bis(phthalocyaninato)lutetium(III)H | 12369-74-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: bis(phthalocyaninato)lutetium(III)H
• 英文别名: 2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene;hydron;lutetium(3+)
• CAS: 12369-74-3
• 化学式: C₆₄H₃₂LuN₁₆*H
• 分子量: 1201.04
• InChiKey: YBUYPYVECVICRC-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  12.37
• 重原子数：
  81
• 可旋转键数：
  0
• 环数：
  18.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  152
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  bis(phthalocyaninato)lutetium(III)H 在 三氧化硫 、 氨 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 diammonium phthalocyaninedisulfonate Lu(III) complex
  参考文献：
  名称：

  Moskalev, P. N.; Kirin, I. S., Zhurnal Obshchei Khimii, 1968, vol. 38, p. 1144

  摘要：

  DOI：
• 作为产物：
  描述：

  {bis(phthalocyaninato)lutetium(III)}{Na.cntnd.18-crown-6} 以 甲醇 、 氯苯 为溶剂， 生成 bis(phthalocyaninato)lutetium(III)H
  参考文献：
  名称：

  Moussavi, Mehdi; De Cian, André; Fischer, Jean, Inorganic Chemistry, 1988, vol. 27, # 7, p. 1287 - 1291

  摘要：

  DOI：

文献信息

• Direct observation of molecular images of lanthanide phthalocyanines
  作者：W.P. Zhang、K.H. Kuo、Y.F. Hou、J.Z. Ni

  DOI：10.1016/0022-4596(88)90351-9

  日期：1988.6

  Lanthanide phthalocyanine (LnPc2H: Ln =Nd, Tb, Er, Tm, Yb, and Lu) thin films prepared epitaxially on KCl and NaCl crystals have been studied at the molecular level by means of high-resolution electron microscopy. Both tetragonal and orthorhombic structures have been found. It is revealed that the interaction between substrates and molecules, the existence of geometric isomers, the anisotropy of molecular

  借助高分辨率电子显微镜研究了在KCl和NaCl晶体上外延制备的镧系酞菁（LnPc 2 H：Ln = Nd，Tb，Er，Tm，Yb和Lu）薄膜。已经发现了四方和正交结构。揭示了底物与分子之间的相互作用，几何异构体的存在，分子形状的各向异性以及分子间的力在分子堆积中起着重要的作用。在KCl上生长的薄膜中大量存在孪晶，从分子形状的几何形状及其排列可以理解孪生关系。建议LnPc 2 H的两个酞菁配体之间的相对角度 分子可以在有限的角度范围内变化。
• Preparation of Bis(phthalocyaninato)lutetium with Various Substituents and Their Electrochemical Properties
  作者：Yunqi Liu、Kiyotaka Shigehara、Akira Yamada

  DOI：10.1246/bcsj.65.250

  日期：1992.1

  A series of bis(phthalocyaninato)lutetium complexes with substituents on each benzoring [Lu(pc2R8)] was prepared and the electrochromic behavior investigated by means of cyclic voltammetry of coated electrodes.Although the unsubstituted complex, Lu(pc)2, showed multistep electrochromism, its stability was quite unsatisfactory due to a falling-off of films from the electrode surface upon repetitive potential scanning. In the case of R = t-butyl, the improved solubility in organic solvents brought about an easier filming process and better adhesion to the electrode surface, though its high oxidation potential caused a cleavage of bi-peripheral complex. In contrast, complexes with electron-donating groups, such as R = propoxy or neopentyloxy, showed a lower oxidation potential and better stability upon repetitive potential scans, though the oxidized color was brownish rather than bright red. Complexes with 4 groups each of tetra-t-butyl and tetra propoxy had the oxidation potential close to that of octapropoxy or octakis(neopentyloxy) complexes and showed much improved stability and electrochromic behavior.

  制备了一系列苯并环上带有取代基的双(酞菁)镥配合物[Lu(pc2R8)]，并通过涂层电极的循环伏安法研究了其电致变色行为。尽管未取代的配合物Lu(pc)2表现出多步电致变色现象，由于重复电位扫描时薄膜从电极表面脱落，其稳定性非常不令人满意。在R=叔丁基的情况下，在有机溶剂中溶解度的提高带来了更容易的成膜过程和对电极表面更好的附着力，尽管其高氧化电位导致双外围络合物的裂解。相比之下，具有给电子基团（例如R =丙氧基或新戊氧基）的配合物在重复电位扫描时表现出较低的氧化电位和更好的稳定性，尽管氧化后的颜色为棕色而不是亮红色。四叔丁基和四丙氧基各有 4 个基团的配合物具有接近八丙氧基或八（新戊氧基）配合物的氧化电位，并且表现出大大改善的稳定性和电致变色行为。
• Kirin, I. S.; Moskalev, P. N.; Makashev, Yu. A., Zhurnal Neorganicheskoi Khimii, 1967, vol. 12, p. 369 - 372
  作者：Kirin, I. S.、Moskalev, P. N.、Makashev, Yu. A.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sc: MVol.D1, 2.23.7, page 96 - 99
  作者：

  DOI：——

  日期：——
• Moskalev, P. N.; Kirin, I. S., Zhurnal Obshchei Khimii, 1968, vol. 38, p. 1144
  作者：Moskalev, P. N.、Kirin, I. S.

  DOI：——

  日期：——