[Mn(N,N'-ethylene-bis(3-ethoxysalicylideneiminate))(water)2]ClO4 | 181126-22-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Mn(N,N'-ethylene-bis(3-ethoxysalicylideneiminate))(water)2]ClO4
• 英文别名: (Mn(N,N-ethylene-bis(3-ethoxysalicylideneiminate)(H2O)2)(ClO4)；[Mn((EtO)C6H3(O)CHNCH2)2(H2O)2]ClO4
• CAS: 181126-22-7
• 化学式: C₂₀H₂₆MnN₂O₆*ClO₄
• 分子量: 544.825
• InChiKey: VPHPNPCYZOGJBV-YSVHZKDNSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium tetracyanonickelate(II) 、 [Mn(N,N'-ethylene-bis(3-ethoxysalicylideneiminate))(water)2]ClO4 以 甲醇 、 水 、 乙腈 为溶剂， 以57%的产率得到(Mn(N,N-ethylene-bis(3-ethoxysalicylideneiminate)(H2O))2(Ni(CN)4)
  参考文献：
  名称：

  通过氢键相互作用构建的两个氰化桥杂金属一维链配合物：合成，晶体结构和磁性

  摘要：

  两个三核氰化物桥杂金属Ni（II）– Mn（III）络合物{[Mn（L 1）（H 2 O）] 2 [Ni（CN）4 ]} 2H 2 O（1）和{[Mn（L 2）（H 2 O）] 2 [Ni（CN）4 ]}（2）（L 1 = N，N-亚乙基双（3-甲氧基水杨酸亚硝酸盐； L 2 = N，N-亚乙基双（3-乙氧基水杨酸亚硝酸盐） ）是使用[Ni（CN）4 ] 2−获得的以及两个含双室席夫碱配体的锰（III）化合物。X射线衍射表明，两个氰化物桥联的三核配合物通过分子间的OH-H…O氢键相互作用而自互补，该分子间的水配体由一个分子与相邻分子的四个酚氧原子形成，形成超分子一维链结构。对这两种络合物的磁化率的研究表明，相邻的Mn（III）离子之间总体上弱的反铁磁相互作用。

  DOI：

  10.1080/15533174.2011.594842
• 作为产物：
  描述：

  、 在 NaOH 作用下， 以 甲醇 、 乙醇 、 水 为溶剂， 生成 [Mn(N,N'-ethylene-bis(3-ethoxysalicylideneiminate))(water)2]ClO4
  参考文献：
  名称：

  四齿席夫碱配体锰（III）配合物中观察到的多样性：结构趋势的评估。

  摘要：

  摘要：通过对锰（II）前体进行空中氧化，制备了一系列芳基取代的N 2 O 2供体集席夫碱配体的锰（III）配合物。化学合成[MnL] C1O 4·n H 2 O（n = 1-3）的合成物已通过元素分析，红外光谱，快速原子轰击（FAB）质谱，磁化率测量和顺磁性1 H进行了全面表征核磁共振。[MnL 7（H 2 O）2] ClO 4·H 4 O，1的晶体结构显示，它由通过复杂连接的近似八面体的[MnL 7（H 2 O）2] +阳离子的聚合物阵列组成。高氯酸根抗衡离子和晶格水分子之间的氢键网络。席夫碱配体的芳基环之间的π-π稳定作用进一步增强了这种氢键。

  DOI：

  10.1016/0277-5387(96)00161-1

文献信息

• Synthesis, Crystal Structures and Magnetic Properties of Cyanide-bridged Trinuclear and Ion-pair Heterometallic Complexes
  作者：Daopeng Zhang、Ping Wang、Chen Xia

  DOI：10.3184/174751913x13606661141430

  日期：2013.3

  cyanide-bridged, trinuclear, heterometallic Pd(II)–Mn(III) complex [Mn(L)(H2O)}2(μ-CN)2Pd(CN)2}] and an ion-pair complex [Co(Phen)2(H2O)2][Pd(CN)4]·MeOH have been synthesised (L = N,N-ethylene-bis(3-ethoxysalicylideneiminate; Phen = 1,10-phenanthroline). Single X-ray diffraction analysis reveals the neutral trinuclear complex is self-complementary through coordinated aqua ligands from one complex and the

  氰化物桥接的三核异金属 Pd(II)-Mn(III) 配合物 [Mn(L)(H2O)}2(μ-CN)2Pd(CN)2}] 和离子对配合物 [Co (Phen)2( )2][Pd(CN)4]·MeOH 已合成（L = N,N-乙烯-双（3-乙氧基水杨亚胺；Phen = 1,10-菲咯啉）。单 X 射线衍射分析表明，中性三核复合物通过来自一个复合物的配位水配体和来自相邻复合物的游离 O4 室进行自我互补，从而提供一维单链超分子结构。离子对复合物通过分子间 O 形成三维网络…H-N 氢键相互作用。磁化率研究表明，三聚体复合物中相邻 Mn(III) 离子之间存在整体弱的反铁磁耦合。
• Hydrogen-Bond Directed Cyanide-Bridged Molecular Magnets Derived from Polycyanidemetalates and Schiff Base Manganese(III) Compounds: Synthesis, Structures, and Magnetic Properties
  作者：Daopeng Zhang、Hailong Wang、Yuting Chen、Zhong-Hai Ni、Laijin Tian、Jianzhuang Jiang

