8-fluoro-4-phenyl-5-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline | 1339191-12-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 8-fluoro-4-phenyl-5-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline
• 英文别名: 2,2,2-trifluoro-1-(8-fluoro-4-phenyl-3,3a,4,9b-tetrahydrocyclopenta[c]quinolin-5-yl)ethanone
• CAS: 1339191-12-6
• 化学式: C₂₀H₁₅F₄NO
• 分子量: 361.339
• InChiKey: ONKPJQKSCGSWIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  8-fluoro-4-phenyl-5-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 7.0h， 以78%的产率得到1,2-epoxy-8-fluoro-4-phenyl-5-trifluoroacetyl-1,2,3a,4,5,9b-hexahydro-3H-cyclopenta[c]quinoline
  参考文献：
  名称：

  Synthesis and curing of epoxy-anhydride polymers modified with an oxirane of the tetrahydroquinoline series

  摘要：

  Epoxy-anhydride polymers were prepared from diphenylolpropane diglycidyl ether and isomethyltetrahydrophthalic anhydride in the presence of a chemical modifier, oxirane of the tetrahydroquinoline series. The kinetics of the reaction of the modifier with the anhydride and the curing kinetics of the polymeric compound containing the modifier were studied. The thermal properties and water absorption of the polymers after their curing and structure formation were determined.

  DOI：

  10.1134/s1070427211090230