Phosphine, [1,2-phenylenebis(methylene)]bis[bis(2-methoxyphenyl)- | 259110-38-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Phosphine, [1,2-phenylenebis(methylene)]bis[bis(2-methoxyphenyl)-
• 英文别名: [2-[bis(2-methoxyphenyl)phosphanylmethyl]phenyl]methyl-bis(2-methoxyphenyl)phosphane
• CAS: 259110-38-8
• 化学式: C₃₆H₃₆O₄P₂
• 分子量: 594.6
• InChiKey: ZDJMEIUMFOTGDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  42
• 可旋转键数：
  12
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• ALIPHATIC KETONE POLYMER
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP1857487A1

  公开（公告）日：2007-11-21

  An aliphatic ketone polymer comprising a unit represented by the following formula (1), the unit represented by the following formula (2), and a unit represented by the following formula (3) or (4). (In the formulae, R1 to R10 may be the same or different and each represents hydrogen, an optionally halogenated C1-20 hydrocarbon group, halogeno, hydroxy, ester, alkoxy, cyano, imide, silyl, or a group selected from the group consisting of C1-20 hydrocarbon groups substituted by a functional group selected among hydroxy, ester, alkoxy, cyano, imide, and silyl, provided that R2 and R8may be bonded to R3 and R9. respectively, to form a monocycle or polycycle; and n1, n2, and N3 satisfy 1≤n1≤20, 1≤n2≤35,000, and 1≤n3≤40,000.)

  一种脂肪族酮聚合物，由下式(1)代表的单元、下式(2)代表的单元和下式(3)或(4)代表的单元组成。(在式中，R1 至 R10 可以相同或不同，各自代表氢、任选卤代的 C1-20 烃基、卤代、羟基、酯、烷氧基、氰基、酰亚胺、硅烷基、或选自被选自羟基、酯、烷氧基、氰基、酰亚胺和硅烷基中的官能团取代的 C1-20 烃基组成的组，条件是 R2 和 R8 可分别与 R3 和 R9 键合以形成单环。且 n1、n2 和 N3 满足 1≤n1≤20、1≤n2≤35,000 和 1≤n3≤40,000）。
• Process for producing polyketone
  申请人：Hyosung Corporation

  公开号：EP1894960A1

  公开（公告）日：2008-03-05

  The present invention relates to a process for preparing polyketone with improved catalytic activity and intrinsic viscosity, and specifically a process for preparing polyketone wherein an organometallic complex comprising acetate-palladium and 1,3-bis[bis(2-methoxy-5-methylphenyl)phosphino]propane is used as a catalyst component, and a mixed solvent of 70 to 90 vol% of acetic acid and 10 to 30 vol% of water is used as a liquid medium.

  本发明涉及一种制备聚酮的工艺，该工艺具有更高的催化活性和内在粘度，特别是一种制备聚酮的工艺，在该工艺中，由醋酸钯和 1,3-双[双(2-甲氧基-5-甲基苯基)膦]丙烷组成的有机金属复合物用作催化剂组分，由 70 至 90 Vol% 的醋酸和 10 至 30 Vol% 的水组成的混合溶剂用作液体介质。
• Process for preparing polyketone
  申请人：Hyosung Corporation

  公开号：EP1942127A1

  公开（公告）日：2008-07-09

  The present invention relates to a process for preparing polyketone with improved catalytic activity and intrinsic viscosity, and specifically a process for preparing polyketone, using a mixed solvent of 40 to 60 mol% acetic acid and 40 to 60 mol% water, as a liquid medium, and the precursor of palladium chloride-1,3-bis[di(methoxyphenyl)phosphino]propane, as a catalyst component.

  本发明涉及一种提高催化活性和内在粘度的聚酮的制备工艺，特别是一种使用 40 至 60 摩尔%的乙酸和 40 至 60 摩尔%的水混合溶剂作为液体介质、氯化钯-1,3-双[二（甲氧基苯基）膦]丙烷前体作为催化剂组分的聚酮的制备工艺。
• POLYKETONE RESIN COMPOSITION HAVING EXCELLENT OIL RESISTANCE
  申请人：Hyosung Corporation

  公开号：EP3187543A2

  公开（公告）日：2017-07-05

  The present invention relates to a polyketone resin composition and a method for manufacturing the same. The polyketone resin composition is prepared by mixing a polyketone terpolymer consisting of repeating units, represented by the following general formulas (1) and (2), with ABS, a glass fiber, a sulfonamide-based plasticizer and a mineral filler, and is applicable to various industrial fields requiring oil resistance, calcium chloride resistance, impact resistance, etc.         -[-CH2CH2-CO]x-     (1)         -[-CH2-CH(CH3)-CO]y-     (2)

  本发明涉及一种聚酮树脂组合物及其制造方法。该聚酮树脂组合物是由以下通式（1）和（2）表示的重复单元组成的聚酮三元共聚物与 ABS、玻璃纤维、磺酰胺基增塑剂和矿物填料混合制备而成，适用于要求耐油性、耐氯化钙性、耐冲击性等的各种工业领域。 -[-CH2CH2-CO]x-（1） -[-CH2-CH(CH3)-CO]y- (2)
• POLYKETONE RESIN COMPOSITION HAVING OUTSTANDING WATER RESISTANCE
  申请人：Hyosung Corporation

  公开号：EP3187544A2

  公开（公告）日：2017-07-05

  The present invention relates to a polyketone resin composition and to a production method therefor; and relates to a polyketone copolymer having outstanding water resistance, moisture-absorption rate and shock resistance, characterised in that the polyketone copolymer comprises repeat units represented by general formulae (1) and (2) and has an intrinsic viscosity of between 1.0 and 2.0 dl/g. Because of the outstanding moisture-absorption rate and shock resistance, the present invention can be used in, inter alia, marine bolts, clips and holders, connectors, switches, bobbins, sludge-treatment chains, cable ties, automotive fuel injection ports, green juicer screws, office partition frames and box frames.         -[-CH2CH2-CO]x-     (1)         -[-CH2-CH(CH3)-CO]y-     (2)

  本发明涉及一种聚酮树脂组合物及其生产方法；并涉及一种具有出色的耐水性、吸湿率和抗冲击性的聚酮共聚物，其特征在于该聚酮共聚物由通式(1)和(2)所代表的重复单元组成，并具有介于 1.0 和 2.0 dl/g 之间的固有粘度。由于本发明具有出色的吸湿率和抗冲击性，因此可用于船用螺栓、夹子和支架、连接器、开关、线轴、污泥处理链、电缆扎带、汽车燃料喷射口、绿色榨汁机螺钉、办公室隔断框架和箱体框架等。 -[-CH2CH2-CO]x-（1） -[-CH2-CH(CH3)-CO]y- (2)