Mesitylene oxide | 38440-96-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: Mesitylene oxide
• 英文别名: 1,3,5-trimethyl-7-oxabicyclo[4.1.0]hepta-2,4-diene
• CAS: 38440-96-9
• 化学式: C₉H₁₂O
• 分子量: 136.19
• InChiKey: JUTKCUHVAYRGBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for preparing aldol derivatives from alkenes using catalyst
  申请人：Jasra V. Raksh

  公开号：US20060149101A1

  公开（公告）日：2006-07-06

  The present invention provides a novel eco-friendly multi-functional catalyst system useful to obtain C 2(n+1) aldol-derivative from C n -alkenes where n ranges from 2 to 10 in a single step under hydroformylation reaction conditions and adol formation conditions.

  本发明提供了一种新型的环保多功能催化剂系统，可在一步反应中利用氢甲酰化反应条件和阿尔多尔形成条件从碳烯烃Cn中获得C2(n+1)阿尔多尔衍生物，其中n的范围为2到10。
• DYE CONJUGATE IMAGING AGENTS
  申请人：Nairne Robert James Domett

  公开号：US20110280806A1

  公开（公告）日：2011-11-17

  The present invention relates to imaging agents suitable for in vivo optical imaging, which comprise conjugates of dihydrocarbazolium dyes with biological targeting moieties, such as peptides. Also disclosed are pharmaceutical compositions and kits, as well as in vivo imaging methods. The dihydrocarbazolium dyes are functionalised with water solubilising groups and have functional groups which facilitate conjugation to biological targeting moieties.

  本发明涉及适用于体内光学成像的成像剂，包括二氢咔唑染料与生物靶向物质（如肽）的共轭物。还公开了药物组合物和试剂盒，以及体内成像方法。二氢咔唑染料被功能化为水溶性基团，并具有促进与生物靶向物质结合的功能基团。
• Aldol condensation using solid basic catalyst of MgO and Al2O3 having a high surface area
  申请人：UOP

  公开号：EP0539002A2

  公开（公告）日：1993-04-28

  Solid solutions of magnesium oxide - aluminum oxide related to hydrotalcite and what previously has been referred to as synthetic hydrotalcites, have been prepared with a surface area in excess of 250 m²/g, especially at low Mg/Al atom ratios. Such high surface area basic materials are found to be quite effective as catalysts in the aldol condensation of aldehydes, and in particular in the conversion of n-butyraldehyde to 2-ethyl-2-hexenal in high yield and with good selectivity in a liquid phase reaction at temperatures under about 200oC.

  与氢滑石有关的氧化镁-氧化铝固溶体以及以前被称为合成氢滑石的物质已经制备出来，其表面积超过 250 m²/g，特别是在镁/铝原子比例较低的情况下。在醛的醛醇缩合反应中，这种高比表面积的碱性材料作为催化剂非常有效，特别是在温度低于 200 摄氏度的液相反应中，正丁醛转化为 2-乙基-2-己烯醛的产率高，选择性好。
• PROCESS FOR PREPARING ALDOL DERIVATES FROM ALKENES USING CATALYST
  申请人：COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH

  公开号：EP1836148A1

  公开（公告）日：2007-09-26
• SYNERGISTIC COMPOSITION AND METHOD OF USE
  申请人：Riceco, LLC

  公开号：EP2470016A2

  公开（公告）日：2012-07-04