Nb(η(5):η(1)-C5H4C(Me2)C9H6)(NMe2)(=N-2,6-i-Pr2C6H3) | 211563-62-1

• 英文名称: Nb(η(5):η(1)-C5H4C(Me2)C9H6)(NMe2)(=N-2,6-i-Pr2C6H3)
• CAS: 211563-62-1
• 化学式: C₃₁H₃₉N₂Nb
• 分子量: 532.57
• InChiKey: ISQLAGPNYHGNGH-OKUPDQQSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Nb(η(5):η(1)-C5H4C(Me2)C9H6)(NMe2)(=N-2,6-i-Pr2C6H3) 、 三甲胺盐酸盐 以 四氢呋喃 为溶剂， 以73%的产率得到[Nb(HNMe2)(η(5):η(3)-C5H4C(Me2)C9H6)(=N-2,6-i-Pr2C6H3)]Cl
  参考文献：
  名称：

  Half-sandwich and ansa-niobiocenes: synthesis and reactivity

  摘要：

  The reaction of [Nb(NMe2)(3)(=N-2,6-iPr(2)C(6)H(3))] 1 with the cyclopentadienyl-indenyl isopropylidene ligand 2 gave the new half-sandwich niobium complex [Nb(eta(5)- C5H4R)(NMe2)(2)(=N-2,6-iPr(2)C(6)H(3))] (R = CMe2C9H7) 3 in high yield. The new ansa-type niobiocene [Nb(NMe2)(=N-2,6-i-Pr2C6H3)(eta 5:eta(1)-{C5H4}C(CH3)(2){C9H6}] 4 was obtained at higher temperatures by an intramolecular deprotonation with concomitant coordination of the indenyl group. The reactivity of the new ansa-niobiocene 4 towards electrophilic reagents, giving chloro- and cationic ansa-type niobium complexes is described. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00720-1
• 作为产物：
  描述：

  (cyclopentadienyl)C(CH3)2(indenyl) 、 tris(dimethylamido)(2,6-diisopropylphenylimido)niobium(V) 以 氘代甲苯 为溶剂， 生成 Nb(η(5):η(1)-C5H4C(Me2)C9H6)(NMe2)(=N-2,6-i-Pr2C6H3)
  参考文献：
  名称：

  Half-sandwich and ansa-niobiocenes: synthesis and reactivity

  摘要：

  The reaction of [Nb(NMe2)(3)(=N-2,6-iPr(2)C(6)H(3))] 1 with the cyclopentadienyl-indenyl isopropylidene ligand 2 gave the new half-sandwich niobium complex [Nb(eta(5)- C5H4R)(NMe2)(2)(=N-2,6-iPr(2)C(6)H(3))] (R = CMe2C9H7) 3 in high yield. The new ansa-type niobiocene [Nb(NMe2)(=N-2,6-i-Pr2C6H3)(eta 5:eta(1)-{C5H4}C(CH3)(2){C9H6}] 4 was obtained at higher temperatures by an intramolecular deprotonation with concomitant coordination of the indenyl group. The reactivity of the new ansa-niobiocene 4 towards electrophilic reagents, giving chloro- and cationic ansa-type niobium complexes is described. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00720-1