ACTIVE-ENERGY-RAY-CURABLE SEALING AGENT COMPOSITION, AND MEMBER HAVING SEALING LAYER ATTACHED THERETO
申请人:Huntsman Advanced Materials (Switzerland) GmbH
公开号:EP2287269A1
公开(公告)日:2011-02-23
An photo-curable sealing agent composition comprising (A) an unsaturated group-containing urethane resin having a number average molecular weight of 1, 000-100, 000 and an unsaturation dgree of 0 .1-1 mol/kg, which is obtained by reaction of (a) a polycarbonate diol having a number average molecular weight of 500-3,000, (b) a bifunctional epoxy (meth)acrylate having two hydroxyl groups and two ethylenically unsaturated groups, and (c) a polyisocyanate; (B) a (meth)acrylic acid ester monomer, wherein an alcohol residue, ester-bonded with an (meth)acyloyl group, is a hydrocarbon group which may contain an oxygen atom, and has 1-20 carbon atoms and a molecular weight of not larger than 1,000; and (C) a photopolymerization initiator. The sealing agent composition exhibits a high curability performance and gives a cured product having a low hardness and enhanced flexibility and elongation, and improved physical and mechanical strength and enhanced durability.
一种光固化密封剂组合物,包括 (A) 含不饱和基团的聚氨酯树脂,其平均分子量为 1 000-100 000,不饱和度为 0 .1-1摩尔/千克,它是由(a)平均分子量为500-3000的聚碳酸酯二元醇,(b)具有两个羟基和两个乙烯不饱和基团的双官能环氧(甲基)丙烯酸酯和(c)多异氰酸酯反应而得;(B) (甲基)丙烯酸酯单体,其中与(甲基)丙烯酰基酯键合的醇残基是可含有氧原子的烃基,具有 1-20 个碳原子,分子量不大于 1,000;以及 (C) 光聚合引发剂。密封剂组合物具有很高的固化性能,固化后的产品硬度低,柔韧性和伸长率增强,物理和机械强度提高,耐久性增强。