9,10,11-Tris(benzylidene)-9H,10H-4b,9a-(<1,2>benzenomethano)indeno<1,2-a>indene | 134939-97-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 9,10,11-Tris(benzylidene)-9H,10H-4b,9a-(<1,2>benzenomethano)indeno<1,2-a>indene
• 英文别名: (8E,10E,23E)-8,10,23-tribenzylidenehexacyclo[7.7.7.01,9.02,7.011,16.017,22]tricosa-2,4,6,11,13,15,17,19,21-nonaene
• CAS: 134939-97-2
• 化学式: C₄₄H₃₀
• 分子量: 558.722
• InChiKey: OAJOBJCRXOEFLN-FRHYWYHZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  44
• 可旋转键数：
  3
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9,10,11-Tribenzyltriptindan-9,10,11-triol 以 二甲基亚砜 为溶剂， 反应 20.0h， 以32%的产率得到9,10,11-Tris(benzylidene)-9H,10H-4b,9a-(<1,2>benzenomethano)indeno<1,2-a>indene
  参考文献：
  名称：

  Benzoannulated centropolyquinones. 8. Synthesis and reactions of 9,10,11-triptindantrione and some other functionalized tribenzo[3.3.3]propellanes (9H,10H-4b,9a-([1,2]benzenomethano)indeno[1,2-a]indenes)

  摘要：

  A new and efficient route to the tribenzo[3.3.3]propellane 1 (triptindan) and to some interesting derivatives such as 9-triptindanone (13) and 9,10,11-triptindantrione (3) has been developed. The propellane framework of 13 is accessible from 1,3-indandione in only two steps. Triketone 3, a versatile substrate with formal C3-upsilon molecular symmetry, is obtained from 13 in two further steps. First examples are presented for reactions of 3 leading to more complex benzoannelated centropolyquinanes (centropolyindans).

  DOI：

  10.1021/jo00015a034