N,N'-bis-(4-methylbenzylidene)-1,4-butanediamine | 141085-50-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis-(4-methylbenzylidene)-1,4-butanediamine
• 英文别名: (E,E)-N,N'-(Butane-1,4-diyl)bis[1-(4-methylphenyl)methanimine]；1-(4-methylphenyl)-N-[4-[(4-methylphenyl)methylideneamino]butyl]methanimine
• CAS: 141085-50-9
• 化学式: C₂₀H₂₄N₂
• 分子量: 292.424
• InChiKey: ZDUMWFCYKZJTOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-bis-(4-methylbenzylidene)-1,4-butanediamine 、 molybdenum hexacarbonyl 以 苯 为溶剂， 以0%的产率得到cis-tetracarbonyl(N,N'-bis(4-methylbenzylidene)-1,4-butanediamine)molybdenum(0)
  参考文献：
  名称：

  Aldimine derivatives of molybdenum carbonyl

  摘要：

  Aldimines (Ald) such as N,N'-bis(4-methylbenzylidene)-1,2-propanediamine (Ald1), N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine (Ald2) or N,N'-bis(4-N,N-dimethylaminobenzylidene)-1,2-propanediamine (Ald3) reacted with MO(CO)6 to give the respective cis-[(Ald)Mo(CO)4] complexes. N,N'-bis-(4-N,N-dimethylaminobenzylidene)1,3-propanediamine, in spite of comparatively poor reactivity, gave analogous tetracarbonyl, but its 1,4-butanediamine and 1,6-hexanediamine analogues did not give similar derivatives. Ald1-Ald3 after reaction with [(Ph3P)Mo(CO)5] gave corresponding aldimine bridged dinuclear [(Ph3P)(CO)4Mo(mu-Ald)Mo(CO)4(Ph3P)]. Cis-[(Ald)Mo(CO)4] gave [(Ald) Mo(CO)3X2] when reacted with X2 (X = Br or I), but produced [(Ald)MoCl4] after reaction with chlorine. NO reacted with tetracarbonyls to yield a mixture of unusual [(NO)(Ald) MO(CO)2(NO2)] and [(NO)2(Ald)Mo(NO2)2], but NOCl yielded only [(Ald) MO(CO)2(NO)Cl].

  DOI：

  10.1016/s0277-5387(00)83018-1

文献信息

• Aldimine derivatives of molybdenum carbonyl
  作者：Amar Srivastava、A.K. Shrimal、S.C. Srivastava

  DOI：10.1016/s0277-5387(00)83018-1

  日期：1994.3

  Aldimines (Ald) such as N,N'-bis(4-methylbenzylidene)-1,2-propanediamine (Ald1), N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine (Ald2) or N,N'-bis(4-N,N-dimethylaminobenzylidene)-1,2-propanediamine (Ald3) reacted with MO(CO)6 to give the respective cis-[(Ald)Mo(CO)4] complexes. N,N'-bis-(4-N,N-dimethylaminobenzylidene)1,3-propanediamine, in spite of comparatively poor reactivity, gave analogous tetracarbonyl, but its 1,4-butanediamine and 1,6-hexanediamine analogues did not give similar derivatives. Ald1-Ald3 after reaction with [(Ph3P)Mo(CO)5] gave corresponding aldimine bridged dinuclear [(Ph3P)(CO)4Mo(mu-Ald)Mo(CO)4(Ph3P)]. Cis-[(Ald)Mo(CO)4] gave [(Ald) Mo(CO)3X2] when reacted with X2 (X = Br or I), but produced [(Ald)MoCl4] after reaction with chlorine. NO reacted with tetracarbonyls to yield a mixture of unusual [(NO)(Ald) MO(CO)2(NO2)] and [(NO)2(Ald)Mo(NO2)2], but NOCl yielded only [(Ald) MO(CO)2(NO)Cl].