2-octyldodecyl 4-hydroxybenzoate | 164389-21-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-octyldodecyl 4-hydroxybenzoate
• 英文别名: 2-Octyldodecyl 4-hydroxybenzoate
• CAS: 164389-21-3
• 化学式: C₂₇H₄₆O₃
• 分子量: 418.66
• InChiKey: YMYPUUZKRZRLAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  30
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-octyldodecyl 4-hydroxybenzoate 在 tris-(dibenzylideneacetone)dipalladium(0) 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.0h， 生成 4,7-di(2-thienothienyl)-5,6-di(4-carbo(2-octyldodecyloxy)phenoxy)-benzothiadiazole
  参考文献：
  名称：

  [EN] DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DISUBSTITUTED WITH THIENOTHIOPHENE GROUPS
  [FR] COMPOSÉS DIARYLOXYBENZOHÉTÉRODIAZOLE DI-SUBSTITUÉS PAR DES GROUPES THIÉNOTHIOPHÈNE

  摘要：

  Diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I): wherein: - Z represents a sulfur atom, an oxygen atom, a selenium atom; or a NR5group wherein R5is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or from aryl groups optionally substituted; - R1and R2, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, cycloalkyl groups optionally substituted, aryl groups optionally substituted, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR6groups wherein R6is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or is a cyano group; - R3and R4, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR7or -OCOR7groups wherein R7is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, thioether groups -R8-S-R9wherein R8and R9, identical to or different from each other, are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing 74 heteroatoms; - A represents an electron acceptor group having general formula (II): wherein X1and X2, identical to or different from each other, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, fluorine, bromine, preferably chlorine, fluorine; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted; or are selected from -COOR10ester groups wherein R10is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted. Said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used as an electron acceptor compound in organic photovoltaic devices (or solar devices) selected, for example, from binary, ternary, quaternary, organic photovoltaic cells (or solar cells), having both simple and tandem architecture, organic photovoltaic modules (or solar modules), both on rigid support and on flexible support. Furthermore, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in perovskite-based photovoltaic cells (or solar cells) in the layer based on electron transport material ("Electron Transport Layer" - ETL). Moreover, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in the construction of organic thin film transistors (OTFTs), or of organic field effect transistors (OFETs).

  公开号：

  WO2023105475A1
• 作为产物：
  描述：

  9-(溴甲基)十九烷 、 对羟基苯甲酸 在 potassium hydrogencarbonate 、 potassium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以66 %的产率得到2-octyldodecyl 4-hydroxybenzoate
  参考文献：
  名称：

  [EN] DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DISUBSTITUTED WITH THIENOTHIOPHENE GROUPS
  [FR] COMPOSÉS DIARYLOXYBENZOHÉTÉRODIAZOLE DI-SUBSTITUÉS PAR DES GROUPES THIÉNOTHIOPHÈNE

  摘要：

  Diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I): wherein: - Z represents a sulfur atom, an oxygen atom, a selenium atom; or a NR5group wherein R5is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or from aryl groups optionally substituted; - R1and R2, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, cycloalkyl groups optionally substituted, aryl groups optionally substituted, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR6groups wherein R6is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or is a cyano group; - R3and R4, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR7or -OCOR7groups wherein R7is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, thioether groups -R8-S-R9wherein R8and R9, identical to or different from each other, are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing 74 heteroatoms; - A represents an electron acceptor group having general formula (II): wherein X1and X2, identical to or different from each other, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, fluorine, bromine, preferably chlorine, fluorine; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted; or are selected from -COOR10ester groups wherein R10is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted. Said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used as an electron acceptor compound in organic photovoltaic devices (or solar devices) selected, for example, from binary, ternary, quaternary, organic photovoltaic cells (or solar cells), having both simple and tandem architecture, organic photovoltaic modules (or solar modules), both on rigid support and on flexible support. Furthermore, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in perovskite-based photovoltaic cells (or solar cells) in the layer based on electron transport material ("Electron Transport Layer" - ETL). Moreover, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in the construction of organic thin film transistors (OTFTs), or of organic field effect transistors (OFETs).

