N-(n-undecyl)-N-(pyridin-2-ylmethylene)amine | 76684-24-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-(n-undecyl)-N-(pyridin-2-ylmethylene)amine
• 英文别名: N-undecyl-2-picolinimine
• CAS: 76684-24-7
• 化学式: C₁₇H₂₈N₂
• 分子量: 260.423
• InChiKey: YFQDUDJKXAZZLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.03
• 重原子数：
  19.0
• 可旋转键数：
  11.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  25.25
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  N-(n-undecyl)-N-(pyridin-2-ylmethylene)amine 在 水 、 草酸 、 lithium diisopropyl amide 作用下， 生成 十一醛
  参考文献：
  名称：

  A facile biomimetic method for oxidative deamination of primary amines to aldehydes via transposition of an imine functionality

  摘要：

  DOI：

  10.1021/jo00322a046
• 作为产物：
  描述：

  吡啶-2-甲醛 、 正十一胺 以 乙醚 为溶剂， 反应 0.67h， 以98%的产率得到N-(n-undecyl)-N-(pyridin-2-ylmethylene)amine
  参考文献：
  名称：

  A facile biomimetic method for oxidative deamination of primary amines to aldehydes via transposition of an imine functionality

  摘要：

  DOI：

  10.1021/jo00322a046

文献信息

• {N-alkyl-N-[pyridin-2-ylmethylene] amine}dichloro palladium(II) complexes: synthesis, crystal structures and evaluation of their catalytic activities for ethylene polymerization
  作者：Rui Chen、John Bacsa、Selwyn F Mapolie

  DOI：10.1016/s0277-5387(03)00410-8

  日期：2003.9

  Three pyridinylimine palladium(II) complexes of the type [(C5H4N)HC=N-(CH2)n-CH3] PdCl2 (n = 4, 7, 11) were synthesized by reacting (COD)PdCl2 with the appropriate pyridyl-imine ligand. The crystal structure of the complex, where n = 7 was determined using single crystal X-ray crystallography and this displays a striking co-planar geometry, with the pyridine ring, the metal coordination sphere N(1)-C(5)-C(6)-N(2)-Pd and the alkyl backbone all being in the same plane. The three complexes prepared were evaluated as catalyst precursors for ethylene polymerization. Activation with methylaluminoxane (MAO) leads to the formation of an active catalyst species, which produces only high-density polyethylene. The effect of the chain length of the alkyl substituent at the imino nitrogen on the catalytic activity was evaluated. It was found that the molecular weight of the polymer increases as the chain length increases, although a higher level of MAO was required to reach optimum activity. (C) 2003 Elsevier Science Ltd. All rights reserved.