W(η2-PhCCPh)3(NMe3) | 444673-37-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: W(η2-PhCCPh)3(NMe3)
• 英文别名: W(NMe3)(η2-C2Ph2)3；N,N-dimethylmethanamine;2-phenylethynylbenzene;tungsten
• CAS: 444673-37-4
• 化学式: C₄₅H₃₉NW
• 分子量: 777.661
• InChiKey: WOSXIGWOTMLRKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  W(η2-PhCCPh)3(NMe3) 、 双(二苯基磷)乙炔 以 二氯甲烷 为溶剂， 以46%的产率得到W(η2-PhCCPh)3(η1-bis(diphenylphosphino)acetylene)
  参考文献：
  名称：

  W(η2-PhCCPh)3(η1-Ph2PCCPPh2) as a ligand to prepare homo- and hetero-nuclear cluster complexes

  摘要：

  Reaction of W(eta(2) -PhCequivalent toCPh)(3)(NMe3) (1) and Ph(2)PCequivalent toCPPh(2) (dppa) produces W(eta(2)-PhCequivalent toCPh)(3)(eta(1)-Ph(2)PCequivalent toCPPh(2)) (2), which contains a pendant phosphine group. Treatment of 2 with W(CO)(4)(NCMe)(2) yields [W(eta(2) -PhCequivalent toCPh)(3)](mu, eta(2)-Ph(2)PCequivalent to CPPh2)[W(CO)(4)(NCMe)] (3). Compound 2 reacts with Os-3(CO)(10)(NCMe)(2) to afford Os-3(CO)(10)[(mu, eta(2)-Ph(2)PCequivalent toCPPh(2))W(eta(2)- PhCequivalent toCPh)(3)](2) (4), and reacts with Ru-3(CO)(9)(NCMe)(3) to afford Ru-3(CO)(9)[(mu,eta(2)-PhPCequivalent toCPPh(2))W(eta(2)-PhCequivalent toCPh)(3)](3) (5). The crystal structures of 2 and 3 are determined by an X-ray diffraction study. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.037
• 作为产物：
  描述：

  tris(diphenylacetylene)tungsten monocarbonyl 、 十二/十四烷基二甲基氧化胺 以 四氢呋喃 为溶剂， 以41%的产率得到W(η2-PhCCPh)3(NMe3)
  参考文献：
  名称：

  WCl(η²-C₂Ph₂)(η⁶-C₆Ph₆H):  A Compound Containing a Metallacycloheptatriene Unit from Trimerization of Diphenylacetylene with W(NMe₃)(η²-C₂Ph₂)₃

  摘要：

  W(NCMe)(eta(2)-C2Ph2)(3) (1) has been previously synthesized by the reaction of W(CO)(eta(2)-C2Ph2)3 Wit Me3NO in acetonitrile, while the same treatment in THF leads to the trimethylamine complex W(NMe3)(eta(2)-C2Ph2)(3) (2). Compound 2 is reactive. Stirring a mixture of 2 and diphenylacetylene in dichloromethane at room temperature affords WCl(eta(2)-C2Ph2)(eta(6)-C6Ph6H) (3), which apparently arises from trimerization of the alkyne ligands concomitant with solvent activation. The structures of 1-3 have been determined by an X-ray diffraction study. A carbene W=C double bond is evidenced in 3.

  DOI：

  10.1021/om0201009