| 1120350-75-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 1120350-75-5
• 化学式: C₄₂H₄₆O₁₀
• 分子量: 710.821
• InChiKey: ADOMHBLBQUKJRJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.84
• 重原子数：
  52.0
• 可旋转键数：
  4.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  107.98
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  、 bis(3-ethyl-4-methyl-1H-pyrrol-2-yl)methane 、 间硝基苯甲醛 在 三氟乙酸 、 邻四氯苯醌 作用下， 以 二氯甲烷 为溶剂， 反应 1.5h， 以5%的产率得到
  参考文献：
  名称：

  Synthesis and basic properties of bisporphyrinocalix[4]arene

  摘要：

  A bisporphyrinocalix[4]arene was prepared, and its basicity was examined spectrophotometrically. The protonation of tetrapyrrole fragments of the porphyrinocalixarene conjugate in the ethanol-sulfuric acid system occurs in two steps and is described by the Hammett equation. The ionization constants and the concentration intervals of the formation of the mono-and dicationic forms of the bisporphyrinocalixarene were determined.

  DOI：

  10.1134/s1070363208040269

文献信息

• Synthesis and design of supramolecular systems on the basis of tetrapyrrole macrocycles
  作者：S. V. Zvezdina、Yu. I. Churakhina、N. Zh. Mamardashvili

  DOI：10.1134/s1070428007120214

  日期：2007.12

  Three new cyclophane-like calixarene-bis-porphyrins were synthesized, and their spectral properties were studied. Zinc complex of meso-(aminophenyl)-substituted calixarene-bis-porphyrin was found to form a stable 1: 1 complex with dimethyl maleate in toluene. Its stability constant was determined by spectrophotometric titration.