N-[N,N-bis(biphenyl-4-yl)amino]vinylphenyl | 943784-72-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-[N,N-bis(biphenyl-4-yl)amino]vinylphenyl
• 英文别名: 4-ethenyl-N,N-bis(4-phenylphenyl)aniline
• CAS: 943784-72-3
• 化学式: C₃₂H₂₅N
• 分子量: 423.557
• InChiKey: LQWGOZCHSYLGGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-二苯胺基苯甲醛 在 四(三苯基膦)钯 potassium iodate 、 potassium tert-butylate 、 sodium carbonate 、 溶剂黄146 、 potassium iodide 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 51.0h， 生成 N-[N,N-bis(biphenyl-4-yl)amino]vinylphenyl
  参考文献：
  名称：

  The synthesis of robust, polymeric hole-transport materials from oligoarylamine substituted styrenes

  摘要：

  报道了一系列新型苯乙烯基低聚芳胺单体，这些单体适用于制备具有极高玻璃化转变温度的聚合物空穴传输材料。这些单体是通过Wittig反应从适当的醛前体合成得到的，而该醛前体则是通过经典的Ullmann反应组装而成的。其中多种单体生成了高质量的晶体，这有助于利用X射线进行表征。通过溶液自由基引发或通过缩聚相热自聚合可以实现聚合。后者提示了一种无需引发剂的聚合方法，该方法可能在多层器件制造中具有潜在应用价值。

  DOI：

  10.1039/b614235d

文献信息

• CONDENSED-CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20140027721A1

  公开（公告）日：2014-01-30

  Embodiments of the invention are directed to a condensed-cyclic compound represented by Formula 1, and to an organic light-emitting device including the condensed-cyclic compound. The organic light-emitting device may include an organic layer containing the condensed-cyclic compound.

  本发明的实施例涉及一种由式1表示的紧凑环状化合物，以及包括该紧凑环状化合物的有机发光器件。该有机发光器件可能包括含有该紧凑环状化合物的有机层。
• Organic light emitting device and method of manufacturing the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10553796B2

  公开（公告）日：2020-02-04

  An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the emission layer and the second electrode, the electron transport region including an electron auxiliary layer, wherein the hole transport region includes at least one copolymer selected from i) a first copolymer of a first compound and a second compound and ii) a second copolymer of a third compound and a fourth compound, wherein the first compound and the second compound are each independently selected from compounds represented by Formula 1, and the third compound and the fourth compound are each independently selected from compounds represented by Formula 2, and wherein the electron auxiliary layer includes a metal oxide.

  一种有机发光器件包括第一电极； 面向第一电极的第二电极； 位于第一电极和第二电极之间的发射层； 位于第一电极和发射层之间的空穴传输区域；和发射层与第二电极之间的电子传输区域，电子传输区域包括电子辅助层，其中空穴传输区域包括至少一种选自 i) 第一化合物和第二化合物的第一共聚物和 ii) 第三化合物和第四化合物的第二共聚物的共聚物，其中第一化合物和第二化合物各自独立地选自式 1 所代表的化合物，第三化合物和第四化合物各自独立地选自式 2 所代表的化合物，电子辅助层包括金属氧化物。
• ORGANIC LIGHT EMITTING DEVICE AND METHOD OF MANUFACTURING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170125682A1

  公开（公告）日：2017-05-04

  An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the emission layer and the second electrode, the electron transport region including an electron auxiliary layer, wherein the hole transport region includes at least one copolymer selected from i) a first copolymer of a first compound and a second compound and ii) a second copolymer of a third compound and a fourth compound, wherein the first compound and the second compound are each independently selected from compounds represented by Formula 1, and the third compound and the fourth compound are each independently selected from compounds represented by Formula 2, and wherein the electron auxiliary layer includes a metal oxide.
• US9150496B2
  申请人：——

  公开号：US9150496B2

  公开（公告）日：2015-10-06
• The synthesis of robust, polymeric hole-transport materials from oligoarylamine substituted styrenes
  作者：Neil B. McKeown、Samer Badriya、Madeleine Helliwell、Maxim Shkunov

  DOI：10.1039/b614235d

  日期：——

  Novel styrene-based oligoarylamine monomers are described which are suitable for the preparation of polymeric hole-transport materials, with very high glass transition temperatures. The monomers are prepared using the Wittig reaction from the appropriate aldehyde precursor, which was assembled using the classical Ullmann reaction. A number of the monomers yielded high-quality crystals which facilitated X-ray characterisation. Polymerisation was achieved either by solution free-radical initiation or by condensed phase thermal autopolymerisation. The latter suggests a method of initiator-free polymerisation which may have potential for multilayer device fabrication.

  报道了一系列新型苯乙烯基低聚芳胺单体，这些单体适用于制备具有极高玻璃化转变温度的聚合物空穴传输材料。这些单体是通过Wittig反应从适当的醛前体合成得到的，而该醛前体则是通过经典的Ullmann反应组装而成的。其中多种单体生成了高质量的晶体，这有助于利用X射线进行表征。通过溶液自由基引发或通过缩聚相热自聚合可以实现聚合。后者提示了一种无需引发剂的聚合方法，该方法可能在多层器件制造中具有潜在应用价值。