  DOI：10.1021/ic901530p

  日期：2009.12.7

  [Mn(L1)(H2O)]3[Fe(CN)5(1-CH3im)]}ClO4·1.5H2O (1) and [Mn(L2)(H2O)]3[Fe(CN)5(1-CH3im)]}ClO4·3H2O (2); two heptanuclear cage-shaped MIIIMnIII6 (M = Fe, Cr) compounds, [Mn(L2)(H2O)]6[Fe(CN)6]}[Fe(CN)6]·6CH3OH (3) and [Mn(L2)(H2O)]6[Cr(CN)6]}[Cr(CN)6]·6CH3OH (4); and two two-dimensional M−MnIII networks, [H3O][Mn(L1)]2[Fe(CN)6]}·2DMF (5) and K[Mn(L1)]2[Cr(CN)6]}·1.5CH3CN·CH3OH (6) (L1 = N,N-ethyl

  一系列六种新的氰化物桥杂金属配合物，包括两种四核T型Fe III Mn III 3化合物，[Mn（L 1）（H 2 O）] 3 [Fe（CN）5（1-CH 3 im） ]} ClO 4 ·1.5H 2 O（1）和[Mn（L 2）（H 2 O）] 3 [Fe（CN）5（1-CH 3 im）]} ClO 4 ·3H 2 O（2）; 两种肝核笼形M III Mn III 6（M = Fe，Cr）化合物，[Mn（L2）（H 2 O）] 6 [Fe（CN）6 ]} [Fe（CN）6 ]·6CH 3 OH（3）和[Mn（L 2）（H 2 O）] 6 [Cr（CN ）6 ]} [Cr（CN）6 ]·6CH 3 OH（4）；和两个二维M-Mn III网络，[H 3 O] [Mn（L 1）] 2 [Fe（CN）6 ]}·2DMF（5）和K [Mn（L 1）] 2 [ Cr（CN）6 ]}·1.5CH
• Electronic and steric effects in manganese Schiff-base complexes as models for the water oxidation complex in photosystem II. The isolation of manganese-(<scp>II</scp>) and -(<scp>III</scp>) complexes of 3- and 3,5-substituted N,N′-bis(salicylidene)ethane-1,2-diamine (H₂salen) ligands
  作者：Manuel R. Bermejo、Alfonso Castiñeiras、Juan C. Garcia-Monteagudo、Manuel Rey、Antonio Sousa、Michael Watkinson、Charles A. McAuliffe、Robin G. Pritchard、Roy L. Beddoes

  DOI：10.1039/dt9960002935

  日期：——

  Manganese-(II) and -(III) complexes of substituted N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) ligands H(2)L (substituents are in the 3,5 or 3,5 positions of the phenyl rings of the salen moiety) have been prepared and thoroughly characterised. The reaction of Mn(ClO4)(2) . 6H(2)O with H(2)L in ethanol in air normally leads to manganese(III) complexes ligated by both the N2O2 ligand and water molecule(s). However, by employing electron-withdrawing substituents on the ligand, e.g. 3-Br,5-NO2, a manganese(II) complex can be obtained. A 'borderline' ligand is represented by the 5-NO2 derivative (nsalen), which produces a manganese(II) complex contaminated with a small amount of a manganese(In) species. Using a more rigorous oxidising agent in the synthesis, [Fe(eta-C5H5)(2)][FeCl4], drives the reaction totally to a manganese(III) complex [Mn(nsalen)Cl(H2O)]. In addition to magnetic susceptibility studies, cyclic voltammetry has been employed. All the complexes exhibit an oxidation and reduction peak, the reversible character being confirmed by pulse voltammetry. Pulse voltammetry also confirmed the nature of the manganese(II) species [Mn(bnsalen)(H2O)(2)]. 2H(2)O [H(2)bnsalen = N,N'-bis(3-bromo-5-nitrosalicylidene)ethane-1,2-diamine] and that a slight amount of a manganese(III) species is present in [Mn(nsalen)(H2O)(2)]. 2H(2)O. Six complexes have been crystallographically characterised. Despite the retention of an octahedral manganese environment in all of them, the supramolecular structures exhibit a wide diversity. The 3,5-dichloro and 5-bromo salen complexes containing co-ordinated water display combined pi and hydrogen bonding, as well as dimerisation. The complex [Mn(mu-dbsalen)(mu-O)}(2)] (dbsalen = 3,5-dibromo derivative) offers an alternative bridging arrangement, and [Mn(bsalen)(MeOH)(OClO3)]. H2O (bsalen = 5-bromo derivative) highlights the versatility of the manganese centre in these systems where, unexpectedly, perchlorate is co-ordinated in place of a lattice water. A more subtle rearrangement of supramolecular structure is obtained in [Mn(nsalen)Cl(H2O)] where the usual combination of pi- or hydrogen-bonding interaction is modified by the corresponding ability of the 5-NO2 substituent.