2-Ethenyl-5-(2-methylpropyl)furan | 917769-46-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Ethenyl-5-(2-methylpropyl)furan
• 英文别名: 2-ethenyl-5-(2-methylpropyl)furan
• CAS: 917769-46-1
• 化学式: C₁₀H₁₄O
• 分子量: 150.221
• InChiKey: NKTRVSGDCVQRNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(1-chloroethyl)-5-(2-methylpropyl)furan 在 sodium diethyl phosphite 作用下， 以 苯 为溶剂， 反应 5.0h， 生成 2-Ethenyl-5-(2-methylpropyl)furan
  参考文献：
  名称：

  2-(1-Chloroalkyl)furans in the reaction with sodium diethyl phosphite

  摘要：

  2-(1-Chloroethyl) and 2-(1-chloro-2-methylpropyl)furans react with sodium diethyl phosphite to give two products, 2-(1-diethoxyphosphorylmethyl)furan and 2-alkyl-5-(diethoxyphosphoryloxy)furan. The fraction of the latter product increases with increasing size of the alkyl radical. 2-Methyl substitution in the substrate completely suppresses phosphate formation. 2-(1-Chloroethyl)-5-(2-methylpropyl)furan under the action of sodium diethyl phosphite eliminates hydrogen chloride to give the corresponding alkene.

  DOI：

  10.1134/s1070363206040207

文献信息

• 2-(1-Chloroalkyl)furans in the reaction with sodium diethyl phosphite
  作者：L. M. Pevzner

  DOI：10.1134/s1070363206040207

  日期：2006.4

  2-(1-Chloroethyl) and 2-(1-chloro-2-methylpropyl)furans react with sodium diethyl phosphite to give two products, 2-(1-diethoxyphosphorylmethyl)furan and 2-alkyl-5-(diethoxyphosphoryloxy)furan. The fraction of the latter product increases with increasing size of the alkyl radical. 2-Methyl substitution in the substrate completely suppresses phosphate formation. 2-(1-Chloroethyl)-5-(2-methylpropyl)furan under the action of sodium diethyl phosphite eliminates hydrogen chloride to give the corresponding alkene.