Co(4-chlorophenyloxyacetic acid)2(H2O)4 | 76147-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Co(4-chlorophenyloxyacetic acid)2(H2O)4
• 英文别名: Co(4-chlorophenyloxyacetic acid)₂(H₂O)₄；CoL₂(H₂O)₄
• CAS: 76147-09-6
• 化学式: C₁₆H₂₀Cl₂CoO₁₀
• 分子量: 502.228
• InChiKey: BOGDJCOTMMRWFW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  对氯苯氧乙酸 、 cobalt(II) chloride hexahydrate 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 72.0h， 以65%的产率得到Co(4-chlorophenyloxyacetic acid)2(H2O)4
  参考文献：
  名称：

  Synthesis and Structure of Three Novel Complexes Based on 4-Chlorophenyloxyacetic Acid

  摘要：

  Three new metal-organic complexes, [CoL2(H2O)(4)] 1, [CdL2(H2O)(2)] 2, and [CuL2(H2O)(2)] 3 [HL = 4-chlorophenyloxyacetic acid], have been synthesized and characterized by IR spectra, elemental analysis, fluorescence spectra, and single-crystal X-ray diffraction. Compounds 1, 2, and 3 are all zero-dimensional dimers. The carboxylate ligand exhibits different coordination modes in all compounds. These compounds exhibit interesting supramolecular architecture according to O-HO and C-HCl interactions. Compounds 1, 2, and 3 develop to different framework though they all are from same ligands, which will be helpful to design of different materials. [Supplemental materials are available for this article. Go to the publisher's online edition of Molecular Crystals and Liquid Crystals to view the free supplemental file: CCDC 902676, 902674, 902675 contains the supplementary crystallographic data for this article. These data can be obtained free of charge viawww.ccdc.cam.ac.uk/conts/retrieving.html(or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; Fax: C44 1223 336033; e-mail: [e-mail]).]

  DOI：

  10.1080/15421406.2013.821917