  公开号：

  WO2023105475A1

文献信息

• MATERIAL FOR MOLDING, MOLDED ARTICLE PRODUCED FROM SAID MATERIAL, AND METHOD FOR PRODUCING SAID MOLDED ARTICLE
  申请人：Teijin Limited

  公开号：EP2871203A1

  公开（公告）日：2015-05-13

  Provided are a carbon fiber-reinforced thermoplastic polyamide shaped product having excellent physical properties and appearance; a simple method for manufacturing the shaped product without incurring an increase in manufacturing costs; and a material for molding, which enables achievement of the manufacturing method. A material for molding including carbon fiber bundles to be easily impregnated, including carbon fibers and at least one impregnation aid in an amount of 3 to 15 parts by mass based on 100 parts by mass of the carbon fibers and satisfying a specific requirement, wherein 50 to 2,000 parts by mass of a thermoplastic polyamide is adhered to the carbon fiber bundles to be easily impregnated.

  本发明提供了一种碳纤维增强热塑性聚酰胺异型产品，该产品具有优异的物理性能和外观；一种制造该异型产品而不会增加制造成本的简单方法；以及一种可实现该制造方法的成型材料。 一种成型材料，包括易于浸渍的碳纤维束，其中包括碳纤维和至少一种浸渍助剂，以 100 重量份的碳纤维为基准，浸渍助剂的量为 3 至 15 重量份，并满足特定要求，其中 50 至 2 000 重量份的热塑性聚酰胺粘附在易于浸渍的碳纤维束上。
• Material for Molding, Shaped Product Therefrom, and Method for Manufacturing Shaped Product
  申请人：Teijin Limited

  公开号：US20150191583A1

  公开（公告）日：2015-07-09

  There is a material for molding including carbon fiber bundles to be easily impregnated, including carbon fibers and at least one impregnation aid in an amount of 3 to 15 parts by mass based on 100 parts by mass of the carbon fibers and satisfying a specific requirement, wherein 50 to 2,000 parts by mass of a thermoplastic polyamide is adhered to the carbon fiber bundles to be easily impregnated.
• US9284436B2
  申请人：——

  公开号：US9284436B2

  公开（公告）日：2016-03-15
• [EN] DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DISUBSTITUTED WITH THIENOTHIOPHENE GROUPS<br/>[FR] COMPOSÉS DIARYLOXYBENZOHÉTÉRODIAZOLE DI-SUBSTITUÉS PAR DES GROUPES THIÉNOTHIOPHÈNE
  申请人：[en]ENI S.P.A.

  公开号：WO2023105475A1

  公开（公告）日：2023-06-15

  Diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I): wherein: - Z represents a sulfur atom, an oxygen atom, a selenium atom; or a NR5group wherein R5is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or from aryl groups optionally substituted; - R1and R2, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, cycloalkyl groups optionally substituted, aryl groups optionally substituted, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR6groups wherein R6is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or is a cyano group; - R3and R4, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR7or -OCOR7groups wherein R7is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, thioether groups -R8-S-R9wherein R8and R9, identical to or different from each other, are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing 74 heteroatoms; - A represents an electron acceptor group having general formula (II): wherein X1and X2, identical to or different from each other, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, fluorine, bromine, preferably chlorine, fluorine; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted; or are selected from -COOR10ester groups wherein R10is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted. Said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used as an electron acceptor compound in organic photovoltaic devices (or solar devices) selected, for example, from binary, ternary, quaternary, organic photovoltaic cells (or solar cells), having both simple and tandem architecture, organic photovoltaic modules (or solar modules), both on rigid support and on flexible support. Furthermore, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in perovskite-based photovoltaic cells (or solar cells) in the layer based on electron transport material ("Electron Transport Layer" - ETL). Moreover, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in the construction of organic thin film transistors (OTFTs), or of organic field effect transistors (OFETs).