(1-tert-Butylcyclopenta-2,4-dien-1-yl)(trimethyl)silane | 62546-06-9

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: (1-tert-Butylcyclopenta-2,4-dien-1-yl)(trimethyl)silane
• 英文别名: (1-tert-butylcyclopenta-2,4-dien-1-yl)-trimethylsilane
• CAS: 62546-06-9
• 化学式: C₁₂H₂₂Si
• 分子量: 194.392
• InChiKey: VOAZYWQQHQPOEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.24
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  乙二醇二甲醚 、 二甲基硫 、 (1-tert-Butylcyclopenta-2,4-dien-1-yl)(trimethyl)silane 、 氯化锆(IV) 以 乙二醇二甲醚 、 二氯甲烷 为溶剂， 以45.7%的产率得到
  参考文献：
  名称：

  Ethylene homopolymerization and ethylene/1-hexene copolymerization catalysed by mixed salicylaldiminato cyclopentadienyl zirconium complexes

  摘要：

  Three new mixed salicylaldiminato cyclopentadienyl zirconium complexes Cp'[2-Bu(t)-6-(C(6)H(11)NCH) C(6)H(3)O]ZrCl(2) (Cp' = (n)BuC(5)H(4) (3a), (t)BuC(5)H(4) (3b) and Me(4)C(5)H (3c)) were prepared and the structure of complex 3c was confirmed by X-ray diffraction analysis. All of the three complexes showed high activities for ethylene homopolymerization with the activation of methylaluminoxane, and 3a showed the highest activity up to 1.15 x 10(6) g PE/mol Zr h for ethylene homopolymerization at 70 degrees C. The (13)C NMR spectrum showed that the obtained polymer is linear polyethylene. Complexes 3a-c also catalysed ethylene/1-hexene copolymerization with high activities from 6.29 x 10(5) to 12.3 x 10(5) g Copolymer/mol Zr h and with 0.89-1.39% 1-hexene incorporation level. In addition, the influence of the substituted alkyl on Cp on the catalytic behavior of corresponding zirconium complexes was discussed. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.06.010

文献信息

• Ethylene homopolymerization and ethylene/1-hexene copolymerization catalysed by mixed salicylaldiminato cyclopentadienyl zirconium complexes
  作者：Wenzhong Huang、Xueqin Sun、Haiyan Ma、Jiling Huang

  DOI：10.1016/j.ica.2009.06.010

  日期：2010.6

  Three new mixed salicylaldiminato cyclopentadienyl zirconium complexes Cp'[2-Bu(t)-6-(C(6)H(11)NCH) C(6)H(3)O]ZrCl(2) (Cp' = (n)BuC(5)H(4) (3a), (t)BuC(5)H(4) (3b) and Me(4)C(5)H (3c)) were prepared and the structure of complex 3c was confirmed by X-ray diffraction analysis. All of the three complexes showed high activities for ethylene homopolymerization with the activation of methylaluminoxane, and 3a showed the highest activity up to 1.15 x 10(6) g PE/mol Zr h for ethylene homopolymerization at 70 degrees C. The (13)C NMR spectrum showed that the obtained polymer is linear polyethylene. Complexes 3a-c also catalysed ethylene/1-hexene copolymerization with high activities from 6.29 x 10(5) to 12.3 x 10(5) g Copolymer/mol Zr h and with 0.89-1.39% 1-hexene incorporation level. In addition, the influence of the substituted alkyl on Cp on the catalytic behavior of corresponding zirconium complexes was discussed. (C) 2009 Elsevier B.V. All rights reserved.