1,2-diazidocyclopentane | 141649-36-7

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 1,2-diazidocyclopentane
• 英文别名: 1,2-Diazidocyclopentane
• CAS: 141649-36-7
• 化学式: C₅H₈N₆
• 分子量: 152.159
• InChiKey: JBELVXJITWLNNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  28.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  环戊烯 在 potassium permanganate 、 sodium azide 作用下， 以 甲醇 为溶剂， 反应 4.0h， 以8%的产率得到trans-1,2-diazidocyclopentane
  参考文献：
  名称：

  The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine

  摘要：

  A complete synthesis of enantiopure trans-cyclopentane-1,2-diamine and trans-cyclobutane-1,2-diamine is described. These diamines have been used as components of novel chiral salen ligands whose chromium and manganese complexes were then evaluated as oxygen transfer agents in the asymmetric epoxidation of alkenes. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00757-7

文献信息

• The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine
  作者：Adrian M. Daly、Declan G. Gilheany

  DOI：10.1016/s0957-4166(02)00757-7

  日期：2003.1

  A complete synthesis of enantiopure trans-cyclopentane-1,2-diamine and trans-cyclobutane-1,2-diamine is described. These diamines have been used as components of novel chiral salen ligands whose chromium and manganese complexes were then evaluated as oxygen transfer agents in the asymmetric epoxidation of alkenes. (C) 2003 Elsevier Science Ltd. All rights reserved.