| 770730-75-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• CAS: 770730-75-1
• 化学式: C₅₃H₃₄CuN₄O
• 分子量: 806.425
• InChiKey: CXNGGZSIKKRPSK-CEOKJYECSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 邻四氯苯醌 作用下， 以 溶剂黄146 、 甲苯 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  Synthesis, Spectroscopy Studies, and Theoretical Calculations of New Fluorescent Probes Based on Pyrazole Containing Porphyrins for Zn(II), Cd(II), and Hg(II) Optical Detection

  摘要：

  New pyrazole porphyrin conjugates were successfully prepared from a reaction of beta-porphyrin chalcone derivatives with phenylhydrazine in acetic acid followed by an oxidative step. This fast and efficient synthetic approach provided the expected compounds in yields up to 82%. The sensing ability of the new porphyrin-pyrazole derivatives to detect the metal ions Ag+, Na+, K+, Mg2+, Ca2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Cr3+ was studied by spectrophotometric and spectrofluorimetric titrations. In the presence of Zn2+, the conjugates exhibit changes in the emission spectra that are desired for a ratiometric-type fluoroionophoric detection probe. The studies were extended to gas phase, where the pyrazole porphyrin conjugates show ability to sense metal ions with high selectivity toward Cu2+ and Ag+, and in poly(methyl methacrylate) doped films with promising results for Zn2+ detection.

  DOI：

  10.1021/ic500634y
• 作为产物：
  描述：

  copper(II) acetate monohydrate 、 2-[3-oxo-3-phenylprop-1-en-1-yl]-5,10,15,20-tetraphenylporphyrin 以 甲醇 、 氯仿 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  Synthesis, Spectroscopy Studies, and Theoretical Calculations of New Fluorescent Probes Based on Pyrazole Containing Porphyrins for Zn(II), Cd(II), and Hg(II) Optical Detection

  摘要：

  New pyrazole porphyrin conjugates were successfully prepared from a reaction of beta-porphyrin chalcone derivatives with phenylhydrazine in acetic acid followed by an oxidative step. This fast and efficient synthetic approach provided the expected compounds in yields up to 82%. The sensing ability of the new porphyrin-pyrazole derivatives to detect the metal ions Ag+, Na+, K+, Mg2+, Ca2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Cr3+ was studied by spectrophotometric and spectrofluorimetric titrations. In the presence of Zn2+, the conjugates exhibit changes in the emission spectra that are desired for a ratiometric-type fluoroionophoric detection probe. The studies were extended to gas phase, where the pyrazole porphyrin conjugates show ability to sense metal ions with high selectivity toward Cu2+ and Ag+, and in poly(methyl methacrylate) doped films with promising results for Zn2+ detection.

  DOI：

  10.1021/ic500634y

文献信息

• Porphyrins and Their Derivatives: XXIII. Reaction of Formylporphyrins with Weak CH Acids
  作者：Yu. V. Ishkov、Z. I. Zhilina、L. P. Bardai、S. V. Vodzinskii

  DOI：10.1023/b:rujo.0000034986.64795.8f

  日期：2004.3

  beta-Formylporphyrin iminium salts generated in situ are more reactive than the initial aldehydes in condensation with ketones having an a-methylene group. A convenient modification of the Claisen-Schimdt reaction has been developed, which makes it possible to involve hydrophobic beta-formyltetraphenylporphyrin in the condensation with acetone, 1,4-diacetylbenzene, 2-acetylthiophene, acetylacetone, and acetophenone to obtain beta-substituted tetraphenylporphyrins of the general formula PorphCH=CR'COCR.
• Porphins and their derivatives: XXIV. meso-Tetraphenylporphyrins with β-pyrazole rings
  作者：Yu. V. Ishkov、Z. I. Zhilina、A. V. Mazepa、S. V. Vodzinskii、L. P. Bardai

  DOI：10.1134/s1070428006080021

  日期：2006.8

  A series of 5-substituted 2-(2-phenyl-3,4-dihydro-2H-pyrazol-3-yl)porphyrins was prepared by treating with phenylhydrazine tetraphenylporphyrin derivatives containing in the beta-position fragments of beta-unsaturated ketones or aldehydes. The compounds obtained were oxidized. with o-chloranil into the corresponding pyrazolylporphyrins.