3-[3-(肼磺酰基)苯基]磺酰基苯磺酰肼 | 3375-11-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-[3-(肼磺酰基)苯基]磺酰基苯磺酰肼
• 英文名称: diphenyl sulfone-3,3'-disulfonohydrazide
• 英文别名: 3,3'-Sulphonyldi(benzenesulphonohydrazide)；3-[3-(hydrazinesulfonyl)phenyl]sulfonylbenzenesulfonohydrazide
• CAS: 3375-11-9
• 化学式: C₁₂H₁₄N₄O₆S₃
• 分子量: 406.464
• InChiKey: BLJHFERYMGMXSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  204
• 氢给体数：
  4
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  3-[3-(肼磺酰基)苯基]磺酰基苯磺酰肼 、 丙酮 以57%的产率得到
  参考文献：
  名称：

  CREMLYN, R.;MONTGOMERY, S.;NG, YEW;SIMPSON, D., PHOSPH. AND SULFUR, 1982, 12, N 3, 341-352

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯砜 在 氯磺酸 、 一水合肼 作用下， 以 甲醇 为溶剂， 反应 5.0h， 生成 3-[3-(肼磺酰基)苯基]磺酰基苯磺酰肼
  参考文献：
  名称：

  Cremlyn, Richard; Montgomery, Stephen; Ng, Yew, Phosphorus and Sulfur and the Related Elements, 1981, vol. 12, p. 341 - 352

  摘要：

  DOI：

文献信息

• LATENT CURING AGENT AND EPOXY COMPOSITIONS CONTAINING THE SAME
  申请人：Horikiri Masashi

  公开号：US20120238653A1

  公开（公告）日：2012-09-20

  A latent curing agent obtained by the reaction of a coumarin compound with an amine.

  一种通过香豆素化合物与胺反应获得的潜在固化剂。
• Olefin block copolymers processes for producing the same and uses thereof
  申请人：——

  公开号：US20030055179A1

  公开（公告）日：2003-03-20

  The present invention provides polymers having any one of properties including affinity for metals or polar resins, impact resistance, mar resistance, heat resistance, rigidity, oil resistance, transparency, anti-fogging properties, electric insulating properties, high breakdown voltage, coating properties, low-temperature flexibility, moldability, environmental degradation, fluidity and dispersibility, and provides a process for preparation thereof. The olefin block copolymers (A-1) of the invention are represented by the formula (I) PO 1 —g 1 —B 1 (I) (wherein PO 1 is a segment composed of repeating units derived from an olefin having 2 to 20 carbon atoms, g 1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B 1 is a segment containing an unsaturated hydrocarbon or a hetero atom). The olefin block copolymers are suitable for uses in adhesives; various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets; modifiers and dispersions.

  本发明提供了具有以下任一性质的聚合物，包括对金属或极性树脂的亲和性，抗冲击性，抗刮伤性，耐热性，刚度，耐油性，透明性，防雾性能，电绝缘性能，高击穿电压，涂料性能，低温柔性，可塑性，环境降解性，流动性和分散性，并提供其制备方法。本发明的烯烃嵌段共聚物（A-1）由公式（I）表示：PO1-g1-B1（I）（其中PO1是由具有2至20个碳原子的烯烃衍生的重复单元组成的片段，g1是酯，醚，酰胺，亚胺，脲，硅醚或羰基连接，B1是含有不饱和碳氢化合物或杂原子的片段）。烯烃嵌段共聚物适用于粘合剂；各种成型品，如建筑和土木工程材料，汽车内外饰料，汽油箱，电子和电气零件，医疗保健和卫生材料，杂货物料，具有环境降解性能的树脂材料，薄膜和片材；改性剂和分散剂。
• Crosslinkable rubber compositions and uses thereof
  申请人：Hakuta Takashi

  公开号：US20050154132A1

  公开（公告）日：2005-07-14

  The crosslinkable rubber composition of the invention is crosslinkable by hot air, and a hot-air crosslinked rubber sheet thereof has no scratch on the surface in a hardness test using a pencil of HB and has a compression set of not more than 70% after a heat treatment at 150° C. for 22 hours. The rubber composition comprises an ethylene/α-olefin/non-conjugated polyene random copolymer rubber comprising a specific vinyl end group-containing norbornene compound, a SiH group-containing compound having at least two SiH groups in one molecule, and if necessary, an addition reaction catalyst comprising a platinum group element and a reaction inhibitor. The automobile weatherstrip, hose, rubber vibration insulator, belt, sealing material, expanded product, covered electric wire, electric wire joint, electric insulating part and household rubber product according to the invention comprise the above-mentioned rubber composition. The rubber composition has a high crosslinking rate and excellent productivity to produce crosslinked rubber molded products, is capable of undergoing hot-air crosslinking such as HAV or UHF and is capable of providing crosslinked rubber molded products having excellent compression set resistance, strength properties, heat resistance, weathering resistance and abrasion resistance.

  本发明的可交联橡胶组合物可通过热空气进行交联，其中的热空气交联橡胶板在使用HB铅笔硬度测试时表面没有划痕，并且在经过150°C的热处理22小时后，其压缩回弹率不超过70％。该橡胶组合物包括一种乙烯/α-烯烃/非共轭聚烯随机共聚物橡胶，其中包含一种特定的含有乙烯基末端的诺博烯化合物，一种具有至少两个SiH基团的化合物，以及必要时包括铂族元素的加成反应催化剂和反应抑制剂。根据本发明的汽车密封条、软管、橡胶减震器、皮带、密封材料、膨胀制品、覆盖电线、电线接头、电绝缘件和家用橡胶制品包括上述橡胶组合物。该橡胶组合物具有高交联速率和优异的生产力，可生产交联橡胶成型产品，能够经受HAV或UHF等热空气交联，并能够提供具有优异的压缩回弹性、强度性能、耐热性、耐候性和耐磨性的交联橡胶成型产品。
• HEAT-EXPANDABLE REMOVABLE ACRYLIC PRESSURE-SENSITIVE ADHESIVE TAPE OR SHEET
  申请人：Higuchi Naoaki

  公开号：US20120034447A1

  公开（公告）日：2012-02-09

  Provided is a heat-expandable removable acrylic pressure-sensitive adhesive tape that has high normal-state adhesive power when bonded independently of whether the adherend has or does not have irregular surface and permits easy separation when the bonded region is separated and disassembled by lowering the adhesive power by heating, that permits easily separation-decomposition, even after long-term storage at high temperature. The heat-expandable removable acrylic pressure-sensitive adhesive tape or sheet according to the present invention includes at least a heat expanding agent-containing pressure-sensitive adhesive layer, and the tape or sheet has an initial 90° peel adhesive strength to a polycarbonate plate as adherend of 10 N/25 mm or more and a 90° peel adhesive strength after storage in an atmosphere at 80° C. for 2 months as bonded to the polycarbonate adherend and after heat expansion treatment of less than 10 N/25 mm.

  提供的是一种热膨胀可拆卸丙烯酸压敏胶粘带，无论粘接的基材表面是否不规则，都具有高粘接力，并且在通过加热降低粘接力进行分离时，可以轻松分离粘接区域，即使在高温长期储存后也可以轻松分离分解。本发明的热膨胀可拆卸丙烯酸压敏胶粘带或薄片至少包括含有热膨胀剂的压敏胶层，该带或薄片在初次粘接到聚碳酸酯基材时的90°剥离粘接强度为10 N/25 mm或更高，并且在80℃环境下储存2个月后进行热膨胀处理后，与聚碳酸酯基材粘接的90°剥离粘接强度小于10 N/25 mm。
• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。