Tridec-5-enoic acid | 92155-42-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Tridec-5-enoic acid
• 英文别名: tridec-5-enoic acid
• CAS: 92155-42-5
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: CMIMTWMGUGEMPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲基锂 、 Tridec-5-enoic acid 以 四氢呋喃 为溶剂， 生成 6-Tetradecen-2-one
  参考文献：
  名称：

  Sex pheromone of oriental beetle,Exomala orientalis: Identification and field evaluation

  摘要：

  A gas chromatograph coupled with a behavioral bioassay was used to identify two sex pheromone components, 7-(Z)- and 7-(E)-tetradecen-2-one of the Oriental beetle (OB), Exomala orientalis. Field experiments showed that the blend of the two isomers (Z:E, 7:1) was not significantly more attractive than the Z component alone. The best performance of traps baited with the synthetic sex pheromone was achieved when they were set with the pheromone device at 30 cm above the ground. Catches in traps baited with 1 and 10 mg were not significant[y different, but they were higher (2.9-fold) than captures in traps loaded with 0.1 mg of the pheromone. Further investigations by GC-EAD revealed the presence of a possible minor component, but the small amount of material prevented its identification. 2-(E)-Nonenol, with the same retention time as the natural product, did not affect the attractancy of the synthetic sex pheromone. GC-EAD screening of previously identified sex pheromones of scarab beetles showed that male antennae of the Oriental beetle responded to japonilure, but it showed neither synergism nor inhibition to the OB sex pheromone.

  DOI：

  10.1007/bf02059892
• 作为产物：
  描述：

  diethyl 2-(2-(1,3-dioxolan-2-yl)ethyl)malonate 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 生成 Tridec-5-enoic acid
  参考文献：
  名称：

  Sex pheromone of oriental beetle,Exomala orientalis: Identification and field evaluation

  摘要：

  A gas chromatograph coupled with a behavioral bioassay was used to identify two sex pheromone components, 7-(Z)- and 7-(E)-tetradecen-2-one of the Oriental beetle (OB), Exomala orientalis. Field experiments showed that the blend of the two isomers (Z:E, 7:1) was not significantly more attractive than the Z component alone. The best performance of traps baited with the synthetic sex pheromone was achieved when they were set with the pheromone device at 30 cm above the ground. Catches in traps baited with 1 and 10 mg were not significant[y different, but they were higher (2.9-fold) than captures in traps loaded with 0.1 mg of the pheromone. Further investigations by GC-EAD revealed the presence of a possible minor component, but the small amount of material prevented its identification. 2-(E)-Nonenol, with the same retention time as the natural product, did not affect the attractancy of the synthetic sex pheromone. GC-EAD screening of previously identified sex pheromones of scarab beetles showed that male antennae of the Oriental beetle responded to japonilure, but it showed neither synergism nor inhibition to the OB sex pheromone.

  DOI：

  10.1007/bf02059892