TNPAT | 1246465-84-8

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: TNPAT
• CAS: 1246465-84-8
• 化学式: C₁₂₉H₉₆
• 分子量: 1646.18
• InChiKey: DDDBFHMOUCUKCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  36.33
• 重原子数：
  129.0
• 可旋转键数：
  15.0
• 环数：
  25.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  2, 7, 12-tribromo-5,5',10,10',15,15'-hexaethyltruxene 、 9-[1-(1-萘基)苯基-4-YL]-10-硼酸蒽 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以48.5%的产率得到TNPAT
  参考文献：
  名称：

  Efficient blue lighting materials based on truxene-cored anthracene derivatives for electroluminescent devices

  摘要：

  A new series of anthracene derivatives containing a truxene moiety as the core have been synthesized and characterized. They emit in the blue region with excellent solution fluorescence quantum yields and possess high thermal decomposition temperature (T-d>458 degrees C). Typical electroluminescence performance was demonstrated by 2-[10-(4-(1-napthenyl)phenyl)anthracene-9-yl]-5,5',10,10',15,15'-hexaethyltruxene (NPAT) as the blue lighting material in the OLED with structure of ITO/CFx/NPAT/TPBI or Alq(3)/LiF/Al, where TPBI and Alq(3) are 1,3,5-tri(N-phenylbenzimidazol-2-yl)-benzene and tris(8-hydroxyquinolinato) aluminum, respectively. Additionally, the effects of the different thickness of the different electron transporting layers on the device performance were investigated. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.07.039