiki Kaisha

  公开号：EP2081056A2

  公开（公告）日：2009-07-22

  A resin composition includes a binder component having at least one of a monomer and an oligomer of one or more of a fluorine system and a silicone system having a polymerizable functional group in a molecule. The resin composition also includes fine metal oxide particles, and a polymerization initiator. The fine metal oxide particles include particles selected from the group of zinc oxide, indium oxide, tin oxide, antimony oxide, tin-doped indium oxide (ITO), antimony-doped tin oxide (ATO), zinc-doped indium oxide (IZO), aluminum-doped zinc oxide (AZO), and fluorine-doped tin oxide (FTO).

  一种树脂组合物包括一种粘合剂成分，该粘合剂成分具有单体和低聚物中的至少一种，而单体和低聚物中的一种或多种是氟体系和硅体系，其分子中具有可聚合的官能团。树脂组合物还包括细金属氧化物颗粒和聚合引发剂。细金属氧化物颗粒包括选自氧化锌、氧化铟、氧化锡、氧化锑、掺锡氧化铟 (ITO)、掺锑氧化锡 (ATO)、掺锌氧化铟 (IZO)、掺铝氧化锌 (AZO) 和掺氟氧化锡 (FTO) 组的颗粒。
• Oil/grease- and water-sizing agent for treatment of cellulosics
  申请人：——

  公开号：US20030217824A1

  公开（公告）日：2003-11-27

  A water-dispersible oil/grease-sizing and water-sizing agent that provides oil/grease and water-sizing for paper and other cellulosic materials. The agent works effectively for both oil/grease and water sizing at high temperatures. The polymeric agent's key features include a polyamine component which is a repeating monomer unit with cellulose-reactive and fluorinated groups substituted on the polyamine.

  一种水分散型油脂施胶剂和水施胶剂，可为纸张和其他纤维素材料提供油脂和水施胶。该剂在高温条件下可有效地进行油/油脂和水施胶。聚合剂的主要特点包括聚胺成分，它是一种重复单体单元，聚胺上有纤维素反应基团和氟化基团。