triammonium salt of 1-phosphonyl-1-cyclopropanecarboxylic acid | 131459-58-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: triammonium salt of 1-phosphonyl-1-cyclopropanecarboxylic acid
• CAS: 131459-58-0
• 化学式: C₄H₇O₅P*3H₃N
• 分子量: 217.162
• InChiKey: IBYOPSUBWZYNCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.06
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  129.83
• 氢给体数：
  4.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1-carbethoxy-1-O,O-diethylphosphonylcyclopropane 在 盐酸 、 ammonium hydroxide 作用下， 生成 triammonium salt of 1-phosphonyl-1-cyclopropanecarboxylic acid
  参考文献：
  名称：

  Cycloalkylation of compounds in the series of phosphorus-substituted derivatives of acetic acid

  摘要：

  1-Phosphoryl-substituted cyclopropanes, cyclobutanes, and cyclopentanes were obtained by the reaction of phosphoryl-substituted esters and nitriles of acetic acid with alpha,omega-dihaloalkanes. The influence of the CH-acidity of the starting compounds and electrophilicity of the alkylating agent on the reaction rate was examined.

  DOI：

  10.1007/bf00961505